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Ratiometric and Selective Fluorescent Sensor for F− Based on Intramolecular Charge Transfer (ICT)

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Abstract

A simple colorimetric and ratiometric fluorescent anion sensor 1, was rationally designed and synthesized by facile one-step condensation on basis of the mechanism of intramolecular charge transfer (ICT). The sensor 1 shows more highly and selectively ability to F− that induced the color changes from little yellow to purple, absorption-transferred to long wavelength and emission-transferred to short wavelength. Accordingly, 1H NMR analysis reveals that the F−-induced colorimetric and fluorometric responses of 1 are simply driven by hydrogen bonding interaction between the NH protons and F− ions.

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Acknowledgments

This project was supported by the National Natural Science Foundation of China (20371028, 20671052).

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, People’s Republic of China

    Yaping Li & Huakuan Lin

  2. Key Laboratory of Functional Polymer Materials of Ministry of Education, Nankai University, Tianjin, 300071, People’s Republic of China

    Hai Lin

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  1. Yaping Li
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  2. Hai Lin
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  3. Huakuan Lin
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Correspondence to Huakuan Lin.

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Li, Y., Lin, H. & Lin, H. Ratiometric and Selective Fluorescent Sensor for F− Based on Intramolecular Charge Transfer (ICT). J Fluoresc 20, 1299–1305 (2010). https://doi.org/10.1007/s10895-010-0681-6

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  • DOI: https://doi.org/10.1007/s10895-010-0681-6

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