Abstract
Ambient concentrations of organic carbon (OC), elemental carbon (EC) and water soluble inorganic ionic components (WSIC) of PM10 were studied at Giridih, Jharkhand, a sub-urban site near the Indo Gangatic Plain (IGP) of India during two consecutive winter seasons (November 2011–February 2012 and November 2012–February 2013). The abundance of carbonaceous and water soluble inorganic species of PM10 was recorded at the study site of Giridih. During winter 2011–12, the average concentrations of PM10, OC, EC and WSIC were 180.2 ± 46.4; 37.2 ± 6.2; 15.2 ± 5.4 and 18.0 ± 5.1 μg m−3, respectively. Similar concentrations of PM10, OC, EC and WSIC were also recorded during winter 2012–13. In the present case, a positive linear trend is observed between OC and EC at sampling site of Giridih indicates the coal burning, as well as dispersed coal powder and vehicular emissions may be the source of carbonaceous aerosols. The principal components analysis (PCA) also identifies the contribution of coal burning + soil dust, vehicular emissions + biomass burning and seconday aerosol to PM10 mass concentration at the study site. Backward trajectoy and potential source contributing function (PSCF) analysis indicated that the aerosols being transported to Giridih from upwind IGP (Punjab, Haryana, Uttar Pradesh and Bihar) and surrounding region.
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Andreae, M.O., Crutzen, P.J.: Atmospheric Aerosols: Biogeochemical Sources and Role in Atmospheric Chemistry. Science. 276, 1052–1058 (1997)
Andreae, M.O., Merlet, P.: Emission of trace gases and aerosols from biomass burning. Glob. Biogeochem. Cycles. 15, 955–966 (2001)
Begum, B.A., Kim, E., Biswas, S.K., Hopke, P.K.: Investigation of sources of atmospheric aerosol at urban and semi-urban areas in Bangladesh. Atmos. Environ. 38, 3025–3038 (2005)
Bond, T.C., Bhardwaj, E., Dong, R., Jogani, R., Jung, S., Roden, C., Streets, D.G., Fernandes, S., Trautmann, N.: Historical emissions of black and organic carbon aerosol from energy-related combustion. Glob. Biogeochem. Cycles. 21, 1850–2000 (2007)
Bond, T.C., Doherty, S.J., Fahey, D.W., et al.: Bounding the role of black carbon in the climate system: a scientific assessment. J. Geophys. Res. Atmos. 118, 5380–5552 (2013)
Chow, J.C., Watson, J.G., Chen, L.W.A., Arnott, W.P., Moosmuller, H.: Equivalence of elemental carbon by thermal/optical reflectance and transmittance with different temperature protocols. Environ. Sci. Technol. 38, 4414–4422 (2004)
Dachs, J., Eisenreich, S.J.: Adsorption onto aerosol soot carbon dominates gas-particle partitioning of polycyclic aromatic hydrocarbons. Environ. Sci. Technol. 34, 3690–3697 (2000)
Draxler, R.R., Rolph, G.D.: HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory) model access via NOAA ARL READY website (http://www.arl.noaa.gov/ready/hysplit4.html). NOAA Air Resources Laboratory, Silver Spring (2003)
Ferek, R.J., Reid, J.S., Hobbs, P.V.: Emission factors of hydrocarbons, halocarbons, trace gases and particles from biomass burning in Brazil. J. Geophys. Res. 103(D24), 32107–32118 (1998)
Jain, S., Sharma, S.K., Mandal, T.K., & Saxena, M., (2017). Source apportionment of PM10 in Delhi, India using PCA/APCS, UNMIX and PMF. Particuology, https://doi.org/10.1016/j.partic.2017.05.009
Kulshrestha, U.C., Saxena, A., Kumar, N., Kumari, K.M., Srivastava, S.S.: Chemical composition and size differentiated aerosols at a suburban site in a semi-arid tract of India. J. Atmos. Chem. 29, 109–118 (1998)
Lawrence, M.G., Lelieveld, J.: Atmospheric pollutant outflow from southern Asia: a review. Atmos. Chem. Phys. 10, 11017–11096 (2010)
