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Influence of Co3O4 Nanoparticles on the Optical, and Electrical Properties of CMC/PAM Polymer: Combined FTIR/DFT Study

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Abstract

The CMC/PAM-Co3O4 nanocomposites were prepared using the casting method. The interaction between Co3O4 and CMC/PAM was analysis and characterized using DFT calculation with FT-IR spectroscopy, UV–Vis analysis and AC conductivity. The interaction between CMC/PAM blend and Co3O4 nanoparticles was occurs and confirmed by DFT calculations due to the presence of OH group in CMC and NH2 group in PAM. The values of the optical band gap (Eg) were decreased as an increase of Co3O4 NPs reflects the effect of the nanoparticles in the modification of electronic structure and the response of Co3O4 NPs to the form of localized electronic states. The values of the optical energy gap were reduced after the addition of Co3O4 nanoparticles. Meanwhile, the electrical conductivity of CMC/PAM-Co3O4 was increased with an increase of Co3O4 NPs at room temperature. The AC conductivity and the dielectric properties were carried out of the nanocomposite films, an enhancement was observed in both values of the dielectric constant \(\left({\epsilon }^{\prime}\right)\) and the dielectric loss (\({{\epsilon }}^{{\prime \prime }})\) after the addition of Co3O4 NPs.

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References

  1. F. Faupel, V. Zaporojtchenko, T. Strunskus, M.J.A.e.m. Elbahri. Metal-polymer nanocomposites for functional applications. 12(12), 1177–1190 (2010)

    CAS  Google Scholar 

  2. L. Nicolais, G. Carotenuto, Metal-Polymer Nanocomposites (Wiley, New York, 2004).

    Book  Google Scholar 

  3. K. Akagi, Interdisciplinary chemistry based on integration of liquid crystals and conjugated polymers: development and progress. Bull. Chem. Soc. Jpn 92(9), 1509–1655 (2019)

    Article  CAS  Google Scholar 

  4. L. Xu, Z. Chu, H. Wang, L. Cai, Z. Tu, H. Liu, C. Zhu, H. Shi, D. Pan, J. Pan, Electrostatically assembled multilayered films of biopolymer enhanced nanocapsules for on-demand drug release. ACS Appl. Bio Mater. 2(8), 3429–3438 (2019)

    Article  CAS  Google Scholar 

  5. H. Wei, H. Wang, A. Li, D. Cui, Z. Zhao, L. Chu, X. Wei, L. Wang, D. Pan, J. Fan, Multifunctions of polymer nanocomposites: environmental remediation, electromagnetic interference shielding, and sensing applications. ChemNanoMat 6(2), 174–184 (2020)

    Article  CAS  Google Scholar 

  6. L. Xu, H. Wang, Z. Chu, L. Cai, H. Shi, C. Zhu, D. Pan, J. Pan, X. Fei, Y. Lei, Temperature-responsive multilayer films of micelle-based composites for controlled release of a third-generation EGFR inhibitor. ACS Appl. Polym. Mater. 2(2), 741–750 (2020)

    Article  CAS  Google Scholar 

  7. S. Pawde, K. Deshmukh, Investigation of the structural, thermal, mechanical, and optical properties of poly (methyl methacrylate) and poly (vinylidene fluoride) blends. J. Appl. Polym. Sci. 114(4), 2169–2179 (2009)

    Article  CAS  Google Scholar 

  8. J. Kim, J.H. Kim, K. Ariga, Redox-active polymers for energy storage nanoarchitectonics. Joule 1(4), 739–768 (2017)

    Article  CAS  Google Scholar 

  9. L. Vtracki, Polymer alloys and blends: thermodynamics and rheology (Hanser Publisher, New York, 1990)

    Google Scholar 

  10. X.-M. Zhang, M.-G. Ma, J. Yang, Z. Xiang, J.-F. Zhu, Y. Alias, Recent advances in cellulose-based materials: synthesis, characterization, and their applications. Int. J. Polym. Sci. 2016, 8730573 (2016)

    Google Scholar 

  11. S.A. Asl, M. Mousavi, M. Labbafi, Synthesis and characterization of carboxymethyl cellulose from sugarcane bagasse. J. Food Process. Technol. 8, 8 (2017)

    Google Scholar 

  12. S. El-Sayed, K. Mahmoud, A. Fatah, A. Hassen, DSC, TGA and dielectric properties of carboxymethyl cellulose/polyvinyl alcohol blends. Physica B 406(21), 4068–4076 (2011)

