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Triple Roles of Thermoplastic Polyurethane in Toughening, Accelerating and Enhancing Self-healing Performance of Thermo-reversible Epoxy Resins

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Abstract

Cracks in polymers can be healed by endowing materials with self-healing performance. Cracks in epoxy resins containing thermo-reversible Diels–Alder bonds (EP-DA) can be self-healed via different heat treatments. However, EP-DA exhibits the disadvantages of brittleness and poor impact resistance yet as that existed in the common epoxy resins, and which limits the application of thermo-reversible self-healing epoxy resins. Herein, thermoplastic polyurethane (TPU) was introduced into EP-DA for the purpose of reducing the brittleness and improving the impact resistance of EP-DA. Meanwhile, it was expected that the self-healing performance of EP-DA could not be affected evidently. Results showed that the impact resistance of EP-DA had been improved greatly as expected upon TPU modification. More importantly, instead of affecting the self-healing performance of EP-DA, the self-healing speed of EP-DA was accelerated evidently by the incorporation of TPU. On the other hand, the healing efficiency of EP-DA was also enhanced markedly. In fact, TPU-modified EP-DA was repaired by dual actions of thermo-reversible DA reaction and thermal movement of thermoplastic polymer chains. In addition, TPU-modified EP-DA could also be healed for many damage-repair cycles. Therefore, thermoplastic polyurethane played a triple role as toughening, accelerating and enhancing self-healing performance of thermo-reversible epoxy resins.

Graphic Abstract

Thermoplastic polyurethane (TPU) was introduced into thermo-reversible self-healing epoxy resins (EP-DA) successfully. As a result, the brittleness was reduced and the impact resistance of EP-DA was improved greatly. What’s more, instead of affecting the self-healing performance of EP-DA, the self-healing speed of EP-DA was accelerated evidently while the self-healing efficiency of EP-DA was enhanced markedly. Therefore, TPU played a triple role as toughening, accelerating and enhancing self-healing performance of thermo-reversible epoxy resins.

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References

  1. Russell BK, Takeda S, Ward C et al (2019) React Funct Polym 144:104353

    Article  Google Scholar 

  2. Kocaman S, Ahmetli G (2020) J Polym Environ 28:1190

    Article  CAS  Google Scholar 

  3. Sarkar S, Kim B (2016) Polym Compos 39:636

    Article  Google Scholar 

  4. Feng LB, Yu ZY, Bian YH et al (2017) Polymer 124:48

    Article  CAS  Google Scholar 

  5. He ZL, Jiang S, An N (2019) J Mater Sci 54:8262

    Article  CAS  Google Scholar 

  6. Feng LB, Bian YH, Chai CS et al (2020) J Polym Environ 28:647

    Article  CAS  Google Scholar 

  7. Yang SW, Du XS, Du ZL et al (2020) Polymer 190:122219

    Article  Google Scholar 

  8. An SY, Noh SM, Nam JH et al (2015) Macromol Rapid Commun 36:1255

    Article  CAS  Google Scholar 

  9. Davis DA, Hamilton A, Yang JL et al (2009) Nature 459:68

    Article  CAS  Google Scholar 

  10. Garcia-Jimeno S, Cano-Sarabia M, Mejias N et al (2015) J Mater Chem A 3:17966

    Article  CAS  Google Scholar 

  11. Chen QM, Yu XW, Pei ZQ et al (2017) Chem Sci 8:724

    Article  CAS  Google Scholar 

  12. Lu YX, Guan Z (2012) J Am Chem Soc 134:14226

    Article  CAS  Google Scholar 

  13. Kim S, Jeon H, Shin S et al (2018) Adv Mater 30:1705145

    Article  Google Scholar 

  14. Montarnal D, Tournilhac F, Hidalgo M et al (2009) J Am Chem Soc 131:7966

    Article  CAS  Google Scholar 

  15. Thakur VK, Kessler MR et al (2015) Polymer 69:369

    Article  CAS  Google Scholar 

  16. Shi Y, Wang M, Ma C et al (2015) Nano Lett 15:6276

    Article  CAS  Google Scholar 

  17. Jo YY, Lee AS, Baek KY et al (2016) Polymer 108:58

    Article  Google Scholar 

  18. Feng LB, Yu ZY, Bian YH et al (2018) Constr Build Mater 186:1212

    Article  CAS  Google Scholar 

  19. Postiglione G, Turri S, Levi M (2015) Prog Org Coat 78:526

    Article  CAS  Google Scholar 

  20. Duval A, Couture G, Caillol S et al (2017) ACS Sustain Chem Eng 5:1199

    Article  CAS  Google Scholar 

  21. Henderson JR, Chesterman JP, Parvez M et al (2010) J Org Chem 75:988

    Article  CAS  Google Scholar 

  22. Samaneh S, Morteza A, Bahram R (2019) J Ind Eng Chem 75:271

    Article  Google Scholar 

  23. Ma SQ, Liu WQ, Hu CH (2010) Macromol Res 18:392

    Article  CAS  Google Scholar 

  24. He S, Shi K, Bai J et al (2001) Polymer 42:9641

    Article  CAS  Google Scholar 

  25. Bakar M, Duk R, Przybylek M et al (2009) J Reinf Plast Compos 28:2107

    Article  CAS  Google Scholar 

  26. Gui D, Xue G, Hao J et al (2014) Polym Eng Sci 54:1704

    Article  CAS  Google Scholar 

  27. Chen TH, Li HS, Gao Y et al (1998) J Appl Polym Sci 69:887

    Article  CAS  Google Scholar 

  28. Bakar M, Kostrzewa M, Pawelec Z (2014) J Thermoplast Compos 27:620

    Article  Google Scholar 

  29. Zhao HW, Feng LB, Shi XT et al (2018) Acta Polym Sin 3:395

    Google Scholar 

  30. Chen SB, Wang QH, Wang TM (2013) J Reinf Plast Compos 32:1136

    Article  Google Scholar 

  31. Ho T, Wang C (2015) J Appl Polym Sci 74:1905

    Article  Google Scholar 

  32. Scheltjens G, Diaz MM, Brancart J et al (2013) React Funct Polym 73:413

    Article  CAS  Google Scholar 

  33. Grenier-Loustalot MJ, Cunha JD (1998) Eur Polym J 34(1998):95

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This research is supported by National Natural Science Foundation of China (Grant No. 51463010).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China

    Libang Feng, Xia He, Yunpeng Zhang & Dongan Qu

  2. School of Bailie Mechanical Engineering, Lanzhou City University, Lanzhou, 730070, China

    Changsheng Chai

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  1. Libang Feng
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  2. Xia He
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  3. Yunpeng Zhang
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  4. Dongan Qu
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  5. Changsheng Chai
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Correspondence to Libang Feng.

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Feng, L., He, X., Zhang, Y. et al. Triple Roles of Thermoplastic Polyurethane in Toughening, Accelerating and Enhancing Self-healing Performance of Thermo-reversible Epoxy Resins. J Polym Environ 29, 829–836 (2021). https://doi.org/10.1007/s10924-020-01923-4

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  • DOI: https://doi.org/10.1007/s10924-020-01923-4

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