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Effects of Transition-Metal V-Doping on the Structural, Magnetic and Transport Properties in La0.67Sr0.33MnO3 Manganite Oxide

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Abstract

We have investigated the structural, magnetic, and electrical transport properties of a series of ABO3-type perovskite compounds, La0.67Sr0.33Mn1−x V x O3 (0≤x≤0.15). The samples were characterized by X-ray diffraction and data were analyzed using Rietveld refinement technique, it has been concluded that these materials have the rhombohedral structure with \(\mathrm{R}\overline{3}\mathrm{C}\) space group. The magnetization and resistivity measurements versus temperature proved that all our samples exhibit a ferromagnetic to paramagnetic transition and a metallic to semiconductor one when the temperature increases. Both the Curie temperature T C and the resistivity transition temperature T P of the composites decrease, while the resistance increases as the V content increases. It has been concluded that the electrical conduction mechanism in the metallic regime at low temperatures (T<T P) can be explained on the basis of grain boundary effects and the single electron-magnon scattering process. Resistivity data were well fitted with the relation ρ=ρ 0+ρ 2 T 2+ρ 4.5 T 4.5, whereas the adiabatic Small Polaron Hopping (SPH) and Variable Range Hopping (VRH) models are found to fit well in the paramagnetic semiconducting regime at the high temperature (T>T P).

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Correspondence to Safa Mnefgui.

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Mnefgui, S., Dhahri, A., Dhahri, J. et al. Effects of Transition-Metal V-Doping on the Structural, Magnetic and Transport Properties in La0.67Sr0.33MnO3 Manganite Oxide. J Supercond Nov Magn 26, 251–260 (2013). https://doi.org/10.1007/s10948-012-1756-1

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