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A new layered zirconium biphosphonate framework covalently pillared with N,N′-piperazinebis(methylene) moiety: synthesis and characterization

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Abstract

A new hybrid organic–inorganic material denoted by ZrPMP·1.7H2O, where PMP = N,N′-piperazinebis(methylenephosphonic acid), is prepared through the decomposition of zirconium fluoro-complex in the presence of PMP. This material is characterized by X-ray diffractometry, solid 31P NMR and FT-IR spectrophotometries and thermal analyses. All of the above mentioned analyses provide strong evidence that this material is structurally related to α-type layered zirconium phosphate.

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Acknowledgments

The authors wish to thank the Association of Arab Universities for financial support and Mr. Kamal Alhendawi for English revision.

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Author notes

  1. Muhammad Al-Asqalany

    Present address: Department of Health Professions, University College of Applied Sciences, 1415, Gaza, Palestine

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Al-Azhar University of Gaza, 1277, Gaza, Palestine

    Hussein Alhendawi, Nabil Shurrab & Salem Idhair

  2. Departamento de Química Orgánica, Facultad de Ciencias C-I-602, Universidad Autónoma de Madrid, 28049, Madrid, Spain

    Ernesto Brunet, Elena Rodríguez Payán & Olga Juanes

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  1. Hussein Alhendawi
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  2. Ernesto Brunet
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  3. Elena Rodríguez Payán
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  4. Nabil Shurrab
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  6. Salem Idhair
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  7. Muhammad Al-Asqalany
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Correspondence to Hussein Alhendawi.

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Alhendawi, H., Brunet, E., Payán, E.R. et al. A new layered zirconium biphosphonate framework covalently pillared with N,N′-piperazinebis(methylene) moiety: synthesis and characterization. J Porous Mater 20, 1189–1194 (2013). https://doi.org/10.1007/s10934-013-9702-6

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  • DOI: https://doi.org/10.1007/s10934-013-9702-6

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