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Mixed Solvothermal Synthesis of a New Heterometallic Coordination Polymer Containing Two Distinct Inorganic Cd–O–Ca Chains

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Abstract

A new heterometallic coordination polymer, namely [Cd2Ca2(PBDC)(H2O)2(e-urea)(DMF)]n·2n(DMF) (1 H2PBDC = terephthalic acid, DMF = N,N-dimethylformamide, e-urea = ethyleneurea) has been synthesized by combining the PBDC ligand with Cd(II) and Ca(II) salts under mixed solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 is an extended three-dimensional framework containing two distinct inorganic Cd–O–Ca chains, and can be simplified into a 4-connected topological network based on three unequivalent nodes. Luminescent study reveals that 1 exhibits strong, ligand-centred luminescence in the solid-state at room temperature.

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Acknowledgments

This work was supported by Grants of the National Natural Science Foundation of China (No. 21107076).

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Authors and Affiliations

  1. College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142, China

    Ying Zhang

  2. School of Mechanical Engineering, Shenyang University of Chemical Technology, Shenyang, 110142, China

    Kai Chen

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  1. Ying Zhang
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  2. Kai Chen
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Correspondence to Kai Chen.

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Zhang, Y., Chen, K. Mixed Solvothermal Synthesis of a New Heterometallic Coordination Polymer Containing Two Distinct Inorganic Cd–O–Ca Chains. J Inorg Organomet Polym 23, 1049–1053 (2013). https://doi.org/10.1007/s10904-013-9884-z

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  • DOI: https://doi.org/10.1007/s10904-013-9884-z

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