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Gamma Irradiation and Heat Treatment Effects on Barium Borosilicate Glasses Doped Titanium Oxide

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Abstract

A simple comparative study on the effect of doping barium borosilicate glasses by two different concentrations of TiO2 is studied. Changes occurred in some of their physical properties due to subjecting to gamma radiation or heat treatment processes are also discussed. The measured properties are Density, Optical UV absorbance and transmittance, infrared absorption spectroscopy and scanning electron microscope. Ti ions can participate in the glassy network as effective modifier ions in the form of TiO6 and TiO4 octahedral groups. Titanium ions can exist in two valence states; the trivalent Ti3+and tetravalent Ti4+ ions giving UV bands at 340 nm on the UV spectrum and at 400–480 nm after gamma irradiation. The main constituting groups BO3 and BO4 units give IR bands at 1250–1500 and 800–1200 cm−1, respectively. In Ti-doped glasses, vibrational bands of SiO4, TiO4 or (Si–O–Ti) vibrations are detected at 600–800 cm−1. Heat treatment process at 525 °C for 6 h gives more ordered glassy structures with good properties; higher density, lower UV absorbance and higher transmittance, on the contrary, the effect of radiation that weakens the glassy structure and creates more non-bridging oxygens NBOs.

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Authors and Affiliations

  1. National Center for Radiation Research and Technology, Radiation Chemistry Department, Atomic Energy Authority, P. O. Box 8029, Nasr City, Cairo, 11371, Egypt

    N. A. El-Alaily, E. M. Abou Hussein & F. M. Ezz Eldin

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  1. N. A. El-Alaily
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  2. E. M. Abou Hussein
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  3. F. M. Ezz Eldin
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Correspondence to E. M. Abou Hussein.

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El-Alaily, N.A., Hussein, E.M.A. & Ezz Eldin, F.M. Gamma Irradiation and Heat Treatment Effects on Barium Borosilicate Glasses Doped Titanium Oxide. J Inorg Organomet Polym 28, 2662–2676 (2018). https://doi.org/10.1007/s10904-018-0934-4

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