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Two Novel Heterothiometallic Clusters Modified by 1,1′-Bis(diphenylphosphino) ferrocene (dppf) in Quasi-Closed Bridging Mode: Syntheses, Structures and Properties

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Abstract

Two heterothiometallic clusters modified by 1,1′-bis(diphenylphosphino) ferrocene (dppf) ligand [(Ag4Mo2S8)(dppf)2] (1) and [(Ag4Mo2S6O2)(dppf)2] (2) have been synthesized and characterized. X-ray single-crystal studies reveal that the structures of the two clusters are both hexagonal prism-shaped cages, which are modified by dppf ligands in rarely quasi-closed mode. While, the terminal atoms of the hexagonal prism cages are different, S atoms for 1 and O atoms for 2. The discrete clusters of 1 and 2 are connected to form 2-D supramolecular layers through hydrogen bonds C–H···S, C–H···π for 1 and C–H···O for 2. The different supramolecular interactions may be caused by the different terminal atoms, which also result in different fluorescence emissions and oxidation potentials.

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References

  1. A. Fihri, P. Meunier, and J.-C. Hierso (2007). Coord. Chem. Rev. 251, 2017.

    Article  CAS  Google Scholar 

  2. D. R. van Staveren and N. Metzler-Nolte (2004). Chem. Rev. 104, 5931.

    Article  Google Scholar 

  3. T. J. Colacot (2003). Chem. Rev. 103, 3101.

    Article  CAS  Google Scholar 

  4. S. Y. Ng, G. Fang, W. K. Leong, L. Y. Goh, and M. V. Garland (2007). Eur. J. Inorg. Chem. 452.

  5. L.-C. Song, Z.-Y. Yang, H.-Z. Bian, Y. Liu, H.-T. Wang, X.-F. Liu, and Q.-M. Hu (2005). Organometallics 24, 6126.

    Article  CAS  Google Scholar 

  6. C. Bianchini, W. Oberhauser, A. Orlandini, C. Giannelli, and P. Frediani (2005). Organometallics 24, 3692.

    Article  CAS  Google Scholar 

  7. P. Teo, L. L. Koh, and T. S. Andy Hor (2007). Chem. Commun. 4221.

  8. L. M. Scolaro, M. R. Plutino, A. Romeo, R. Romeo, G. Ricciardi, S. Belviso, and A. Albinati (2006). Dalton Trans. 2551.

  9. J. Albers, V. Cadierno, P. Crochet, S. E. García-Garrido, and J. Gimeno (2007). J. Organomet. Chem. 692, 5234.

    Article  CAS  Google Scholar 

  10. S. Roy, B. Sarkar, D. Bubrin, M. Niemeyer, S. Zásiš, G. K. Lahiri, and W. Kaim (2008). J. Am. Chem. Soc. 130, 15230.

    Article  CAS  Google Scholar 

  11. A. Listorti, G. Accorsi, Y. Rio, N. Armaroli, O. Moudam, A. Gégout, B. Delavaux-Nicot, M. Holler, and J.-F. Nierengarten (2008). Inorg. Chem. 47, 6254.

    Article  CAS  Google Scholar 

  12. S. Roy, M. Sieger, P. Singh, M. Niemeyer, J. Fiedler, C. Duboc, and W. Kaim (2008). Inorg. Chim. Acta 361, 1699.

    Article  CAS  Google Scholar 

  13. T. S. A. Hor, L.-T. Phang, L.-K. Liu, and Y.-S. Wen (1990). J. Organomet. Chem. 397, 29.

    Article  CAS  Google Scholar 

  14. D. T. Hill, G. R. Girard, F. L. McCabe, R. K. Johnson, P. D. Stupik, J. H. Zhang, W. M. Reiff, and D. S. Eggleston (1989). Inorg. Chem. 28, 3529.

    Article  CAS  Google Scholar 

  15. S. T. Chacon, W. R. Cullen, M. I. Bruce, O. B. Shawkataly, F. W. B. Einstein, R. H. Jones, and A. C. Willis (1990). Can. J. Chem. 68, 2001.

    Article  CAS  Google Scholar 

  16. N. Armaroli, G. Accorsi, G. Bergamini, P. Ceroni, M. Holler, O. Moudam, C. Duhayon, B. Delavaux-Nicot, and J.-F. Nierengarten (2007). Inorg. Chim. Acta 360, 1032.

