Skip to main content
SpringerLink
Log in

3D-Interpenetrating Frameworks of 3∞[Cu2(CN)4(Me3Pb)2(bpy)] Containing the Rhombic [Cu2(µ3-CN)2] Motifs

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A supramolecular coordination polymer (SCP), 3∞[Cu2(CN)4(Me3Pb)2(bpy)], 1, based on the Cun(CN)m building blocks and (Me3Pb)+ cation was synthesized in the presence of an auxiliary rigid-planar bipodal 4,4′-bipyridine (4,4′-bpy) ligand under ambient conditions. The single crystal X-ray diffraction analysis revealed that the Cu(I) sites acquire T-4 geometry and the lead atom, Pb1 assumes TBPY-5 configuration. The rhombic [Cu2(µ3-CN)2] motifs display the essential role as the main building blocks which are interconnected by the (Me3Pb)+ cations to form infinite quasi-planer sheets containing the 24-atomic C8N8Cu4Pb4 rings. These sheets are connected by the bpy ligands producing 3D-network. The wide vacant space present in the framework of 1 is occupied by a second and identical 3D-framework in that each bpy pillar of one framework passes the center of the 24-atomic ring of the complementary framework producing an inextricably interpenetrated structure. The IR, electronic absorption and emission spectra are also investigated. The SCP 1 is an effective catalyst for methylene blue degradation in presence of H2O2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. S.E.H. Etaiw, S.N. Abdou, A.A. Faheim, J. Coord. Chem. 68(3), 491 (2015)

