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Crystal Structures of Two Copper(I) Iodides: Chained [CuI(bta)] and Tetranuclear [(mdabco)2Cu4I6] (bta = Benzotriazole; mdabco = N-methyl-1,4-diazabicyclo[2,2,2]octane)

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Abstract

In methanol solutions, two types of organic N-donor ligands bta and dabco (bta = benzotriazole; dabco = 1,4-diazabicyclo[2,2,2]octane) were selected to react with CuI under the solvothermal conditions, creating two new copper(I) iodides as one-dimensional (1D) chained [CuI(bta)] 1 and tetranuclear [(mdabco)2Cu4I6] (mdabco = N-methyl-1,4-diazabicyclo[2,2,2]octane). Note that mdabco derived from the solvothermal in situ alkylation reaction between dabco and methanol solvent. The photoluminescence analysis revealed that compound 2 is a potential fluorescence material with maximum emission at 506 nm.

Graphical Abstract

The structural characterization of two new copper(I) iodides as chained [CuI(bta)] 1 and tetranuclear [(mdabco)2Cu4I6] (bta = benzotriazole; mdabco = N-methyl-1,4-diazabicyclo[2,2,2]octane) 2 were reported. Mdabco derived from the solvothermal in situ alkylation reaction between dabco and methanol solvent.

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Acknowledgment

This research was supported by the basic research foundation of Jilin University (No. 200903133).

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130023, Jilin, People’s Republic of China

    Xue-Jian Qu, Juan Jin, Jin-Jing Zhao, Jie-Hui Yu & Ji-Qing Xu

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, Jilin, People’s Republic of China

    Juan Jin, Jin-Jing Zhao, Jie-Hui Yu & Ji-Qing Xu

  3. College of Chemistry and Material Science, Shandong Agricultural University, Taian, 271018, Shandong, People’s Republic of China

    Qin Hou

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  1. Qin Hou
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  2. Xue-Jian Qu
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Correspondence to Jie-Hui Yu or Ji-Qing Xu.

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Hou, Q., Qu, XJ., Jin, J. et al. Crystal Structures of Two Copper(I) Iodides: Chained [CuI(bta)] and Tetranuclear [(mdabco)2Cu4I6] (bta = Benzotriazole; mdabco = N-methyl-1,4-diazabicyclo[2,2,2]octane). J Clust Sci 22, 715–722 (2011). https://doi.org/10.1007/s10876-011-0418-y

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  • DOI: https://doi.org/10.1007/s10876-011-0418-y

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