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Fluorogenic Recognition of Zn2+, Al3+ and F− Ions by a New Multi-Analyte Chemosensor Based Bisphenol A-Quinoline

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Abstract

A new available multi-analyte fluorescent sensor based on a bisphenol A-quinoline conjugate (BFQ) was synthesized in two facile steps and was characterized systematically. BFQ exhibited an effectively selective and sensitive recognition toward Zn2+and Al3+ cations in EtOH-H2O (v/v = 9/1) over other cations and F− anion in CH3CN over other anions with remarkably enhanced fluorescent intensities. According to the quantum yield (Φ) measurements, BFQ-Zn2+, BFQ-Al3+ and BFQ-F− complexes showed 16, 22 and 30 times higher Φ values than BFQ, respectively. The complexation properties of BFQ with Zn2+, Al3+ and F− ions were also examined by 1H NMR titration experiments.

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Acknowledgement

We thank the Research Foundation of Selcuk University (SUBAP) for financial support of this work.

Compliance with Ethical Standards

We state compliance with ethical standards of the present study, below.

Funding

This study was funded by SUBAP.

Conflict of Interest

We declare that they have no conflict of interest.

Research involving Human Participants and/or Animals

This study does not contain any studies with human participants performed by any of the authors.

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For this study, any informed consent form was not obtained.

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Authors and Affiliations

  1. Science Faculty, Department of Chemistry, Selcuk University, Konya, 42031, Turkey

    Serkan Erdemir, Ozcan Kocyigit & Sait Malkondu

Authors
  1. Serkan Erdemir
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  2. Ozcan Kocyigit
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  3. Sait Malkondu
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Corresponding author

Correspondence to Serkan Erdemir.

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Erdemir, S., Kocyigit, O. & Malkondu, S. Fluorogenic Recognition of Zn2+, Al3+ and F− Ions by a New Multi-Analyte Chemosensor Based Bisphenol A-Quinoline. J Fluoresc 25, 719–727 (2015). https://doi.org/10.1007/s10895-015-1557-6

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  • DOI: https://doi.org/10.1007/s10895-015-1557-6

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