Li, X., Wang, S., Duan, L., Hao, J., Nie, Y.: Carbonaceous aerosol emissions from household biofuel combustion in China. Environ. Sci. Technol. 43, 6076–6081 (2009)
Mandal, P., Saud, T., Sarkar, R., Mandal, A., Sharma, S.K., Mandal, T.K., Bassin, J.K.: High seasonal variation of atmospheric C and particulate concentrations in Delhi, India. Environ. Chem. Lett. 12, 225–230 (2014)
Meng, Z.Y., Lin, W.L., Jiang, X.M., Yan, P., Wang, Y., Zhang, Y.M., Jia, X.F., Yu, X.L.: Characteristics of atmospheric ammonia over Beijing. China. Atmos. Chem. Phys. 11, 6139–6151 (2011)
Mkoma, S.L., Kawamura, K., Fu, P.Q.: Contributions of biomass/biofuel burning to organic aerosols and particulate matter in Tanzania, East Africa, based on analyses of ionic species, organic and elemental carbon, levoglucosan and mannosan. Atmos. Chem. Phys. 13, 10325–10338 (2013)
Parashar, D.C., Gadi, R., Mandal, T.K., Mitra, A.P.: Carbonaceous aerosol emissions from India. Atmos. Environ. 39, 7861–7871 (2005)
Perrino, C., Tiwari, S., Catrambone, M., Torre, S.D., Rantica, E., Canepari, S.: Chemical characterization of atmospheric PM in Delhi, India during defferent periods of the year including Diwali festival. Atmos. Pollut. Res. 2, 418–427 (2011)
Pope III, C.A., Ezzati, M., Dockery, D.W.: Fine-particulate air pollution and life expectancy in the United States. N. Engl. J. Med. 360(4), 376–386 (2009)
Ramgolam, K., Favez, O., Cachier, H., Gaudichet, A., Marano, F., Martinon, L., et al.: Size-partitioning of an urban aerosol to identify particle determinants involved in the proinflammatory response induced in airway epithelial cells. Part. Fibre Toxicol. 6(1), 10.1186/1743-8977-6-10 (2009)
Ram, K., Sarin, M.M.: Spatio-temporal variability in atmospheric abundances of EC, OC and WSOC over northern India. J. Aerosol Sci. 41(1), 88–98 (2010)
Ram, K., Sarin, M.M.: Day–night variability of EC, OC, WSOC and inorganic ions in urban environment of indo-Gangetic plain: implications to secondary aerosol formation. Atmos. Environ. 45, 460–468 (2011)
Ram, K., Sarin, M.M., Tripathi, S.N.: One-year record of carbonaceous aerosols from an urban location (Kanpur) in the indo-Gangetic plain: characterization, sources and temporal variability. J. Geophys. Res. (2010). https://doi.org/10.1029/2010JD014188
Ram, K., Sarin, M.M., Sudheer, A.K., Rengarajan, R.: Carbonaceous and secondary aerosols during wintertime fog and haze over urban sites in the indo-Gangetic plain. Aerosol Air Qual. Res. 12, 359–370 (2012)
Rengarajan, R., Sarin, M.M., Sudheer, A.K.: Carbonaceous and inorganic species in atmospheric aerosols during wintertime over urban and high-altitude sites in North India. J. Geophys. Res. 112, D21307 (2007)
Saarikoski, S., Timonen, H., Saarnio, K., et al.: Sources of organic carbon in fine particulate matter in northern European urban air. Atmos. Chem. Phys. 8, 6281–6295 (2008)
Salma, I., Chi, X.G., Maenhaut, W.: Elemental and organic carbon in urban canyon and background environments in Budapest, Hungary. Atmos. Environ. 38, 2517–2528 (2004)
Saxena, M., Sharma, A., Sen, A., Saxena, P., Saraswati, Mandal, T.K., Sharma, S.K.: Water soluble inorganic species of PM10 and PM2.5 at an urban site of Delhi, India: seasonal variability and sources. Atmos. Res. 184, 112–125 (2017)
Schwartz, J., Dockery, D.W., Neas, L.M.: Is daily mortality associated specifically with fine particle? JAPCA. 46, 927–939 (1996)
Sen, A., Ahammed, Y.N., Banerjee, T., Begam, G.R., Burah, B.P., Chatterjee, A., et al.: Atmospheric fine and coarse mode aerosols at different environments of India and the bay of Bengal during winter-2014: implication of a coordinated campaign. Mapan-J. Metrol. Soc. India. 29(4), 273–284 (2014)
Sharma, M., McBean, E.A., Ghosh, U.: Prediction of atmospheric sulphate deposition at sensitive receptors in northern India. Atmos. Environ. 29, 2157–2162 (1995)