    Article  CAS  Google Scholar 

  17. P. Braunstein, D. Bubrin, and B. Sarkar (2009). Inorg. Chem. 48, 2534.

    Article  CAS  Google Scholar 

  18. Y.-C. Liu, C.-I. Li, W.-Y. Yeh, G.-H. Lee, and S.-M. Peng (2006). Inorg. Chim. Acta 359, 2361.

    Article  CAS  Google Scholar 

  19. X. L. Lu, S. Y. Ng, J. J. Vittal, G. K. Tan, L. Y. Goh, and T. S. Andy Hor (2003). J. Organomet. Chem. 688, 100.

    Article  CAS  Google Scholar 

  20. J. J. Fernández, N. Gómez-Blanco, A. Fernández, D. Vázquez-García, M. López-Torres, and J. M. Vila (2009). Polyhedron 28, 2679.

    Article  Google Scholar 

  21. M. W. Hooper and J. F. Hartwig (2003). Organometallics 22, 3394.

    Article  CAS  Google Scholar 

  22. Y. C. Neo, J. S. Lip Yeo, P. M. Neo Low, S. W. Chien, T. C. W. Mak, J. J. Vittal, and T. S. Andy Hor (2002). J. Organomet. Chem. 658, 159.

    Article  CAS  Google Scholar 

  23. X. L. Lu, W. K. Leong, L. Y. Goh, and A. T. S. Hor (2004). Eur. J. Inorg. Chem. 2504.

  24. D. R. Smyth, J. Hester, V. G. Y. Jrc, and E. R. T. Tiekink (2002). CrystEngComm 4, 517.

    Article  CAS  Google Scholar 

  25. V. Cadierno, P. Crochet, J. Díez, S. E. García-Garrido, and J. Gimeno (2003). Organometallics 22, 5226.

    Article  CAS  Google Scholar 

  26. S. Canales, O. Crespo, M. C. Gimeno, P. G. Jones, and A. Laguna (2004). Inorg. Chem. 43, 7234.

    Article  CAS  Google Scholar 

  27. A. M. Johns, M. Utsunomiya, C. D. Incarvito, and J. F. Hartwig (2006). J. Am. Chem. Soc. 128, 1828.

    Article  CAS  Google Scholar 

  28. W.-Y. Wong, G.-L. Lu, and K.-H. Choi (2002). J. Organomet. Chem. 659, 107.

    Article  CAS  Google Scholar 

  29. Y. C. Neo, J. J. Vittal, and T. S. Andy Hor (2002). J. Chem. Soc. Dalton Trans. 337.

  30. O. Crespo, F. Canales, M. C. Gimeno, P. G. Jones, and A. Laguna (1999). Organometallics 18, 3142.

    Article  CAS  Google Scholar 

  31. Y.-Y. Niu, T.-N. Chen, S.-X. Liu, Y.-L. Song, Y.-X. Wang, Z.-L. Xue, and X.-Q. Xin (2002). J. Chem. Soc. Dalton Trans. 1980.

  32. L. Song, S.-Q. Xia, S.-M. Hu, S.-W. Du, and X.-T. Wu (2005). Polyhedron 24, 831.

    Article  CAS  Google Scholar 

  33. Y. Cai, Y. Song, H. Zheng, Y. Niu, C. Du, and X. Xin (2002). Chem. Lett. 508.

  34. C. Zhang, Y. Song, and X. Wang (2007). Coord. Chem. Rev. 251, 111.

    Article  CAS  Google Scholar 

  35. Y. Han, Z. Zhang, Y. Liu, Y. Niu, D. Ding, B. Wu, H. Hou, and Y. Fan (2011). Cryst. Growth Des. 11, 3448.

    Article  CAS  Google Scholar 

  36. W. H. Zhang, J. P. Lang, Y. Zhang, and B. F. Abrahams (2008). Cryst. Growth Des. 8, 399.

    Article  CAS  Google Scholar 

  37. J. X. Chen, X. Y. Tang, Y. Chen, W. H. Zhang, L. L. Li, R. X. Yuan, Y. Zhang, and J. P. Lang (2009). Cryst. Growth Des. 9, 1461.

