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Highly active recyclable SBA-15-EDTA-Pd catalyst for Mizoroki-Heck, Stille and Kumada C–C coupling reactions

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Abstract

Highly efficient SBA-15-EDTA-Pd(11) heterogeneous catalyst was synthesized by covalent anchoring Pd-EDTA complex over organo-modified surface of SBA-15. SBA-15-EDTA-Pd(11) catalyst was found to exhibit excellent catalytic activity in appreciable yield for Heck, Stille and Kumada cross-coupling reactions. Catalytic system exhibited excellent activity for completion of reaction, isolation, Pd loading (0.87 mmol%) and yields of products as compared to earlier reported heterogeneous supported Pd catalysts. Covalently anchored heterogeneous SBA-15-EDTA-Pd(11) catalyst can be recycled for more than five times without noticeable loss in activity and selectivity.

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Acknowledgements

APS acknowledges CSIR, New Delhi for the financial support in the form of an Emeritus Scientist. Priti Sharma thanks the Department of Science and Technology (DST) for the financial assistance. Jayant Rathod thanks the Council of Scientific and Industrial Research (CSIR), New Delhi for a Senior Research Fellowship. The authors also thank the CSIR, New Delhi for financial support as part of XII Five Year Plan under the title ORIGIN (CSC0108).

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    Authors and Affiliations

    1. Division of Organic Chemistry, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India

      Jayant Rathod, Punam Pandey & Pradeep Kumar

    2. Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India

      Priti Sharma & A. P. Singh

    Authors
    1. Jayant Rathod
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    2. Priti Sharma
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    3. Punam Pandey
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    4. A. P. Singh
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    5. Pradeep Kumar
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    Corresponding author

    Correspondence to Pradeep Kumar.

    Additional information

    Jayant Rathod and Priti Sharma have contributed equally to this work.

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    Rathod, J., Sharma, P., Pandey, P. et al. Highly active recyclable SBA-15-EDTA-Pd catalyst for Mizoroki-Heck, Stille and Kumada C–C coupling reactions. J Porous Mater 24, 837–846 (2017). https://doi.org/10.1007/s10934-016-0323-8

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    • DOI: https://doi.org/10.1007/s10934-016-0323-8

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