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Preparation and Characterization of Novel Hybrid Nanocomposites by Free Radical Copolymerization of Vinyl pyrrolidone with Incompletely Condensed Polyhedral Oligomeric Silsesquioxane

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Abstract

A new series of hybrid nanocomposites based on poly (vinyl pyrrolidone) (PVP) containing incompletely condensed polyhedral oligomeric silsesquioxane (IC-POSS) with different percentages of POSS were prepared via free radical copolymerization. Incompletely condensed, phenyl-POSS (Na3O12Si7(C6H5)7) with the highly reactive group of trisodium silanolate was used to prepare desire IC-POSS by nucleophilic substitution reaction. The products were characterized by Fourier transform infrared, X-ray diffraction, scanning electron microscopy, differential scanning calorimetry and thermogravimetric analysis techniques. The results of analysis confirmed that there are good interactions between IC-POSS and the PVP matrix. The thermal stability of the PVP was enhanced with the addition of small amounts of nano-filler. The solubility of the nanocomposites has been also tested and the results showed that with increasing the IC-POSS content the hydrophobicity of nanocomposites were increased.

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Acknowledgments

The authors would like to thank the Tabriz University for financially supporting this research.

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Authors and Affiliations

  1. Research Laboratory of Polymer, Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Ali Akbari & Nasser Arsalani

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  1. Ali Akbari
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  2. Nasser Arsalani
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Correspondence to Nasser Arsalani.

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Akbari, A., Arsalani, N. Preparation and Characterization of Novel Hybrid Nanocomposites by Free Radical Copolymerization of Vinyl pyrrolidone with Incompletely Condensed Polyhedral Oligomeric Silsesquioxane. J Inorg Organomet Polym 26, 536–544 (2016). https://doi.org/10.1007/s10904-016-0340-8

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  • DOI: https://doi.org/10.1007/s10904-016-0340-8

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