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Spectroscopic and Computational Study of a Naphthalene Derivative as Colorimetric and Fluorescent Sensor for Bioactive Anions

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Abstract

The anion recognition property of a naphthalene based receptor (L) was investigated by naked-eye, UV-Vis, fluorescence, 1H NMR and computational methods. The receptor L showed fluoride selective naked-eye detectable colorimetric and UV-Vis spectral changes over other tested anions due to the formation of hydrogen bonding complex in 1:1 stoichiometry and/or deprotonation between fluoride and the receptor. Interestingly, the fluorescence of L was quenched by fluoride but enhanced by acetate.

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Acknowledgment

This work was made possible by a grant from the DST, New Delhi under Fast Track Young Scientist Scheme.

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Authors and Affiliations

  1. Department of Applied Chemistry, S.V. National Institute of Technology (SVNIT), Surat, Gujrat, India

    Darshna Sharma & Suban K. Sahoo

  2. Department of Chemistry, Sant Longowal Institute of Engineering & Technology (SLIET), Longowal, Punjab, India

    Rati Kanta Bera

  3. Department of Chemistry, Kurukshetra University, Kurukshetra, Haryana, India

    Raj Kamal

Authors
  1. Darshna Sharma
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  2. Suban K. Sahoo
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  3. Rati Kanta Bera
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  4. Raj Kamal
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Correspondence to Suban K. Sahoo.

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Sharma, D., Sahoo, S.K., Bera, R.K. et al. Spectroscopic and Computational Study of a Naphthalene Derivative as Colorimetric and Fluorescent Sensor for Bioactive Anions. J Fluoresc 23, 387–392 (2013). https://doi.org/10.1007/s10895-013-1178-x

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  • DOI: https://doi.org/10.1007/s10895-013-1178-x

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