    Article  CAS  Google Scholar 

  38. Z. R. Pan, J. Xu, H. G. Zheng, K. X. Huang, Y. Z. Li, Z. J. Guo, and S. R. Batten (2009). Inorg. Chem. 48, 5772.

    Article  CAS  Google Scholar 

  39. Y. J. Huang, Y. L. Song, Y. Chen, H. X. Li, Y. Zhang, and J. P. Lang (2009). Dalton Trans. 1411.

  40. L. Song, J. R. Li, P. Lin, Z. H. Li, T. Li, S. W. Du, and X. T. Wu (2006). Inorg. Chem. 45, 10155.

    Article  CAS  Google Scholar 

  41. K. X. Huang, Y. L. Song, Z. R. Pan, Y. Z. Li, X. Zhuo, and H. G. Zheng (2007). Inorg. Chem. 46, 6233.

    Article  CAS  Google Scholar 

  42. W. H. Zhang, Y. L. Song, Z. G. Ren, H. X. Li, L. L. Li, Y. Zhang, and J. P. Lang (2007). Inorg. Chem. 46, 6647.

    Article  CAS  Google Scholar 

  43. K. Liang, H. G. Zheng, Y. L. Song, Y. Z. Li, and X. Q. Xin (2007). Cryst. Growth Des. 7, 373.

    Article  CAS  Google Scholar 

  44. Q. F. Xu, J. X. Chen, W. H. Zhang, Z. G. Ren, H. X. Li, Y. Zhang, and J. P. Lang (2006). Inorg. Chem. 45, 4055.

    Article  CAS  Google Scholar 

  45. Y. Y. Niu, B. L. Wu, X. L. Guo, Y. L. Song, X. C. Liu, H. Y. Zhang, H. W. Hou, C. Y. Niu, and S. W. Ng (2008). Cryst. Growth Des. 8, 2393.

    Article  CAS  Google Scholar 

  46. W.-Y. Wong, F.-L. Ting, and W.-L. Lam (2002). Eur. J. Inorg. Chem. 8, 2103.

    Article  Google Scholar 

  47. J. W. Mcdonald, G. D. Friesen, L. D. Rosenhein, and W. E. Newton (1983). Inorg. Chim. Acta 72, 205.

    Article  CAS  Google Scholar 

  48. B. Wu, W.-H. Zhang, H.-X. Li, Z.-G. Ren, J.-P. Lang, Y. Zhang, and Y.-L. Song (2007). J. Mol. Struct. 829, 128.

    Article  CAS  Google Scholar 

  49. A. Muller, H. Bögge, E. Königer-Ahlborn, and W. Hellmann (1979). Inorg. Chem. 18, 2301.

    Article  Google Scholar 

  50. G. Sakane, T. Shibahare, H. W. Hou, X. Q. Xin, and S. Shi (1995). Inorg. Chem. 34, 4785.

    Article  CAS  Google Scholar 

  51. T. S. Andy Hor, J. S. Ping Neo, C. S. Tan, T. C. W. Mak, K. W. P. Hung, and R.-J. Wangg (1992). Inorg. Chem. 31, 4510.

    Article  Google Scholar 

  52. S. Lanza, F. Loiseau, G. Tresoldi, S. Serroni, and S. Campagna (2007). Inorg. Chim. Acta 360, 1929.

    Article  CAS  Google Scholar 

  53. S.-K. Lee and D.-Y. Noh (2010). Inorg. Chem. Commun. 13, 183.

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of People’s Republic of China (No. 20971063, 21101086), Natural Science Foundation of Shandong Province (Y2007B01).

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, China

    Jing Lu, Cheng-Chen Zhu, Da-Cheng Li & Jian-Min Dou

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  1. Jing Lu
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  2. Cheng-Chen Zhu
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Correspondence to Jian-Min Dou.

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Lu, J., Zhu, CC., Li, DC. et al. Two Novel Heterothiometallic Clusters Modified by 1,1′-Bis(diphenylphosphino) ferrocene (dppf) in Quasi-Closed Bridging Mode: Syntheses, Structures and Properties. J Clust Sci 23, 545–555 (2012). https://doi.org/10.1007/s10876-012-0467-x

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