Abstract
A novel thin-film composite (TFC) nanofiltration membrane was prepared by interfacial polymerization of polyamide layer on a polyethersulfone support, using monoethanolamine (MEA) and diethanolamine (DEA) with m-phenylenediamine as monomers and trimesoyl chloride (TMC) as crosslink agent. The membrane surface before and after using aminoalcohol monomers (MEA and DEA) was investigated in detail using ATR-FTIR, TGA, AFM and SEM. The AFM and SEM images showed that addition of MEA and DEA had a strong impact on surface morphology. The polyamide layer thickness of control and modified TFC membranes based on MEA and DEA were calculated to be in 180–230 nm range and the mean pore sizes were about 0.35–1.2 nm. The RO performance tests indicated that addition of MEA and DEA can increase the NaCl and Na2SO4 rejection remarkably with little decline in the pure water permeation flux.
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Ghaffarian V, Mousavi SM, Bahreini M, Afifi M (2012) Preparation and characterization of biodegradable blend membranes of PBS/CA. J Polym Environ 21:1150–1157
Misdan N, Lau WJ, Ismail AF (2012) Seawater reverse osmosis (SWRO) desalination by thin-film composite membrane-current development, challenges and future prospects. Desalination 287:228–237
Fathizadeh M, Aroujalian A, Raisi A (2012) Effect of lag time in interfacial polymerization on polyamide composite membrane with different hydrophilic sub layers. Desalination 284:32–41
Jewrajka SK, Reddy AVR, Rana HH, Mandal S, Khullar S et al (2013) Use of 2,4,6-pyridinetricarboxylic acid chloride as a novel co-monomer for the preparation of thin film composite polyamide membrane with improved bacterial resistance. J Membr Sci 439:87–95
Huang SH, Hsu CJ, Liaw DJ, Hu CC, Lee KR, Lai JY (2008) Effect of chemical structures of amines on physicochemical properties of active layers and dehydration of isopropanol through interfacially polymerized thin-film composite membranes. J Membr Sci 307:73–81
Lau WJ, Ismail AF, Misdan N, Kassim MA (2012) A recent progress in thin film composite membrane: a review. Desalination 287:190–199
Lee KP, Arnot TC, Mattia D (2011) A review of reverse osmosis membrane materials for desalination-development to date and future potential. J Membr Sci 370:1–22
Saha NK, Joshi SV (2009) Performance evaluation of thin film composite polyamide nanofiltration membrane with variation in monomer type. J Membr Sci 342:60–69
Xiang J, Xie Z, Hoang M, Zhang K (2013) Effect of amine salt surfactants on the performance of thin film composite poly(piperazine-amide) nanofiltration membranes. Desalination 315:156–163
Hou J, Yuan J, Shang R (2013) Surface-modified zeolite-filled poly(piperazine-amide)/polysulfone composite membrane for potassium extraction. Key Eng Mater 531–532:186–199
Xie W, Geise GM, Freeman BD, Lee HS, Byun G, McGrath JE (2012) Polyamide interfacial composite membranes prepared from m-phenylene diamine, trimesoyl chloride and a new disulfonated diamine. J Membr Sci 403–404:152–161
Fathizadeh M, Aroujalian A, Raisi A (2011) Effect of added NaX nano-zeolite into polyamide as a top thin layer of membrane on water flux and salt rejection in a reverse osmosis process. J Membr Sci 375:88–95
Yingfei X, Akhil P, Vinayak S, Shilpa S (2016) Semiquantitative FTIR analysis of the crosslinking density of poly(ester amide)-based thermoset elastomers. Macromol Mater Eng 301:296–305
Oldan M, Schock G (1989) Characterization of ultrafiltration membranes by infrared spectroscopy, esca, and contact angle measurements. J Membr Sci 43:243–258
Ghosh AK, Jeong BH, Huang X, Hoek EMV (2008) Impacts of reaction and curing conditions on polyamide composite reverse osmosis membrane properties. J Membr Sci 311:34–45
Li X, Wang KY, Helmer B, Chung TS (2012) Thin-film composite membranes and formation mechanism of thin-film layers on hydrophilic cellulose acetate propionate substrates for forward osmosis processes. Ind Eng Chem Res 51:10039–10050
Freger V (2003) Nanoscale heterogeneity of polyamide membranes formed by interfacial polymerization. Langmuir 19:4791–4797
Wang T, Dai L, Zhang Q, Li A, Zhang S (2013) Effects of acyl chloride monomer functionality on the properties of polyamide reverse osmosis (RO) membrane. J Membr Sci 440:48–57
Gang H, Tai-Shung C, MasahiroT, Shoji T (2012) Thin-film composite forward osmosis membranes with novel hydrophilic supports for desalination. J Membr Sci 423–424:543–555
Singh S, Khulbe KC, Matsuura T, Ramamurthy P (1998) Membrane characterization by solute transport and atomic force microscopy. J Membr Sci 142:111–127
Duong PHH, Chung TS (2014) Application of thin film composite membranes with forward osmosis technology for the separation of emulsified oil–water. J Membr Sci 452:117–126
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Hosseinzadeh, M.T., Hosseinian, A. Novel Thin Film Composite Nanofiltration Membrane Using Monoethanolamine (MEA) and Diethanolamine (DEA) with m-Phenylenediamine (MPD). J Polym Environ 26, 1745–1753 (2018). https://doi.org/10.1007/s10924-017-1063-9
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DOI: https://doi.org/10.1007/s10924-017-1063-9