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Synthesis of an Organic–Inorganic Alq3-Based Hybrid Material by Sol–Gel Method

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Abstract

A novel solution processable tris(8-hydroxyquinolinato)aluminum (Alq3)-containing organic inorganic hybrid material was synthesized from 8-hydroxyquinoline-5-sulfonic acid and alkoxysilane precursors using a sol–gel method. By this functionalization, Alq3 could be easily deposited on a glass substrate with spin coating deposition method, the structure of which was characterized by nuclear magnetic resonance (1H NMR), Fourier transform infra red spectroscopy, differential scanning calorimetry, scanning electron microscopy and photoluminescence studies. The new hybrid material contained a siloxane network attached to the phenoxide ring showed excitation and emission spectra near the characteristic emission of Alq3 with a little blue shift.

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Authors and Affiliations

  1. Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, PO Box 15875-4413, Tehran, Iran

    Sina Modiri & Mohsen Mohseni

  2. Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113, Tehran, Iran

    Ezzedin Mohajerani

  3. Department of Chemistry, Amirkabir University of Technology, PO Box 15875-4413, Tehran, Iran

    Elaheh Kowsari

Authors
  1. Sina Modiri
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  2. Mohsen Mohseni
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  3. Ezzedin Mohajerani
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  4. Elaheh Kowsari
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Corresponding author

Correspondence to Mohsen Mohseni.

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Modiri, S., Mohseni, M., Mohajerani, E. et al. Synthesis of an Organic–Inorganic Alq3-Based Hybrid Material by Sol–Gel Method. J Inorg Organomet Polym 25, 680–686 (2015). https://doi.org/10.1007/s10904-014-0142-9

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  • DOI: https://doi.org/10.1007/s10904-014-0142-9

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