Skip to main content
SpringerLink
Log in

Facile microwave-assisted production of Fe3O4 decorated porous melamine-based covalent organic framework for highly selective removal of Hg2+

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

Well dispersed magnetic Fe3O4 decorated porous melamine-based covalent organic frameworks (M-COFs) were facilely fabricated through a microwave-assisted process. The result showed that magnetic M-COFs possess large surface areas of 344–600 m2 g−1 and good magnetic separation performance (M S = 0.75–3.59 emu g−1). Adsorption properties were preliminarily tested by the adsorptive removal of heavy metal ions from waste water. Remarkably, the as-synthesized Fe3O4/M-COFs display highly selective adsorption of Hg2+ with high adsorption capacity (97.65 mg g−1). This highly selective removal of Hg2+ was caused by the high density of N group in M-COFs. In addition, this selective adsorption of Hg2+ was not interfered with other metal ions such as Na+, Cd2+, Zn2+, Ni2+, Pb2+, Mg2+ and Cr3+.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. P.D. Armitage, M.J. Bowes, H.M. Vincent, River Res. Appl. 23, 997–1015 (2007)

    Article  Google Scholar 

  2. S. Islam, K. Ahmed, R. Mohammad, H. Mamun, K. Islam, Ecol. Indic. 48, 282–291 (2015)

    Article  CAS  Google Scholar 

  3. A. Singh, R.K. Sharma, M. Agrawal, F.M. Marshall, Food Chem. Toxicol. 48, 611–619 (2010)

    Article  CAS  Google Scholar 

  4. E.M. Nolan, S.J. Lippard, Chem. Rev. 108, 3443–3480 (2008)

    Article  CAS  Google Scholar 

  5. M. Hua, S. Zhang, B. Pan, W. Zhang, L. Lv, Q. Zhang, J. Hazard. Mater. 211–212, 317–331 (2012)

    Article  Google Scholar 

  6. P. Miretzky, A.F. Cirelli, J. Hazard Mater. 167, 10–23 (2009)

    Article  CAS  Google Scholar 

  7. W.S. WanNgah, M.A.K.M. Hanafiah, Bioresour. Technol. 99, 3935–3948 (2008)

    Article  CAS  Google Scholar 

  8. K. Xia, R.Z. Ferguson, M. Losier, N. Tchoukanova, R. Brüning, Y. Djaoued, J. Hazard Mater. 183, 554–564 (2010)

    Article  CAS  Google Scholar 

  9. P. Huttenloch, K.E. Roehl, K. Czurda, Environ. Sci. Technol. 37, 4269–4273 (2003)

    Article  CAS  Google Scholar 

  10. N. Pourreza, K. Ghanemi, J. Hazard Mater. 161, 982–987 (2009)

    Article  CAS  Google Scholar 

  11. A. Dabrowski, Z. Hubicki, P. Podkośielny, E. Robens, Chemosphere 56, 91–106 (2004)

    Article  CAS  Google Scholar 

  12. M. Huebra, M.P. Elizalde, A. Almela, Hydrometallurgy 68, 33–42 (2003)

    Article  CAS  Google Scholar 

  13. R.J. Lu, J.A. Hou, J. Xu, T.M. Tang, X.H. Xu, J. Hazard Mater. 196, 160–165 (2011)

    Article  CAS  Google Scholar 

  14. F.M. Koehler, M. Rossier, M. Waelle, E.K. Athanassiou, L.K. Limbach, R.N. Grass, D. Günther, W.J. Stark, Chem. Commun. 32, 4862–4864 (2009)

