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Solvothermal Synthesis of a New Amine-Templated Vanadium Sulfate

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Abstract

A new organic-templated vanadium sulfate with formula [C4H12N2][VIII (OH)(SO4)2] · H2O 1 has been prepared under solvothermal conditions by using a mixture of glycol and water as solvent. The structure of this compound was characterized by IR, element analysis, TG and single crystal X-ray diffraction. The title compound crystallizes in the space group monoclinic, P21/c, a = 9.290(4) Å, b = 18.264(7) Å, c = 7.132(3) Å, β = 98.149(8)°,V = 1197.88 Å3, Z = 4. Structural analysis indicates that the title compound 1 possesses a 1D chain structure formed by VO6 octahedra and SO4 tetrahedra.

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Acknowledgment

We thank the National Natural Science Foundation of China (20771050) and Liaoning province (20062139) for financial support.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing, 210009, P.R. China

    Xiaochang Sun, Fan Zhang & Yan Xu

  2. Liaoning Key Laboratory of Bio-Organic Chemistry, Dalian University, Dalian, 116622, People’s Republic of China

    Xuefang Zheng

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  1. Xiaochang Sun
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  2. Fan Zhang
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  3. Yan Xu
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  4. Xuefang Zheng
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Correspondence to Yan Xu.

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Sun, X., Zhang, F., Xu, Y. et al. Solvothermal Synthesis of a New Amine-Templated Vanadium Sulfate. J Clust Sci 19, 481–489 (2008). https://doi.org/10.1007/s10876-008-0193-6

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