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12-Tungstophosphoric acid supported on nano sized MCM-41 as an efficient and reusable solid acid catalyst for the three-component imino Diels–Alder reaction

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Abstract

One pot three-component imino Diels–Alder reactions of various types of aldehydes, aniline and dihydropyrane were studied in the presence of nano sized MCM-41 supported 12-tungstophosphoric acid (TPA) as solid acid catalyst. MCM-41 as solid support was synthesized in nano size and the catalysts with different loading amounts of TPA (5–30 wt%) were prepared and characterized by XRD, FT-IR and SEM techniques. The results confirm a good dispersion of the heteropoly acid on the solid supports and based on the experimental results, the catalyst with 10 wt% heteropoly acid shows the best catalytic activity using 0.5 mol% heteropoly acid relative to the aldehyde. The recovery experiments show that the catalyst is reusable after calcination without significant loss in its activity.

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Acknowledgment

We are thankful to the Yazd University Research Council for partial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Yazd University, 89195-741, Yazd, Iran

    Mohammad Abdollahi-Alibeik & Marjan Pouriayevali

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  1. Mohammad Abdollahi-Alibeik
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  2. Marjan Pouriayevali
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Correspondence to Mohammad Abdollahi-Alibeik.

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Abdollahi-Alibeik, M., Pouriayevali, M. 12-Tungstophosphoric acid supported on nano sized MCM-41 as an efficient and reusable solid acid catalyst for the three-component imino Diels–Alder reaction. Reac Kinet Mech Cat 104, 235–248 (2011). https://doi.org/10.1007/s11144-011-0345-9

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  • DOI: https://doi.org/10.1007/s11144-011-0345-9

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