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Synthesis, characterization, and property study of coordination polymers constructed from Cd salt and mixed ligands

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Abstract

Two interesting new coordination polymers {[Cd(Dcbpyno)(1,4′-Bix)1.5] · 2H2O} n (I) and [Cd(1,2′-Cy)(4,4′-Bipy)] n (II) (Dcbpyno = 2,2-bipyridine-3,3-dicarboxylate-1,1′-dioxide, 1,4-Bix = 1,4-bis(imidazol-1-ylmethyl)benzene, 1,2′-Cy = 4-cyclohexene-1,2-dicarboxylate and 4,4′-Bipy = 4,4′-bipyridine) have been synthesized under different conditions. The X-ray crystal structures of these two complexes are presented (CIF files CCDC nos. 905357 (I), 874125 (II)). Complex I exhibits three-dimensional network, while complex II shows an interesting two-dimensional covalent layer structure. Furthermore, the photocatalytic property of complex I and the fluorescent property of complex II were reported.

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    P. Zhang, J. Tong & C. Y. Xing

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  1. P. Zhang
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  2. J. Tong
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  3. C. Y. Xing
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Correspondence to P. Zhang.

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Zhang, P., Tong, J. & Xing, C.Y. Synthesis, characterization, and property study of coordination polymers constructed from Cd salt and mixed ligands. Russ J Coord Chem 41, 80–85 (2015). https://doi.org/10.1134/S107032841501011X

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  • DOI: https://doi.org/10.1134/S107032841501011X

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