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Polynuclear Loop-Modified Molybdenum Arsenate: Synthesis, Structure and Property

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Abstract

The new molybdenum arsenate compound {Cu4(btp)4[(CuO6)(As3O3)2Mo6O18]}·2H2O (1) [btp = 1,3-bis(1,2,4-triazol-1-yl)propane] has been hydrothermally synthesized and characterized by routine physical methods. This compound crystallizes in the triclinic space group, a = 9.3345(4) Å, b = 13.0930(5) Å, c = 14.6444(6) Å, α = 100.94, β = 90.73, γ = 109.56, V = 1650.19(12) Å3, Z = 1. Interestingly, compound 1 exhibits 1D ladder-like chain in which [(CuO6)(As3O3)2Mo6O18]4− inorganic building block as “bullseye” is modified by tetra-nuclear CuI–btp loops. The luminescence property and the electrochemical behavior of compound 1 have been studied in detail.

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References

  1. P. Gouzerh, A. Proust, Chem. Rev. 98, 77 (1998)

    Article  CAS  Google Scholar 

  2. P. Gouzerh, R. Villanneau, R. Delmont, A. Proust, Chem. Eur. J. 6, 1184 (2000)

    Article  Google Scholar 

  3. M.T. Pope, A. Müller, Angew. Chem. Int. Ed. Engl. 30, 34 (1991)

    Article  Google Scholar 

  4. D.L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 36, 105 (2007)

    Article  CAS  Google Scholar 

  5. A. Müller, F. Reters, M.T. Pope, D. Gatteschi, Chem. Rev. 98, 239 (1998)

    Article  Google Scholar 

  6. J. Salta, Q. Chen, Y.D. Chang, J. Zubieta, Angew. Chem. Int. Ed. Engl. 33, 757 (1994)

    Article  Google Scholar 

  7. X.K. Fang, T.M. Anderson, W.A. Neiwert, C.L. Hill, Inorg. Chem. 42, 8600 (2003)

    Article  CAS  Google Scholar 

  8. K. Yu, Y.G. Li, B.B. Zhou, Z.H. Su, Z.F. Zhao, Y.N. Zhang, Eur. J. Inorg. Chem. 36, 5662 (2007)

    Article  Google Scholar 

  9. D. Hagrman, C. Zubieta, D.J. Rose, J. Zubieta, R.C. Haushalter, Angew. Chem. Int. Ed. Engl. 36, 873 (1997)

    Article  CAS  Google Scholar 

  10. P.J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed. 38, 2638 (1999)

    Article  CAS  Google Scholar 

  11. M. Bartholomä, S. Jones, J. Zubieta, Inorg. Chem. Commun. 14, 107 (2011)

    Article  Google Scholar 

  12. B. Liu, J. Yang, G. Yang, J. Ma, Inorg. Chem. 52, 84 (2013)

    Article  CAS  Google Scholar 

  13. B. Liu, Z.T. Yu, J. Yang, W. Hua, Y.Y. Liu, J.F. Ma, Inorg. Chem. 50, 8967 (2011)

    Article  CAS  Google Scholar 

  14. C. Sun, Y. Li, E. Wang, D. Xiao, H. An, L. Xu, Inorg. Chem. 46, 1563 (2007)

    Article  CAS  Google Scholar 

  15. K. Darling, E.M. Burkholder, S. Pellizzeri, M. Nanao, J. Zubieta, Inorg. Chem. Commun. 14, 1745 (2011)

    Article  CAS  Google Scholar 

  16. Z.H. Su, Z.F. Zhao, B.B. Zhou, Q.H. Cai, Q. Wang, Solid State Sci. 13, 417 (2011)

    Article  CAS  Google Scholar 

  17. H.Y. He, D. Collins, F.N. Dai, X.L. Zhao, G.Q. Zhang, H.Q. Ma, D.F. Sun, Cryst. Growth Des. 10, 895 (2010)

    Article  CAS  Google Scholar 

  18. K.L. Gurunatha, T.K. Maji, Inorg. Chem. 48, 10886 (2009)

    Article  CAS  Google Scholar 

  19. L. Tian, Z. Chen, A. Yu, H.B. Song, P. Cheng, CrystEngComm 14, 2032 (2012)

    Article  CAS  Google Scholar 

  20. M.V. Marinho, M.I. Yoshida, K.J. Guedes, K. Krambrock, A.J. Bortoluzzi, M. Horner, F.C. Machado, W.M. Teles, Inorg. Chem. 43, 1539 (2004)

