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A nano magnetically mesoporous catalyst for the synthesis of propargylamine derivatives

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Abstract

The condensation of aldehydes or ketones with amines and alkynes in the presence of pyridine-2-carboimine copper(I) complex immobilized on Fe3O4@MCM-41 nanoparticles as a novel catalyst was described, which provides an efficient and practical route to synthesize propargylamine derivatives in the mild conditions. The prepared catalyst was characterized by XRD, SEM, EDX, TEM, VSM, UV–Vis, BET and FTIR techniques. The results have been shown a unique activity for the catalyst in the reaction even at room temperature. The nano-sized magnetic catalyst was recovered by simple separation with an external magnet and favorable reusability was observed after several cycles for recovered catalyst in the model reaction.

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Acknowledgements

We are thankful to the Yazd University Research Council and Iran’s National Science Foundation (INSF) for the financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Yazd University, Yazd, 89158-13149, Iran

    Ali Moaddeli & Mohammad Abdollahi-Alibeik

  2. Legal Medicine Research Center, Legal Medicine Organization, Tehran, Iran

    Ali Moaddeli

Authors
  1. Ali Moaddeli
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  2. Mohammad Abdollahi-Alibeik
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Correspondence to Mohammad Abdollahi-Alibeik.

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Moaddeli, A., Abdollahi-Alibeik, M. A nano magnetically mesoporous catalyst for the synthesis of propargylamine derivatives. J Porous Mater 25, 147–159 (2018). https://doi.org/10.1007/s10934-017-0428-8

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  • DOI: https://doi.org/10.1007/s10934-017-0428-8

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