    Article  CAS  Google Scholar 

  2. S.E.H. Etaiw, A.S. Badr, El-din. J. Inorg. Organomet. Polym. 22, 478 (2012)

    Article  CAS  Google Scholar 

  3. S.E.H. Etaiw, A.S. Sultan, A.S. Badr, El-din. Eur. J. Med. Chem. 46, 5370 (2011)

    Article  CAS  Google Scholar 

  4. S.E.H. Etaiw, M.E. El-Zaria, T.A. Fayed, S.N. Abdou, J. Inorg. Organomet. Polym. 21, 480 (2011)

    Article  CAS  Google Scholar 

  5. S.E.H. Etaiw, S.N. Abdou, J. Inorg. Organomet. Polym. 22, 780 (2012)

    Article  CAS  Google Scholar 

  6. S.E.H. Etaiw, T.A. Fayed, S.N. Abdou, J. Organomet. Chem. 695, 1918 (2010)

    Article  CAS  Google Scholar 

  7. A.M.A. Ibrahim, E. Siebel, R.D. Fischer, Inorg. Chem. 37, 3521 (1998)

    Article  CAS  Google Scholar 

  8. E. Siebel, A.M.A. Ibrahim, R.D. Fischer, Inorg. Chem. 38, 2530 (1999)

    Article  CAS  Google Scholar 

  9. H. Hanika-Heidl, S.E.H. Etaiw, MSh Ibrahim, A.S. Badr El-din, R.D. Fischer, J. Organomet. Chem. 684, 329 (2003)

    Article  CAS  Google Scholar 

  10. S.E.H. Etaiw, S.A. Amer, M.M. El-Bendary, J. Inorg. Organomet. Polym. 21, 662 (2011)

    Article  CAS  Google Scholar 

  11. U. Muller, M. Schubert, F. Teich, H. Puetter, K. Schierle-Arndt, J. Pastre´, J. Mater. Chem. 16, 626 (2006)

    Article  Google Scholar 

  12. M. Dincaj, A.F. Yu, J.R. Long, J. Am. Chem. Soc. 128, 8904 (2006)

    Article  Google Scholar 

  13. J.C. Vickery, M.M. Olmstead, E.Y. Fung, A.L. Balch, Angew. Chem. Int. Ed. 36, 1179 (1997)

    Article  CAS  Google Scholar 

  14. S.M. Drew, D.E. Janzen, C.E. Buss, D.I. MacEwen, K.I. Dublin, K.R. Mann, J. Am. Chem. Soc. 123, 8414 (2001)

    Article  CAS  Google Scholar 

  15. C.E. Buss, K.R. Mann, J. Am. Chem. Soc. 124, 1031 (2002)

    Article  CAS  Google Scholar 

  16. W. Lu, M.C.W. Chan, N. Zhu, C.-M. Che, Z. He, K.-Y. Wong, Chem. Eur. J. 9, 6155 (2003)

    Article  CAS  Google Scholar 

  17. J.W. Eastes, W.M. Burgess, J. Am. Chem. Soc. 64, 1187 (1942)

    Article  CAS  Google Scholar 

  18. T.A. Tronic, K.E. Dekrafft, M.J. Lim, A.N. Ley, R.D. Pike, Inorg. Chem. 46, 8897 (2007)

    Article  CAS  Google Scholar 

  19. D.J. Chesnut, D. Plewak, J. Zubieta, J. Chem. Soc. Dalton Trans. 2567 (2001)

  20. S.E.H. Etaiw, S.N. Abdou, J. Inorg. Organomet. Polym. 20, 622 (2010)

    Article  CAS  Google Scholar 

  21. J.D. Kildea, B.W. Skelton, A.H. Wite, Aust. J. Chem. 38, 1329 (1985)

    Article  CAS  Google Scholar 

  22. D.T. Cromer, A.C. Larson, R.B. Roof Jr, Acta Crystallogr. 19, 192 (1965)

    Article  CAS  Google Scholar 

  23. F.B. Stocker, T.P. Staeva, C.M. Rienstra, D. Britton, Inorg. Chem. 38, 984 (1999)

    Article  CAS  Google Scholar 

  24. R. Wiess, G. Jansen, R. Boese, M. Epple, Dalton Trans. 1831 (2006)

  25. J.M. Zheng, S.R. Batten, M. Du, Inorg. Chem. Commun. 44, 3371 (2005)

    Article  CAS  Google Scholar 

  26. B. Liu, L. Xu, G.-C. Guo, J.-S. Huang, Inorg. Chem. Commun. 8, 796 (2005)

    Article  CAS  Google Scholar 

  27. A.F. Wells, Z. Kristallogr. 94, 447 (1936)

    CAS  Google Scholar 

  28. A.M.A. Ibrahim, J. Organomet. Chem. 556, 1 (1998)

    Article  CAS  Google Scholar 

  29. J. Yang, Q. Yue, G.-D. Li, J.-J. Cao, G.-H. Li, J.-S. Chen, Inorg. Chem. 45, 2857 (2006)

    Article  CAS  Google Scholar 

  30. A. Thirumurugan, S. Natarajan, Dalton Trans. 2923 (2004)

  31. K. Yamamote, T. Takemura, H. Baba, Bull. Chem. Soc. Jpn 51, 729 (1978)

    Article  Google Scholar 

  32. M.J. Lim, C.A. Murray, T.A. Tronic, K.E. deKrafft, A.N. Ley, J.C. deButts, R.D. Pike, H. Lu, H.H. Patterson, Inorg. Chem. 47, 6931 (2008)

    Article  CAS  Google Scholar 

  33. C.A. Bayse, T.P. Brewster, R.D. Pike, Inorg. Chem. 48, 174 (2009)

    Article  CAS  Google Scholar 

  34. G.L. Baughman, E.J. Weber, Environ. Sci. Technol. 28, 267 (1994)

    Article  CAS  Google Scholar 

  35. S. Ameen, M. Shaheer Akhtar, Y. Soon Kim, O. Bong Yang, H. Shik Shin, Y., O- & H.-. Colloid Polym. Sci. 289, 415 (2011)

    Article  CAS  Google Scholar 

  36. C. Comninellis, A. Kapalka, S. Malato, S.A. Parsons, I. Poulios, D. Mantzavinos, J. Chem. Technol. Biotechnol. 83(6), 769 (2008)

    Article  CAS  Google Scholar 

  37. D. Bahnemann, Sol. Energy 77(5), 445 (2004)

    Article  CAS  Google Scholar 

Download references

Author information

Author notes

  1. Safaa N. Abdou

    Present address: Chemistry Department, Faculty of Education and Science (Khourma), Taif University, Taif, Saudi Arabia

  2. Ahmed S. Badr El-din

    Present address: Department of Chemistry, Faculty of Science, University of Tabuk, Tabuk, Saudi Arabia

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

    Safaa Eldin H. Etaiw, Safaa N. Abdou & Ahmed S. Badr El-din

Authors
  1. Safaa Eldin H. Etaiw
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Safaa N. Abdou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ahmed S. Badr El-din
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Safaa Eldin H. Etaiw.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Etaiw, S.E.H., Abdou, S.N. & Badr El-din, A.S. 3D-Interpenetrating Frameworks of 3∞[Cu2(CN)4(Me3Pb)2(bpy)] Containing the Rhombic [Cu2(µ3-CN)2] Motifs. J Inorg Organomet Polym 25, 1478–1485 (2015). https://doi.org/10.1007/s10904-015-0264-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-015-0264-8

Keywords

Search

Navigation