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Synthesis and Characterization of Organically Templated Copper Halides with Zero and One-dimensional Hybrid Structures: (nbq)4Cu4I8 and [(ipq)2(Cu5I7)] n

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Abstract

Two new organically templated copper halides, (nbq)4Cu4I8 (1) and [(ipq)2(Cu5I7)] n (2) have been synthesized in the presence of nbq+ and ibq+ (nbq+ = N-(n-butyl)-quinolinium, ibq+ = N-(iso-pentyl)-quinolinium) acting as structure-directing agents(SDAs). Both of the compounds present hybrid structures with SDAs and inorganic moieties being incorporated. In 1, tetrameric Cu4I8 4− anion is composed by edge-sharing CuI4 tetrahedrons and CuI3 planar triangles. But the inorganic framework of 2 presents one-dimensional arrangement which results from the tetrahedron CuI4 and pseudo trigonal pyramid CuI3 through edge-sharing fashion. Electrostatic interactions between organic counter cations and inorganic moieties could be observed and contribute to the crystal packing. Both compounds are further characterized by IR, UV–Vis, elemental analysis, fluorescence and cyclic voltammetry.

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Acknowledgments

We acknowledge support of this research by the Special Foundation for Young Scientists of Fuzhou Unviersity(XRC-0644), Sci & Tech Promotion Foundation of Fuzhou University (XJJ-0605), the Key Project of Fujian Province (2005HZ01 -2-6), Ph. D. Programs Foundation of Ministry of Education of China(20050386003), the National Natural Science Foundation of China (20273013), Natural Science Foundation of Fujian province (2002F010), Natural Science Found of Fujian Province (E0510004) Foundation of Education Committee of Fujian Province (JB06013).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350002, China

    Hao-Hong Li, Zhi-Rong Chen, Yuan Liu, Kai-Ning Ding, Jun-Qian Li, Chang-Cang Huang & Liang-Qia Guo

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, Fujian, 350002, P.R. China

    Jun-Qian Li

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  1. Hao-Hong Li
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  2. Zhi-Rong Chen
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  3. Yuan Liu
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Correspondence to Zhi-Rong Chen.

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Li, HH., Chen, ZR., Liu, Y. et al. Synthesis and Characterization of Organically Templated Copper Halides with Zero and One-dimensional Hybrid Structures: (nbq)4Cu4I8 and [(ipq)2(Cu5I7)] n . J Clust Sci 18, 817–829 (2007). https://doi.org/10.1007/s10876-007-0137-6

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