Skip to main content
SpringerLink
Log in

Two Lanthanide-Based Metal–Organic Frameworks with Flexible Alicyclic Carboxylate Ligands: Synthesis, Crystal Structures, and Near-Infrared Luminescence Property

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Two lanthanide-based metal–organic frameworks with flexible alicyclic carboxylate ligands, generally formulated as [Sm(TMG)(HTMG)(H2O)] (1) and [Nd2(CHDC)3(H2O)] (2), have been successfully synthesized and characterized. They represent the first example of lanthanide-TMG and lanthanide-CHDC systems. Their structures range from 1D infinite chains to 2D extended layer structure. Complexes 2 exhibit strong fluorescent emissions in the near-infrared region at room temperature. Interestingly, the structural difference between compounds 1 and 2 indicates the pH values have subtle influence on the coordination modes of ligands and dimension of LMOFs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. M. Eddaoudi, D.B. Moler, H.L. Li, B.L. Chen, T.M. Reineke, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 34, 319 (2001)

    Article  CAS  Google Scholar 

  2. B. Moulton, M.J. Zaworotko, Chem. Rev. 101, 1629 (2001)

    Article  CAS  Google Scholar 

  3. O.M. Yaghi, M. O’Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature 423, 705 (2003)

    Article  CAS  Google Scholar 

  4. S. Kitagawa, R. Kitaura, S.I. Noro, Angew. Chem. Int. Ed. 43, 2334 (2004)

    Article  CAS  Google Scholar 

  5. D. Parker, Coord. Chem. Rev. 205, 109 (2000)

    Article  CAS  Google Scholar 

  6. J. Kido, Y. Okamoto, Chem. Rev. 102, 2357 (2002)

    Article  CAS  Google Scholar 

  7. C. Benelli, D. Gatteschi, Chem. Rev. 102, 2369 (2002)

    Article  CAS  Google Scholar 

  8. G. Adachi, N. Imanaka, S. Tamura, Chem. Rev. 102, 2405 (2002)

    Article  CAS  Google Scholar 

  9. J.-C.G. Bünzli, Acc. Chem. Res. 39, 53 (2006)

    Article  Google Scholar 

  10. C.L. Cahill, D.T. de Lill, M. Frisch, CrystEngComm 9, 15 (2007)

    Article  CAS  Google Scholar 

  11. K. Binnemans, Chem. Rev. 109, 4283 (2009)

    Article  CAS  Google Scholar 

  12. L. Pan, E.B. Woodlock, X.T. Wang, C. Zheng, Inorg. Chem. 39, 4174 (2000)

    Article  CAS  Google Scholar 

  13. Y. J. Kim, D.-Y. Jung, Chem, Commun. 908 (2002)

  14. D. T. de Lill, C. L. Cahill, Chem. Commun. 4946 (2006)

  15. S. Surblé, C. Serre, F. Millange, F. Pellé, G. Férey, Solid State Sci. 9, 131 (2007)

    Article  Google Scholar 

  16. J. Lü, W.-H. Bi, F.-X. Xiao, S.R. Batten, R. Cao, Chem. Asian J. 3, 542 (2008)

    Article  Google Scholar 

  17. J. Lü, W.-H. Bi, R. Cao, CrystEngComm 11, 2248 (2009)

    Article  Google Scholar 

  18. X.-J. Zhao, G.S. Zhu, Q.R. Fang, Y. Wang, F.X. Sun, S.-L. Qiu, Cryst. Growth Des. 9, 2 (2009)

    Google Scholar 

  19. Y.-C. Ou, Z.-J. Lina, M.-L. Tong, CrystEngComm 12, 4020 (2010)

    Article  CAS  Google Scholar 

  20. J. Zhao, D.-S. Li, X.-J. Ke, B. Liu, K. Zou, H.-M. Hu, Dalton Trans. 41, 2560 (2012)

    Article  CAS  Google Scholar 

  21. H.-L. Sun, C.-H. Ye, X.-Y. Wang, J.-R. Li, S. Gao, K.-B. Yu, J. Mol. Struct. 702, 77 (2004)

    Article  CAS  Google Scholar 

  22. P.Q. Zheng, Y.P. Ren, L.S. Long, R.B. Huang, L.S. Zheng, Inorg. Chem. 44, 1190 (2005)

