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Temperature-Sensitive Polymer-Based Iron Complexes: Construction, Characterization and Properties in Dye Degradation by Activated H2O2

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Abstract

The preparation of polymer-metal complex is an effective way to achieve the bifunctionality of polymer and metal. In this study, temperature-sensitive polymer was synthesized from triethylene glycol methyl ether methacrylate (MEO2MA) and methacrylic acid N-hydroxysuccinimide ester (NMS) monomers via reversible addition-fragmentation chain transfer (RAFT) polymerization. 6-Aminohexanoic acid was introduced into the temperature-sensitive polymer using an activated ester strategy to obtain branched carboxyl-containing polymers. The carboxyl group in the polymer was coordinated with Fe(III), resulting in temperature-sensitive polymer-based iron complexes. The obtained iron complexes were used as homogeneous catalysts in the Fenton oxidation. Where, 97% and 96% decolorization of rhodamine B (RhB) and methylene blue (MB) could be achieved within 2 h for P(COOH10-co-MEO2MA41)-Fe3+, and the catalytic activities increased with the increase of the COOH content of polymer. In addition, the recycling of the catalyst can be achieved by the heating-centrifugal precipitation method using the temperature-sensitive nature of the polymer.

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Funding

The work was supported by the National Natural Science Foundation of China (52273216), the Zhejiang Provincial Key Research and Development Program (2023C01094) and the Leading Talents of the Zhejiang Provincial 10000 Talents Plan for Scientific and Technological Innovation (2020R52023).

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Authors and Affiliations

  1. Zhejiang Provincial Engineering Research Center for Green and Low-Carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou, 310018, China

    Xiaokang Zhu, Xiuwu Wang, Dongming Qi & Tao Chen

  2. Zhejiang NHU Special Materials Co., Ltd., Shaoxing, 312300, China

    Guiyang Zhou & Hangjun Deng

  3. College of Chemical & Biological Engineering, Zhejiang University, Hangzhou, 310027, China

    Hong Yin

  4. Key Laboratory of Green Cleaning Technology & Detergent of Zhejiang Province, Lishui, 323000, China

    Dongming Qi & Tao Chen

Authors
  1. Xiaokang Zhu
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  2. Xiuwu Wang
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  3. Guiyang Zhou
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  4. Hong Yin
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  5. Dongming Qi
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  6. Hangjun Deng
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  7. Tao Chen
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Contributions

XZ: conducting the experiments, and writing the first draft. XW: participating in some experiments and data analysis. GZ and HY: methodology, project administration. DQ: funding acquisition and co-supervision of the students. HD: planning the experimental route and revision of the draft. TC: funding acquisition, design of the catalyst and revision of the final manuscript. All authors agreed with the final version of the submitted manuscript.

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Correspondence to Hangjun Deng or Tao Chen.

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Zhu, X., Wang, X., Zhou, G. et al. Temperature-Sensitive Polymer-Based Iron Complexes: Construction, Characterization and Properties in Dye Degradation by Activated H2O2. J Inorg Organomet Polym 33, 3237–3246 (2023). https://doi.org/10.1007/s10904-023-02752-3

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  • DOI: https://doi.org/10.1007/s10904-023-02752-3

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