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Multicomponent Self-assembly of Two Cd(II)-Based Coordination Polymers: Synthesis, Structures and Photocatalytic Properties

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Abstract

Two Cd(II) coordination polymers (CPs), namely {[Cd(L1)(mip)]·0.33H2O}n (1) and {[Cd(L2)(BDC-Cl4)]·1.35H2O}n (2) (H2mip = 5-methylisophthalic acid; L1 = 1,5-bis(benzimidazol-1-yl)pentane; H2BDC-Cl4  =   tetrachloroterephthalic acid; L2 = 1,2-bis(2-methylbenzimidazol-1-yl)benzene) were synthesized and characterized. 1 features a 3D pcu network, 2 displays a 2D (4,4) layer. The photocatalytic activities of CPs 1 and 2 for degradation of methylene blue (MB) solution as well as the influence factors such as pH, concentration of dye and catalyst dosage were investigated under UV irradiation. The thermogravimetric analyses and luminescence properties of 1 and 2 were also carried out.

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Acknowledgements

The work was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation–Steel and Iron Foundation of Hebei Province (B2015209299).

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, No. 21 Bohai Road, Caofeidian New-City, Tangshan, 063210, Hebei, People’s Republic of China

    Wen-Chao Kang, Zeng-Chuan Hao, Chao Han & Gui-Ying Dong

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  1. Wen-Chao Kang
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  2. Zeng-Chuan Hao
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Correspondence to Zeng-Chuan Hao or Gui-Ying Dong.

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Kang, WC., Hao, ZC., Han, C. et al. Multicomponent Self-assembly of Two Cd(II)-Based Coordination Polymers: Synthesis, Structures and Photocatalytic Properties. J Inorg Organomet Polym 30, 1877–1885 (2020). https://doi.org/10.1007/s10904-019-01388-6

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