Abstract
Low-cost activated carbons were prepared from poplar wood by chemical activation with KOH as a chemical activating agent. The thermal behavior of KOH-impregnated poplar wood was analyzed in detail via the Thermogravimetric analysis (TG, DTG and DSC). Moreover, the effects of impregnation ratio, activation temperature and activation time on the porous structure were investigated. Results showed that KOH has catalytic effect which could promote the pyrolysis of poplar wood at lower activation temperature. The activated carbons from poplar wood with KOH activation could be formed at 550–700 °C. The specific surface area and pore volume of activated carbon increased with increasing the impregnation ratio, activation temperature and activation time. Moreover, influence of increasing impregnation ratio on the porosity of activated carbon is sensitive to activation time. The maximum specific surface area (1551 m2/g) activated carbon with uniform micropores distribution was obtained at activation temperature of 700 °C, impregnation ratio of 3/1 and activation time of 30 min. Carbon skeleton could break seriously when activation temperature is higher than 750 °C.
Similar content being viewed by others
References
X. Xin, K. Ito, Y. Kubo, Carbon 99, 167–173 (2016)
G. Sethia, A. Sayari, Carbon 99, 289–294 (2016)
M.J. Prauchner, F. Rodríguez-Reinoso, Microporous Mesoporous Mater. 109, 581–584 (2008)
D. Lozano-Castelló, M.A. Lillo-Ródenas, D. Cazorla-Amorós, A. Linares-Solano, Carbon 39, 741–749 (2001)
T. Otowa, Y. Nojima, T. Miyazaki, Carbon 35, 1315–1319 (1997)
Z.Y. Li, K.W. Wang, J.T. Song, Q. Xu, N. Kobayashi, J. Mater. Cycles Waste Manag. 16, 359–366 (2013)
K.Y. Foo, B.H. Hameed, Bioresour. Technol. 102, 9814–9817 (2011)
T. Maneerung, J. Liew, Y. Dai, S. Kawi, C. Chong, C.-H. Wang, Bioresour. Technol. 200, 350–359 (2015)
S. Yang, H. Hu, G. Chen, Carbon 40, 277–284 (2002)
T. Tsubota, M. Morita, S. Kamimura, T. Ohno, J. Porous Mater. 23, 349–355 (2016)
G. Gentscheva, P. Vassileva, P. Tzvetkova, L. Lakov, O. Peshev, E. Ivanova, J. Porous Mater. 15, 331–334 (2008)
M. Kubota, A. Hata, H. Matsuda, Carbon 47, 2805–2811 (2009)
A.C. Lua, F.Y. Lau, J. Guo, J. Anal. Appl. Pyrolysis 76, 96–102 (2006)
M.A. Lillo-Ródenas, D. Cazorla-Amorós, A. Linares-Solano, Carbon 41, 267–275 (2003)
J.A. Maciá-Agulló, B.C. Moore, D. Cazorla-Amorós, A. Linares-Solano, Carbon 42, 1367–1370 (2004)
M.S. Contreras, C.A. Páez, L. Zubizarreta, A. Léonard, S. Blacher, C.G. Olivera-Fuentes, Carbon 48, 3157–3168 (2010)
S. Yorgun, D. Yıldız, J. Taiwan Inst. Chem. Eng. 53, 122–131 (2015)
J. Díaz-Terán, Colloids Surf. A Physicochem. Eng. Asp 187–188, 167–175 (2001)
A.N.A. El-Hendawy, Appl. Surf. Sci. 255, 3723–3730 (2009)
Y. Gao, Q. Yue, B. Gao, Y. Sun, W. Wang, Q. Li, Chem. Eng. J. 217, 345–353 (2013)
H. Demiral, I. Uzun, Surf. Interface Anal. 42, 1338–1341 (2010)
J. Díaz-Terán, D.M. Nevskaia, J.L.G. Fierro, A.J. López-Peinado, A. Jerez, Microporous Mesoporous Mater. 60, 173–181 (2003)
P. Sannigrahi, A.J. Ragauskas, G.A. Tuskan, Biofuels Bioprod. Biorefining 4, 209–226 (2010)
G. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada, Carbon 48, 1757–1766 (2010)
M. Zhang, F.L.P. Resende, A. Moutsoglou, D.E. Raynie, J. Anal. Appl. Pyrolysis 98, 65–71 (2012)
J.C. Domínguez, M. Oliet, M.V. Alonso, M.A. Gilarranz, F. Rodríguez, Ind. Crops Prod. 27, 150–156 (2008)
H. Yang, R. Yan, H. Chen, D.H. Lee, C. Zheng, Fuel 86, 1781–1788 (2007)
G.H. Oh, C.H. Yun, C.R. Park, Carbon Sci. 4, 1–5 (2003)
D. Lozano-Castelló, J.M. Calo, D. Cazorla-Amorós, A. Linares-Solano, Carbon 45, 2529–2536 (2007)
R. Ball, A.C. Mcintosh, J. Brindley, Combust. Theory Model. 8, 281–291 (2004)
S.J. Gregg, K.S.W. Sing, Adsorption, Surface Area and Porosity, 2nd edn. (Academic Press, New York, 1982)
M.A. Lillo-Ródenas, J. Juan-Juan, D. Cazorla-Amorós, A. Linares-Solano, Carbon 42, 1371–1375 (2004)
Y. Lv, F. Zhang, Y. Dou, Y. Zhai, J. Wang, H. Liu, J. Mater. Chem. 22, 93–99 (2012)
Z. Hu, E.F. Vansant, Microporous Mater. 3, 603–612 (1995)
P. Ehrburger, A. Addoun, F. Addoun, J. Donnet, Fuel 65, 1447–1449 (1986)
Acknowledgments
The research is supported by International Joint Research and Development Project of Tianjin Talent Introduction and Science and Technology Cooperation Plan (14RCGFGX00850).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, Z., Gao, X., Wu, L. et al. Preparation of activated carbons from poplar wood by chemical activation with KOH. J Porous Mater 24, 193–202 (2017). https://doi.org/10.1007/s10934-016-0252-6
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10934-016-0252-6