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Preparation and characterization of magnetic covalent organic framework and its application for efficient adsorption of Benzo[a]pyrene

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Abstract

Benzo[a]pyrene (BaP), one of the polycyclic aromatic hydrocarbons with potential carcinogenic, mutagenic and teratogenic toxicity, have been widely concerned. Herein, we report a simple and rapid co-precipitation method for the synthesis of magnetic covalent organic framework (Fe3O4/COF-DQTp) adsorbent for BaP removal. The magnetized COF-DQTp was characterized by fourier transform infrared, X-ray diffractometer, Brunauer–Emmett–Teller, vibrating sample magnetometer, transmission electron microscopy, high angle annular dark field scanning transmission electron microscopy image and energy-dispersive X-ray spectroscopy elemental mapping. Under the optimized adsorption conditions, the adsorption efficiency was as high as 99% and the maximum adsorption capacity is 19 mg/g in 10 min. The adsorption kinetics shows that adsorption of BaP onto Fe3O4/COF-DQTp follow pseudo-second order kinetic model. Moreover, the prepared Fe3O4/COF-DQTp has good reusability and is a potential material for the adsorption of BaP.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21976070, 22076067), and the Fundamental Research Funds for the Central Universities (JUSRP22003).

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  1. State Key Laboratory of Food Science and Technology, School of Food Science and Technology, Jiangnan University, Wuxi, 214122, China

    Yue-Hong Pang, Nian-Ci Yang, Jin-Yu Qiao, Xiao-Fang Shen & Yu-Ying Huang

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Pang, YH., Yang, NC., Qiao, JY. et al. Preparation and characterization of magnetic covalent organic framework and its application for efficient adsorption of Benzo[a]pyrene. J Porous Mater 29, 169–179 (2022). https://doi.org/10.1007/s10934-021-01151-8

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