    Article  CAS  Google Scholar 

  21. A.X. Tian, J. Ying, J. Peng, J.Q. Sha, Z.G. Han, J.F. Ma, Z.M. Su, N.H. Hu, H.Q. Jia, Inorg. Chem. 47, 3274 (2008)

    Article  CAS  Google Scholar 

  22. W.H. Zhang, Y.L. Song, Z.H. Wei, L.L. Li, Y.J. Huang, Y. Zhang, J.P. Lang, Inorg. Chem. 47, 5332 (2008)

    Article  CAS  Google Scholar 

  23. X.Q. Liang, D.P. Li, X.H. Zhou, Y. Sui, Y.Z. Li, J.L. Zuo, X.Z. You, Cryst. Growth Des. 9, 4872 (2009)

    Article  CAS  Google Scholar 

  24. L. Tian, Z.J. Zhang, A. Yu, W. Shi, Z. Chen, P. Cheng, Cryst. Growth Des. 10, 3847 (2010)

    Article  CAS  Google Scholar 

  25. G.M. Sheldrick, SHELXS-97, program for crystal structure solution (University of Göttingen, Germany, 1997)

    Google Scholar 

  26. G.M. Sheldrick, SHELXL-97, program for crystal structure refinement (University of Göttingen, Germany, 1997)

    Google Scholar 

  27. I.D. Brown, D. Altermatt, Acta Crystallogr. B 41, 244 (1985)

    Article  Google Scholar 

  28. Y.E. Liu, K. Yu, J.H. Wang, Z.H. Su, B.B. Zhou, Q. Wang, J. Inorg. Organomet. Polym. 24, 759 (2014)

    Article  Google Scholar 

  29. J.Q. Sha, J. Peng, H.S. Liu, J. Chen, B.X. Dong, A.X. Tian, Z.M. Su, Eur. J. Inorg. Chem. 9, 1268 (2007)

    Article  Google Scholar 

  30. F.Y. Su, B.B. Zhou, Z.F. Zhao, Z.H. Su, C.C. Zhu, Cryst. Res. Technol. 44, 447 (2009)

    Article  CAS  Google Scholar 

  31. J.Y. Niu, J.P. Wang, Introduction of heteropoly compound (Henan University Press, Kaifeng, 2000)

    Google Scholar 

  32. W. Feng, R.N. Chang, J.Y. Wang, E.C. Yang, X.J. Zhao, J. Coord. Chem. 63, 250 (2010)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported the Natural Science Foundation of Heilongjiang Province (No. B201306), the National Natural Science Foundation of China (Grants Nos. 21271056 and 21371042), the Science and Technology Project of Education Office of Heilongjiang Province (No. 12531182).

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Authors and Affiliations

  1. Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Harbin Normal University, No. 1 South of Shida Road Limin Development Zone, Harbin, 150025, Heilongjiang Province, China

    Wenqi Zhao, Zhanhua Su, Bowen Cong, Lin Xia & Baibin Zhou

  2. Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, 150025, China

    Wenqi Zhao, Zhanhua Su, Bowen Cong, Lin Xia & Baibin Zhou

  3. College of Material Science and Engineering, University of Science and Technology Heilongjiang, Harbin, 150022, China

    Zhifeng Zhao

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  1. Wenqi Zhao
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  2. Zhanhua Su
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  3. Zhifeng Zhao
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Correspondence to Zhanhua Su or Baibin Zhou.

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Zhao, W., Su, Z., Zhao, Z. et al. Polynuclear Loop-Modified Molybdenum Arsenate: Synthesis, Structure and Property. J Inorg Organomet Polym 25, 1373–1379 (2015). https://doi.org/10.1007/s10904-015-0249-7

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  • DOI: https://doi.org/10.1007/s10904-015-0249-7

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