Sharma, M., Kishore, S., Tripathi, S.N., Behra, S.N.: Role of atmospheric ammonia in the formation of inorganic secondary particulate matter: a study at Kanpur, India. J. Atmos. Chem. 58, 1–17 (2007)
Sharma, S.K., Singh, A.K., Saud, T., Mandal, T.K., Saxena, M., Singh, S., Ghosh, S., Raha, S.: Study on water soluble ionic composition of PM10 and trace gases over bay of Bengal during W_ICARB campaign. Meteorog. Atmos. Phys. 118, 37–51 (2012)
Sharma, S.K., Mandal, T.K., Saxena, M., Rashmi, Rohtash, Sharma, A., Gautam, R.: Source apportionment of PM10 by using positive matrix factorization at an urban site of Delhi, India. Urban Climate. 10, 656–670 (2014)
Sharma, S.K., Mandal, T.K.: Chemical composition of fine mode particulate matter (PM2.5) at an urban area of Delhi and its source apportionment. Urban Climate. 21, 106–122 (2017)
Sharma, S.K., Sharma, A., Saxena, M., Choudhary, N., Masiwal, R., Mandal, T.K., Sharma, C.: Chemical characterization and source apportionment of aerosol at an urban area of Central Delhi, India. Atmos. Pollut. Res. 7, 110–121 (2016)
Song, Y., Zhang, Y., Xie, S., Zeng, L., Zheng, M., Salmon, L.G., Shao, M., Slanina, S.: Source apportionment of PM2.5 in Beijing by positive matrix factorization. Atmos. Environ. 40(1), 526–1537 (2006)
Srinivas, B., Sarin, M.M.: PM2.5, EC and OC in atmospheric outflow from the Indo-Gangetic Plain: temporal variability and aerosol organic carbon-to-organic mass conversion factor. Sci. Total Environ. 487, 196–205 (2014)
Tare, V., Tripathi, S.N., Chinnam, N., Srivastava, A.K., Dey, S., Manar, M., Kanawade, V.P., Aggarwal, A., Kishore, L., Lal, R.B., Sharma, M.: Measurement of atmospheric parameters during Indian space research organization geosphere biosphere program land campaign II at a typical location in the Ganga Basin: 2. Chemical Properties. J. Geophys. Res. 111, D23210 (2006). https://doi.org/10.1029/2006/JD007279
Tiwari, S., Srivastava, A.K., Bisht, D.S., Bano, T., Singh, S., Behura, S., Srivastava, M.K., et al.: Black carbon and chemical characteristics of PM10 and PM2.5 at an urban site of North India. J. Atmos. Chem. 62, 193–209 (2009)
Tiwari, S., Pervez, S., Perrino, C., Bisht, D.S., Srivastava, A.K., Chate, D.M.: Chemical characterization of atmospheric particulate matter in Delhi, India, part II: source apportionment studies using PMF3.0. Sustain. Environ. Res. 23(5), 295–306 (2013)
Xu, Y., Bahadur, R., Zhao, C., RubyLeung, L.: Estimating the radiative forcing of carbonaceous aerosols over California based on satellite and ground observations. J. Geophys. Res.-Atmos. 118, 11–148 (2013)
Zhang, Q., Worsnop, D.R., Canangaratna, M.R., Jimenez, J.L.: Hydocarbon-like and ogygenated organic aerosols in Pittsburgh: Insights into sources and processes of organic aerosol. Atmos. Chem. Phys. 5, 3289–3311 (2005)
Acknowledgements
The authors are thankful to the Director, CSIR-NPL, New Delhi and Head, Environmental Sciences and Biomedical Metrology Division (ES&BMD), CSIR-NPL, New Delhi for their encouragement and support for this study. The authors also acknowledge Indian Statistical Institute, Kolkata for partial financial support for this study (ISI-Institutional Project). The authors are thankful to the anonymous reviewers and Editor for their constructive suggestions to improve the manuscript
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Sharma, S.K., Mandal, T.K., De, A.K. et al. Carbonaceous and inorganic species in PM10 during wintertime over Giridih, Jharkhand (India). J Atmos Chem 75, 219–233 (2018). https://doi.org/10.1007/s10874-017-9373-9
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DOI: https://doi.org/10.1007/s10874-017-9373-9