    Article  Google Scholar 

  15. Y. Ni, L. Jin, L. Zhang, J. Hong, J. Mater. Chem. 20, 6430–6436 (2010)

    Article  CAS  Google Scholar 

  16. D. Huang, C.G. Niu, M. Ruan, X.Y. Wang, G.M. Zeng, C.H. Deng, Environ. Sci. Technol. 47, 4392–4398 (2013)

    Article  CAS  Google Scholar 

  17. G.L. Li, Z.S. Zhao, J.Y. Liu, G.B. Jiang, J. Hazard Mater. 192, 277–283 (2011)

    CAS  Google Scholar 

  18. H.Y. Lee, D.R. Bae, J.C. Park, H. Song, W.S. Han, J.H. Jung, Angew. Chem. Int. Ed. 48, 1239–1243 (2009)

    Article  CAS  Google Scholar 

  19. J.S. Liu, X.Z. Du, J. Mater. Chem. 21, 6897–6981 (2011)

    Google Scholar 

  20. H. Parham, B. Zargar, R. Shiralipour, J. Hazard Mater. 205, 94–100 (2012)

    Article  Google Scholar 

  21. D.M. Saad, E.M. Cukrowska, H. Tutu, Appl. Water Sci. 3, 527–534 (2013)

    Article  CAS  Google Scholar 

  22. F. Ke, L.G. Qiu, Y.P. Yuan, F.M. Peng, X. Jiang, A.J. Xie, Y.H. Shen, J.F. Zhu, J. Hazard Mater. 96, 36–43 (2011)

    Article  Google Scholar 

  23. S.T. Zhang, H. Li, Z.Y. Wang, J. Liu, H.L. Zhang, B.D. Wang, Z.Y. Yang, Nanoscale 7, 8495–8502 (2015)

    Article  CAS  Google Scholar 

  24. R.W. Tilford, S.J. Mugavero III, P.J. Pellechia, J.J. Lavigne, Adv. Mater. 20, 2741–2746 (2008)

    Article  CAS  Google Scholar 

  25. S.S. Han, H. Furukawa, O.M. Yaghi, W.A. Goddard III, J. Am. Chem. Soc. 130, 11580–11581 (2008)

    Article  CAS  Google Scholar 

  26. F.J. Uribe-Romo, J.R. Hunt, H. Furukawa, C. Klöck, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 131, 4570–4571 (2009)

    Article  CAS  Google Scholar 

  27. J.D. Xiao, L.G. Qiu, F. Ke, Y.P. Yuan, G.S. Xu, Y.M. Wang, X. Jiang, J. Mater. Chem. A. 1, 8745–8752 (2013)

    Article  CAS  Google Scholar 

  28. R.W. Tilford, W.R. Gemmill, H.C.Z. Loye, J.J. Lavigne, Chem. Mater. 18, 5296–5301 (2006)

    Article  CAS  Google Scholar 

  29. W. Zhang, L.G. Qiu, Y.P. Yuan, A.J. Xie, Y.H. Shen, J.F. Zhu, J. Hazard Mater. 221, 147–154 (2012)

    Article  Google Scholar 

  30. X.C. Wu, Y. Zhang, T. Han, H.X. Wu, S.W. Guo, J.Y. Zhang, RSC Adv. 4, 3299–3305 (2014)

    Article  CAS  Google Scholar 

  31. H. Wang, Z.Y. Wei, H. Matsui, S.Q. Zhou, J. Mater. Chem. A. 2, 15740–15745 (2014)

    Article  CAS  Google Scholar 

  32. J. Cao, B.J. Wang, D.L. Han, S. Yang, J.H. Yang, M.B. Wei, L. Fan, Q.Y. Liu, T.T. Wang, CrystEngComm 15, 6971–6978 (2013)

    Article  CAS  Google Scholar 

  33. S. Han, X. Li, Y. Wang, C. Su, Anal. Methods 6, 2855–2861 (2014)

    Article  CAS  Google Scholar 

  34. A.H. Lu, E.L. Salabas, F. Schüth, Angew. Chem. Int. Ed. 46, 1222–1244 (2007)

    Article  CAS  Google Scholar 

  35. P.N. Diagboya, B.I.O. Owolabi, K.O. Adebowale, RSC Adv. 5, 2536–2542 (2015)

    Article  CAS  Google Scholar 

  36. J.C. Park, D.A. Gilbert, K. Liu, A.Y. Louie, J. Mater. Chem. 22, 8449–8454 (2012)

    Article  CAS  Google Scholar 

  37. Y. Deng, C. Deng, D. Qi, C. Liu, J. Liu, X. Zhang, D. Zhao, Adv. Mater. 21, 1377–1382 (2009)

    Article  CAS  Google Scholar 

  38. A. Banerjee, R. Gokhale, S. Bhatnagar, J. Jog, M. Bhardwaj, B. Lefez, B. Hannoyer, S. Ogale, J. Mater. Chem. 22, 19694–19699 (2012)