    Article  CAS  Google Scholar 

  13. I. Dueramae, M. Okhawilai, P. Kasemsiri, H. Uyama, R. Kita, Properties enhancement of carboxymethyl cellulose with thermo-responsive polymer as solid polymer electrolyte for zinc ion battery. Sci. Rep. 10(1), 1–12 (2020)

    Article  Google Scholar 

  14. S. Awad, S. El-Gamal, A.M. El Sayed, E.E.J.P.F.AT. Abdel‐Hady, Characterization, optical, and nanoscale free volume properties of Na‐CMC/PAM/CNT nanocomposites. Polym. Adv. Technol.  31(1),4–125 (2010)

  15. D.C. Lin, B. Yurke, N.A. Langrana, Mechanical properties of a reversible, DNA-crosslinked polyacrylamide hydrogel. J. Biomech. Eng. 126(1), 104–110 (2004)

    Article  PubMed  Google Scholar 

  16. A. Martinez-Ruvalcaba, J. Sánchez-Díaz, F. Becerra, L. Cruz-Barba, A. González-Álvarez, Swelling characterization and drug delivery kinetics of polyacrylamide-co-itaconic acid/chitosan hydrogels. Express Polym Lett 3(1), 25–32 (2009)

    Article  CAS  Google Scholar 

  17. L.H. Gaabour, Influence of silica nanoparticles incorporated with chitosan/polyacrylamide polymer nanocomposites. J. Mater. Res. Technol. 8(2), 2157–2163 (2019)

    Article  CAS  Google Scholar 

  18. S. Roy, B. Prabhakar, Bioadhesive polymeric platforms for transmucosal drug delivery systems–a review. Trop. J. Pharm. Res. 9, 1 (2010)

    Article  Google Scholar 

  19. A. Mandal, D. Chakrabarty, Characterization of nanocellulose reinforced semi-interpenetrating polymer network of poly (vinyl alcohol) & polyacrylamide composite films. Carbohydrate polymers 134, 240–250 (2015)

    Article  CAS  PubMed  Google Scholar 

  20. L. Xu, V. Selin, A. Zhuk, J.F. Ankner, S.A. Sukhishvili, Molecular weight dependence of polymer chain mobility within multilayer films. ACS Macro Lett. 2(10), 865–868 (2013)

    Article  CAS  Google Scholar 

  21. J. Sharma, P. Srivastava, G. Singh, M.S. Akhtar, S.J.M.S. Ameen, E. B, Green synthesis of Co3O4 nanoparticles and their applications in thermal decomposition of ammonium perchlorate and dye-sensitized solar cells. Mater. Sci. Eng.  193, 181–188 (2015)

  22. R. Bhargava, S. Khan, N. Ahmad, M.M.N. Ansari. Investigation of structural, optical and electrical properties of Co3O4 nanoparticles. In:  AIP Conference Proceedings. 2018. AIP Publishing LLC

  23. A. Rajeh, M. Morsi, I. Elashmawi, Enhancement of spectroscopic, thermal, electrical and morphological properties of polyethylene oxide/carboxymethyl cellulose blends: combined FT-IR/DFT. Vacuum 159, 30–440 (2019)

  24. M. Morsi, A. Rajeh, A. Al-Muntaser, Reinforcement of the optical, thermal and electrical properties of PEO based on MWCNTs/Au hybrid fillers: nanodielectric materials for organoelectronic devices. Composites Part B 173, 106957 (2019)

    Article  CAS  Google Scholar 

  25. K.G. Wilson, Ab initio quantum chemistry: a source of ideas for lattice gauge theorists. Nucl. Phys. B  17, 82–92 (1990)

  26. W.J. Hehre, Ab initio molecular orbital theory. Acc. Chem. Res. 9(11), 399–406 (1976)

    Article  CAS  Google Scholar 

  27. K. Yin, D. Zou, B. Yang, X. Zhang, Q. Xia, D. Xu, Investigation of H-bonding for the related force fields in materials studio software. Comput. Appl. Chem 23, 1335–1340 (2006)

    CAS  Google Scholar 

  28. J.P. Perdew, K. Burke, M.J.P.r.l. Ernzerhof. Generalized gradient approximation made simple. 77(18), 3865 (1996)

    CAS  Google Scholar 

  29. C.B. Godiya, X. Cheng, D. Li, Z. Chen, X.J.J.o.h.m. Lu. Carboxymethyl cellulose/polyacrylamide composite hydrogel for cascaded treatment/reuse of heavy metal ions in wastewater. 364, 28–38 (2019)

