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Two New Borates Made of [B5O6(OH)4]− and [B5O10(OH)]6− Clusters, Accompanying a Novel In Situ Organic Reaction

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Abstract

Two new pentaborate clusters, [MPD][B5O6(OH)4] (1, MPD = 2-methyl-1,4,5,6-tetrahydropyrimidine-3-ium) and SrB5O8(OH) H2O (2), have been hydro(solvo)thermally synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P21/c, a = 9.3384(3) Å, b = 17.3774(5) Å, c = 9.1886(3) Å, β = 93.172(3)°, Z = 4. Crystal data for 2: triclinic, P-1, a = 6.6406(6) Å, b = 6.6784(8) Å, c = 10.2162(15) Å, α = 98.905(11)°, β = 92.237(9)°, γ = 119.446(11)°, Z = 2. In compound 1, all the terminal O atoms of [B5O6(OH)4]− clusters are hydroxyl groups, which hinder the further connection of the [B5O6(OH)4]− clusters, only forming 3-D supramolecular frameworks via extensive hydrogen-bonding interactions. In compound 2, the [B5O10(OH)]6− clusters link each other to form a 2-D layer, which are further extended to 3-D supramolecular frameworks via extensive hydrogen-bonding interactions. Interestingly, a novel in situ organic reaction between 1,3-diaminoprapane and CH3COO− group has been observed during the formation of compound 1.

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Acknowledgments

This work was supported by the NSFC (Nos. 21201017, 91122028 and 50872133), the NSFC of Distinguished Young Scholars (No. 20725101), and the 973 Program (No. 2014CB932101).

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Authors and Affiliations

  1. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

    Guang Huang, Rui Pan, Huan He, Bai-Feng Yang & Guo-Yu Yang

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  1. Guang Huang
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  2. Rui Pan
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  3. Huan He
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Correspondence to Guo-Yu Yang.

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Huang, G., Pan, R., He, H. et al. Two New Borates Made of [B5O6(OH)4]− and [B5O10(OH)]6− Clusters, Accompanying a Novel In Situ Organic Reaction. J Clust Sci 26, 2023–2032 (2015). https://doi.org/10.1007/s10876-015-0900-z

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