    Article  CAS  Google Scholar 

  39. J.D. Xiao, L.G. Qiu, X. Jiang, Y.J. Zhu, S. Ye, X. Jiang, Carbon 59, 372–382 (2013)

    Article  CAS  Google Scholar 

  40. S.Y. Ding, W. Wang, Chem. Soc. Rev. 42, 548–568 (2013)

    Article  CAS  Google Scholar 

  41. J. Zheng, C. Cheng, W.J. Fang, C. Chen, R.W. Yan, H.X. Huai, C.C. Wang, CrystEngComm 16, 3960–3964 (2014)

    Article  CAS  Google Scholar 

  42. F. Chang, J.P. Guo, G.T. Wu, L. Liu, M. Zhang, T. He, P.K. Wang, P. Yu, P. Chen, RSC Adv. 5, 3605–3610 (2015)

    Article  CAS  Google Scholar 

  43. M.G. Schwab, B. Fassbender, H.W. Spiess, A. Thomas, X. Feng, K. Mülen, J. Am. Chem. Soc. 131, 7216–7217 (2009)

    Article  CAS  Google Scholar 

  44. S. Bhattacharjee, Y.R. Lee, W.S. Ahn, CrystEngComm 17, 2575–2582 (2015)

    Article  CAS  Google Scholar 

  45. S. Venkateswarlu, M. Yoon, Dalton Trans. 44, 18427–18437 (2015)

    Article  CAS  Google Scholar 

  46. W. Yantasee, R.D. Rutledge, W. Chouyyok, V. Sukwarotwat, G. Orr, C.L. Warner, M.G. Warner, G.E. Fryxell, R.J. Wiacek, C. Timchalk, R.S. Addleman, ACS Appl. Mater. Interfaces 2, 2749–2758 (2010)

    Article  CAS  Google Scholar 

  47. X. Sun, S. Guo, Y. Liu, S. Sun, Nano Lett. 12, 4859–4863 (2012)

    Article  CAS  Google Scholar 

  48. R.G. Pearson, J. Am. Chem. Soc. 85, 3533–3539 (1963)

    Article  CAS  Google Scholar 

  49. C.M. Sun, F. Ma, G.H. Zhang, R.J. Qu, Y. Zhang, J. Chem. Eng. Data 56, 4407–4415 (2011)

    Article  CAS  Google Scholar 

  50. C. Wang, S.Y. Tao, W. Wei, C.G. Meng, F.Y. Liu, M. Han, J. Mater. Chem. 20, 4635–4641 (2010)

    Article  CAS  Google Scholar 

  51. A. Denizli, G. Özkan, M.Y. Arica, J. Appl. Polym. Sci. 78, 81–89 (2000)

    Article  CAS  Google Scholar 

  52. Y. Wang, B. Li, L. Zhang, P. Li, L. Wang, J. Zhang, Langmuir 28, 1657–1662 (2012)

    Article  CAS  Google Scholar 

  53. Z. Zhu, X.X. Yang, L.N. He, W. Li, RSC Adv. 2, 1088–1095 (2012)

    Article  CAS  Google Scholar 

  54. X. Tang, D. Niu, C. Bi, B. Shen, Ind. Eng. Chem. Res. 52, 13120–13127 (2013)

    Article  CAS  Google Scholar 

  55. S. Thakur, G. Das, P.K. Raul, N. Karak, J. Phys. Chem. C 117, 7636–7642 (2013)

    Article  CAS  Google Scholar 

  56. Z. Lin, W. Bian, J.N. Zheng, Z.W. Cai, Chem. Commun. 51, 8785–8788 (2015)

    Article  CAS  Google Scholar 

  57. T. Kang, Y. Park, J. Yi, Ind. Eng. Chem. Res. 43, 1478–1484 (2004)

    Article  CAS  Google Scholar 

  58. K.Y. Shin, J.Y. Hong, J. Jang, J. Hazard Mater. 190, 36–44 (2011)

    Article  CAS  Google Scholar 

  59. X.J. Cheng, J.P. Li, X.H. Li, D.H. Zhang, H.J. Zhang, A.Q. Zhang, H. Huang, J.S. Lian, J. Mater. Chem. 22, 24102–24108 (2012)

    Article  CAS  Google Scholar 

  60. Q. Lv, G. Li, Z.H. Cheng, H. Lu, X.X. Gao, Environ. Sci. Process. Impacts 16, 116–123 (2014)

    Article  CAS  Google Scholar 

  61. X.H. Zhang, J.G. Huang, Chem. Commun. 46, 6042–6044 (2010)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (21371002, 21303002, 21406003), Anhui Provincial Natural Science Foundation (No. 1408085MB22), and the National “211 Project” of Anhui University.

Author information

Authors and Affiliations

  1. Laboratory of Advanced Porous Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601, People’s Republic of China

    Jinlong Ge, Juanding Xiao, Lingli Liu, Lingguang Qiu & Xia Jiang

  2. Department of Applied Chemistry and Environmental Engineering, Bengbu University, Bengbu, 233030, People’s Republic of China

    Jinlong Ge

Authors
  1. Jinlong Ge
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Juanding Xiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lingli Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lingguang Qiu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xia Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Jinlong Ge or Lingguang Qiu.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 10549 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ge, J., Xiao, J., Liu, L. et al. Facile microwave-assisted production of Fe3O4 decorated porous melamine-based covalent organic framework for highly selective removal of Hg2+ . J Porous Mater 23, 791–800 (2016). https://doi.org/10.1007/s10934-016-0134-y

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-016-0134-y

Keywords

Search

Navigation