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Dye Adsorption on Cubic Polyhedral Oligomeric Silsesquioxane-Based Poly(acrylamide-co-itaconic acid) Hybrid Nanocomposites: Kinetic, Thermodynamic and Isotherms Studies

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Abstract

In the present study, poly(acrylamide-co-itaconic acid) hybrid nanocomposites were synthesized via free radical copolymerization method. Octavinyl polyhedral oligomeric silsesquioxane (OV-POSS) with different weight ratio (0, 4, 8, 12 and 14 wt%) was utilized as a cross-linker. Dye adsorption properties of the as-prepared hybrid nanocomposites were investigated for crystal violet (CV) elimination from aqueous solution. The effect of various parameters, such as OV-POSS content, adsorbent amount, pH, temperature, contact time and initial dye concentration, on the adsorption of CV was studied. Moreover, adsorption kinetic, isotherm and the thermodynamic of the CV adsorption on the so-called hybrid nanocomposites were studied.

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Acknowledgements

We are grateful to the University of Maragheh for financial support. Corresponding author thanks the Iran Science Elites Federation (ISEF).

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Authors and Affiliations

  1. Department of Chemistry, University of Maragheh, Maragheh, 55181-83111, Iran

    Bagher Eftekhari-Sis, Ali Akbari, Parisa Yekan Motlagh & Zahra Bahrami

  2. Polymer Research Laboratory, Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Nasser Arsalani

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  1. Bagher Eftekhari-Sis
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  2. Ali Akbari
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Correspondence to Bagher Eftekhari-Sis.

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Eftekhari-Sis, B., Akbari, A., Motlagh, P.Y. et al. Dye Adsorption on Cubic Polyhedral Oligomeric Silsesquioxane-Based Poly(acrylamide-co-itaconic acid) Hybrid Nanocomposites: Kinetic, Thermodynamic and Isotherms Studies. J Inorg Organomet Polym 28, 1728–1738 (2018). https://doi.org/10.1007/s10904-018-0820-0

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