    Article  CAS  Google Scholar 

  23. Q. Yu, X.-Q. Zhang, H.-D. Bian, H. Liang, B. Zhao, S.-P. Yan, D.-Z. Liao, Cryst. Growth Des. 8, 1140 (2008)

    Article  CAS  Google Scholar 

  24. D. Sun, Z.-H. Wei, C.-F. Yang, D.-F. Wang, N. Zhang, R.-B. Huang, L.-S. Zheng, CrystEngComm 13, 1591 (2011)

    Article  CAS  Google Scholar 

  25. B. Liu, G.-P. Yang, Y–.Y. Wang, R.-T. Liu, L. Hou, Q.-Z. Shi, Inorg. Chim. Acta 367, 127 (2011)

    Article  CAS  Google Scholar 

  26. C.-J. Li, Y.-Q. Peng, S.-N. Wang, X–.X. Zhang, Y.-Z. Li, J.-M. Dou, D.-C. Li, J. Solid State Chem. 184, 1581 (2011)

    Article  CAS  Google Scholar 

  27. X.D. Zhu, J. Lü, X.J. Li, S.Y. Gao, G.L. Li, F.X. Xiao, R. Cao, Cryst. Growth Des. 8, 1897 (2008)

    Article  CAS  Google Scholar 

  28. O. Fabelo, J. Pasán, L. Canadillas-Delgado, F.S. Delgado, F. Lloret, M. Julve, C. Ruiz-Perez, Inorg. Chem. 48, 6086 (2009)

    Article  CAS  Google Scholar 

  29. F. Li, T.-H. Li, X.-J. Li, X. Li, Y.L. Wang, R. Cao, Cryst. Growth Des. 6, 1458 (2006)

    Article  CAS  Google Scholar 

  30. J.H. Nettleman, R.M. Supkowski, R.L. LaDuca, J. Solid State Chem. 183, 291 (2010)

    Article  CAS  Google Scholar 

  31. J.H. Nettleman, P.J. Szymanski, L.K. Sposato, R.L. LaDuca, Inorg. Chim. Acta 363, 225 (2010)

    Article  CAS  Google Scholar 

  32. CrystalClear, Version 1.35; Software User’s Guide for the Rigaku R-Axis and Mercury and Jupiter CCD Automated X-Ray Imaging System (Rigaku Molecular Structure Corporation, The Woodlands, 2002)

  33. SHELXTL Reference Manual, Version 5.10 (Siemens Analytical X-Ray Instruments Inc., Madison, 1994)

  34. J.-L. Song, J.-G. Mao, Chem. Eur. J. 11, 1417 (2005)

    Article  CAS  Google Scholar 

  35. Y.-F. Yuan, T. Cardinaels, K. Lunstroot, K.V. Hecke, L.V. Meervelt, C. Görller- Walrand, K. Binnemans, P. Nockemann, Inorg. Chem. 46, 5302 (2007)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported from NSF of China (21171003), NSF of Anhui Province (1208085QB44), NSF for Colleges and Universities in Anhui Province (KJ2010B012) and Scientific Research Foundation of Anhui Polytechnic University (2008YQQ010).

Author information

Authors and Affiliations

  1. College of Biological and Chemical Engineering, Anhui Polytechnic University, Wuhu, 241000, People’s Republic of China

    Xian-Dong Zhu & Zhi-Xi Hang

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, People’s Republic of China

    Jun Zhao, Jin-Run He & Yu-Ling Wang

Authors
  1. Xian-Dong Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhi-Xi Hang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jun Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jin-Run He
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu-Ling Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xian-Dong Zhu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhu, XD., Hang, ZX., Zhao, J. et al. Two Lanthanide-Based Metal–Organic Frameworks with Flexible Alicyclic Carboxylate Ligands: Synthesis, Crystal Structures, and Near-Infrared Luminescence Property. J Inorg Organomet Polym 22, 1087–1092 (2012). https://doi.org/10.1007/s10904-012-9688-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-012-9688-6

Keywords

Search

Navigation