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An Interesting Complex: [Cd(l -trp) (d-trp)] n

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Abstract

A novel coordination polymer [Cd(l-trp) (d-trp)] n (where l-trp and d-trp are l-tryptophan and d-tryptophan or (S)-2-amino-3-(3-indolyl)propionic acid and (R)-2-amino-3-(3-indolyl)propionic acid) was prepared by a solvent-thermal method and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The compound(monoclinic space group P2(1)/c with a = 19.759(2) Å, b = 5.2496(10) Å, c = 9.7594(16) Å, β = 97.2760(10)°, Z = 2) shows a two-dimensional plane structure. The crystallized coordination polymer has a centrosymmetric space group. Each Cd2+ ion coordinates with a pair of racemes, and the complex is a mesomer. Although l-trp was used, both l-trp and d-trp appear in the complex.

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References

  1. J Gao, Synthesis, Structure and Antimicrobial Activity Study on New Complexes Derived from Polyamine. Ph.D. Dissertation of Nanjing University of Science & Technology (2004)

  2. H.K. Liu, J.P. Liu, Chem. Sensors 15, 110 (1995)

    CAS  Google Scholar 

  3. E.L. Giroux, R.I. Henkin, Bioinorg. Chem. 2, 125 (1973)

    Article  CAS  Google Scholar 

  4. J. Hugues, P. Ryser, W.C. Shen, F.B. Merk, Life Sci. 22, 1253 (1978)

    Article  Google Scholar 

  5. M. Katoh, N. Mizutani, H. Keino, S. Kashiwamata, Toxicol. Appl. Pharmacol. 73, 97 (1984)

    Article  CAS  Google Scholar 

  6. J. Yuan, Chinese J. Spectro. Lab. 19, 393 (2002)

    CAS  Google Scholar 

  7. J. Yuan, H.M. Zhong, L.M. Fan, Yunnan Environ. Sci. 17, 15 (1998)

    Google Scholar 

  8. J. Yuan, C. Li, H.M. Zhong, A.R. Yang, H. Ma, J. Amino Acids 2, 6 (1993)

    Google Scholar 

  9. M.C. Capllonch, G.R. Angel, A. Terrón, M.C. Apella, E. Espinosa, E. Molins, J. Inorg. Biochem. 85, 173 (2001)

    Article  CAS  Google Scholar 

  10. S. Kuriyama, Y. Inomata, Y. Arai, F.S. Howell, J. Inorg. Biochem. 100, 1299 (2006)

    Article  CAS  Google Scholar 

  11. Y. Inomata, Y. Arai, T. Yamakoshi, F.S. Howell, J. Inorg. Biochem. 98, 2149 (2004)

    Article  CAS  Google Scholar 

  12. K.Y. Choi, Y.M. Jeon, Inorg. Chem. Commun. 6, 1294 (2003)

    Article  CAS  Google Scholar 

  13. T. Kobayashi, Y. Inomata, T. Takeuchi, F.S. Howell, Inorganica Chim. Acta 258, 109 (1997)

    Article  CAS  Google Scholar 

  14. J. Yamada, Y. Inomata, T. Takeuchi, Inorganica Chim. Acta 249, 121 (1996)

    Article  CAS  Google Scholar 

  15. J.Y. Lu, M.A. Lawandy, J. Li, Inorg. Chem. 38, 2695 (1999)

    Article  CAS  Google Scholar 

  16. R.A. Ludise, A. Rabenau, Angew. Chem. Int. Ed. Engl. 24, 1026 (1985)

    Article  Google Scholar 

  17. J.Y. Lu, B.R. Cabrera, R.J. Wang, J. Li, Inorg. Chem. 37, 4480 (1998)

    Article  CAS  Google Scholar 

  18. B.R. Cabrera, J. Li, T. Yuen, Solid State Chem. Inorg. Mater. II, Mater. Res. Soc. Symp. Proc. 547, 493 (1999)

    CAS  Google Scholar 

  19. S. Jeon, P.V. Braun, Chem. Mater. 15, 1256 (2003)

    Article  CAS  Google Scholar 

  20. G.M. Sheldrick, SHELXTL-97 (Univ. of Göttingen, Germany, 1997)

  21. G.M. Sheldrick, SHELXTL V5.1 (1997)

  22. A.X.S. Bruker, Inc., Madison, Wisconsin, USA. Siemens. SMART and SAINT. Area Detector Control and Integration Software (1996)

  23. S.H. Feng, J. Anhui Normal Univ. (Natural Science). 23, 149 (2000)

  24. B.Y. Fang, D.Y. Feng, Chem. Res. Appl. l9, 40 (1997)

    Google Scholar 

  25. P.M. Masters, M. Friedman, J. Agric. Food. Chem. 27, 507 (1979)

    Article  CAS  Google Scholar 

  26. L. Wendie, L. Jenkins, T. Raul, E.S. Daniel, L.Remy, J. C.Kenneth, J. Agric. Food. Chem. 32, 1035 (1984)

    Article  Google Scholar 

  27. L. Remy, F.H. Richard, J. Agric. Food. Chem. 31, 432 (1983)

    Article  Google Scholar 

  28. C.T. Yang, M. Vetrichelvan, X.D. Yang, B. Moubaraki, K.S. Murray, J.J. Vittal, Dalton Trans. 113–121 (2004)

  29. H. Masuda, O. Matsumoto, A. Odani, O. Yamauchi. J. Chem. Soc. Jpn. 783 (1988)

  30. A. Garcia-Raso, J.J. Fiol, F. Badenas, E. Lago, E. Molins, Polyhedron. 20, 2877 (2001)

    Article  CAS  Google Scholar 

  31. Y. Xie, H.H. Wu, G.P. Yong, Z.Y. Wang, Acta Cryst. E 62, 2089 (2006)

    Article  Google Scholar 

  32. J. Wang, X.Y. Xu, W.X. Ma, X.L. Hu, P.F. Shi, M.Y. Wang, L.D. Lu, X.J. Yang, X. Wang, Chin J Inorg Chem. 24, 1514 (2008)

    CAS  Google Scholar 

  33. J. Wang, X.Y. Xu, W.X. Ma, H. Zhao, L.D. Lu, X.J. Yang, X. Wang, J. Synth. Crystal 37, 1119 (2008)

    Google Scholar 

  34. J. Wang, X.Y. Xu, W.X. Ma, L.D. Lu, X.J. Yang, Acta Cryst. E 63, m2867 (2007)

    Article  Google Scholar 

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Authors and Affiliations

  1. Huaihai Institute of Technology, Jiangsu, 222005, People’s Republic of China

    Jian Wang, Xingyou Xu, Weixing Ma, Fujun Yin & Teng Guo

  2. Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing, 210094, People’s Republic of China

    Jian Wang, Xingyou Xu, Fujun Yin, Lude Lu, Xujie Yang & Xin Wang

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  1. Jian Wang
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Wang, J., Xu, X., Ma, W. et al. An Interesting Complex: [Cd(l -trp) (d-trp)] n . J Inorg Organomet Polym 19, 401–405 (2009). https://doi.org/10.1007/s10904-009-9279-3

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  • DOI: https://doi.org/10.1007/s10904-009-9279-3

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