    CAS  Google Scholar 

  30. Y. Lu, A. Zhuk, L. Xu, X. Liang, E. Kharlampieva, S.A. Sukhishvili, Tunable pH and temperature response of weak polyelectrolyte brushes: role of hydrogen bonding and monomer hydrophobicity. Soft Matter 9(22), 5464–5472 (2013)

    Article  CAS  Google Scholar 

  31. A. Al-Muntaser, M. El-Nahass, H.A. Saad, DFT calculation and experimental study on electronic structure and optical properties of 7-Amino-4-oxo-3-(2-(2-thienyl) vinyl)-4H, 8H-[1, 2, 4] triazino [3, 4-b, 1, 3, 4] thiadiazine-8-carbonitrile thin films. Optik  220,  165199 (2020)

  32. S. Yamago, Photoactivation of organotellurium compounds in precision polymer synthesis: controlled radical polymerization and radical coupling reactions. Bull. Chem. Soc. Jpn 93(2), 287–298 (2020)

    Article  CAS  Google Scholar 

  33. A. Al-Muntaser, M. El-Nahass, A. Oraby, M. Meikhail, H. Zeyada, Structural and optical characterization of thermally evaporated nanocrystalline 5, 10, 15, 20-Tetraphenyl-21H, 23H-porphine manganese (III) chloride thin films. Optik 167, 204–2017 (2018)

  34. V. Ganesh, B.R. Kumar, Y. Bitla, I.S. Yahia, S. AlFaify, Structural, Optical and Dielectric Properties of Nd Doped NiO Thin Films Deposited with a Spray Pyrolysis Method. J. Inorg. Organomet. Polym Mater. (2021). https://doi.org/10.1007/s10904-021-01889-3

    Article  Google Scholar 

  35. F. Abd El-kader, N. Hakeem, R. Hafez, A. Ismail, Effect of Li 4 Ti 5 O 12 nanoparticles on structural, optical and thermal properties of PVDF/PEO blend. J. Inorg. Organomet. Polym Mater. 28(3), 1037–1048 (2018)

    Article  CAS  Google Scholar 

  36. A. Al-Muntaser, A. Abdelghany, E. Abdelrazek, A. Elshahawy, Enhancement of optical and electrical properties of PVC/PMMA blend films doped with Li4Ti5O12 nanoparticles. J. Mater. Res. Techol. 9(1), 789–797 (2020)

    Article  CAS  Google Scholar 

  37. M. Meikhail, A. Oraby, M. El-Nahass, H. Zeyada, A. Al-Muntaser, Electrical conduction mechanism and dielectric characterization of MnTPPCl thin films. Physica B 539, 1–7 (2018)

    Article  CAS  Google Scholar 

  38. E. Abdelrazek, I. Elashmawi, A. Hezma, A. Rajeh, M. Kamal, Effect of an encapsulate carbon nanotubes (CNTs) on structural and electrical properties of PU/PVC nanocomposites. Physica B 502, 48–55 (2016)

    Article  CAS  Google Scholar 

  39. I. Elashmawi, E. Abdelrazek, A. Hezma, A. Rajeh, Modification and development of electrical and magnetic properties of PVA/PEO incorporated with MnCl2. Physica B 434, 57–63 (2014)

    Article  CAS  Google Scholar 

  40. A.L. Saad, S. El-Sabbagh, Compatibility studies on some polymer blend systems by electrical and mechanical techniques. J. Appl. Polym. Sci. 79(1), 60–71 (2001)

    Article  CAS  Google Scholar 

  41. S. El-Sabbagh, S.M. Mokhtar, S.L. Abd‐El, Messieh, Electrical and mechanical properties of grafted and ungrafted polyacrylamide–rubber blends. J. Appl. Polym. Sci. 70(10), 2053–2059 (1998)

    Article  CAS  Google Scholar 

  42. C. Koops, On the dispersion of resistivity and dielectric constant of some semiconductors at audiofrequencies. Phys. Rev. 83(1), 121 (1951)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Physics Division, Spectroscopy Department, National Research Centre (NRC), Doki, Egypt

    I. S. Elashmawi

  2. Physics Department, Faculty of Education and Applied Sciences at Arhab, Sana′a University, Sana′a, Yemen

    A. A. Al-Muntaser

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  1. I. S. Elashmawi
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  2. A. A. Al-Muntaser
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Elashmawi, I.S., Al-Muntaser, A.A. Influence of Co3O4 Nanoparticles on the Optical, and Electrical Properties of CMC/PAM Polymer: Combined FTIR/DFT Study. J Inorg Organomet Polym 31, 2682–2690 (2021). https://doi.org/10.1007/s10904-021-01956-9

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