Skip to main content
SpringerLink
Log in

SYNTHESIS, CHARACTERIZATION, AND CRYSTAL STRUCTURE OF A NOVEL DECAVANADATE Mg(H2O)6(C6H14N2)2V10O28·8H2O

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

A novel decavanadate salt Mg(H2O)6(C6H14N2)2V10O28·8H2O is obtained by the reaction of vanadium oxide and 1,4-diazabicyclo [2.2.2] octane (DABCO). The title compound is characterized by infrared (IR) spectroscopy and powder X-ray diffraction (XRD). The spectroscopic characterization confirms the presence of the different groups in the structure. Powder XRD confirms the purity of the phase. Optical properties are recorded at room temperature using UV-Visible spectroscopy in the spectral range of 250-800 nm. According to the single crystal XRD analysis, the structure of the compound is orthorhombic: a = 17.927(6) Å, b = 15.798(6) Å, c = 15.723(5) Å, V = 4452.8(7) Å3, and Z = 4. The formula unit of Mg(H2O)6(C6H14N2)2V10O288H2O is formed by a decavanadate group, the \(\text{Mg(}{{\text{H}}_{2}}\text{O)}_{6}^{2+}\) polyhedron, two organic (C6H14N2)2+ cations, and eight water molecules. In the crystal, molecules are linked by O–H…O and N–H…O hydrogen bonds, forming a three-dimensional network.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

REFERENCES

  1. Q. Wei and L. Wu. Polym. Int., 2009, 58, 1217.

    Article  CAS  Google Scholar 

  2. T. Yamase. J. Mater. Chem., 2005, 15, 4773.

    Article  Google Scholar 

  3. L. Klištincová, E. Rakovsky, and P. Schwendt. Inorg. Chem. Commun., 2008, 1, 1140.

  4. E. M. Villa, C. A. Ohlin, E. Balogh, T. M. Anderson, M. D. Nyman, and W. H. Casey. Angew. Chem., Int. Ed., 2008, 47, 4844.

    Article  CAS  Google Scholar 

  5. A. K. Srivastava and J. L. Chiasson. Mol. Cell. Biochem., 1995, 153, 5.

    Article  CAS  Google Scholar 

  6. J. C. Pessoa, S. Etcheverry, and D. Gambino. Coord. Chem. Rev., 2015, 301, 24.

    Article  CAS  Google Scholar 

  7. D. C. Crans. J. Org. Chem., 2015, 80, 11899.

    Article  CAS  PubMed  Google Scholar 

  8. D. Rehder. Future Med. Chem., 2012, 4, 1823-1837.

    Article  CAS  PubMed  Google Scholar 

  9. D. Rehder. J. Inorg. Biochem., 2015, 147, 25.

    Article  CAS  PubMed  Google Scholar 

  10. D. Rehder. Metallomics, 2015, 7, 730.

    Article  CAS  PubMed  Google Scholar 

  11. E. S. Lara, S. Treviño, L. B. S. Gaytán, E. S. Mora, M. E. Castro, F. J. M. Bustamante, M. A. M. Rojas, and E. G. Vergara. Front. Chem., 2018, 6, 402.

  12. M. Aureliano. World J. Biol. Chem., 2011, 26, 215.

    Article  PubMed  PubMed Central  Google Scholar 

  13. M. Aureliano. Dalton Trans., 2009, 42, 9093.

    Article  PubMed  Google Scholar 

  14. J. M. Missina, B. Gavinho, K. Postal, F. S. Santana, G. Valdameri, E. M. Souza, D. L. Hughes, M. I. Ramirez, J. F. Soares, and G. G. Nunes. Inorg. Chem., 2018, 57, 11930.

    Article  CAS  PubMed  Google Scholar 

  15. T. L. Turner, V. H. Nguyen, C. C. McLauchlan, Z. Dymon, B. M. Dorsey, J. D. Hooker, and M. A. Jones. J. Inorg. Biochem., 2012, 108, 96.

    Article  CAS  PubMed  Google Scholar 

  16. R. Ksiksi, M. Graia, and T. Jouini. Acta Crystallogr., Sect. E, 2004, 60, 105.

    Article  CAS  Google Scholar 

  17. L. Klištincová, E. Rakovsky, and P. Schwendt. Inorg. Chem. Commun., 2008, 11, 1140.

  18. M. Cheng, N. Li, N. Wang, K. Hu, Z. Xiao, P. Wu, and Y. Wei. Polyhedron, 2018, 155, 313.

    Article  CAS  Google Scholar 

  19. R. Ksiksi, M. Graia, and T. Jouini. Acta Crystallogr., Sect. E, 2015, 61, 177.

  20. K. Harms and S. Wocadlo. XCAD4. University of Marburg: Germany, 1995.

  21. G. M. Sheldrick. SHELXS-97: Program for the Solution of Crystal Structures. University of Gottingen: Gottingen, Germany, 1997.

  22. G. M. Sheldrick. SHELXL-97: Program for the Refinement of Crystal Structures. University of Gottingen: Gottingen, Germany, 1997.

  23. K. Brandenburg. DIAMOND, Version 2.1e. Crystal Impact GbR: Bonn, Germany, 2001.

  24. N. Zhen, K. Wu, Q. Li, S.-L. Pan, W.-H. Gao, and Z.-H. Yang. New J. Chem., 2015, 39, 8866.

    Article  CAS  Google Scholar 

  25. S. Y. Luo, X. L. Wu, Q. P. Hu, J. X. Wang, C. Z. Liu, and Y. Y. Sun. J. Struct. Chem., 2012, 53, 915.

    Article  CAS  Google Scholar 

  26. I. D. Brown. Acta Crystallogr., Sect. A, 1976, 32, 24-31.

    Article  Google Scholar 

  27. I. Nagazi and A. Haddad. J. Clust. Sci., 2014, 25, 627.

    Article  CAS  Google Scholar 

  28. F. Hmida, M. Ayed, B. Ayed, and A. Haddad. J. Chem. Sci., 2015, 127, 1645-1651.

    Article  CAS  Google Scholar 

  29. B. H. Toby. J. Appl. Crystallogr., 2001, 34, 210.

    Article  CAS  Google Scholar 

  30. J. Tauc. Mater. Res. Bull., 1968, 3, 37.

    Article  CAS  Google Scholar 

  31. D. Abdelkader, A. Jebali, A. Larbi, A. Harizi, M. Ben Rabeh, N. Khemiri, F. Antoni, and M. Kanzari. Adv. Power Technol., 2016, 27, 734.

    Article  CAS  Google Scholar 

  32. I. Jendoubi, R. B. Smail, M. Maczka, and M. F. Zid. Ionics, 2018, 24, 1.

    Article  CAS  Google Scholar 

Download references

Funding

We would like to thank the Tunisian Ministry of Higher Education and Scientific Research for the financial support of this work. This work is carried out as part of a Federated Research Project (PRF) under the code PRF2019-D3P2.

Author information

Authors and Affiliations

  1. University of Tunis El Manar, Faculty of Sciences of Tunis, Laboratory of Materials, Crystal Chemistry and Applied Thermodynamics, El Manar II, Tunis, Tunisia

    R. Ksiksi, I. Jendoubi, H. Chebbi & M. F. Zid

  2. University of Carthage, High Institute of Preparatory Studies in Biology and Geology (ISEP-BG) of Soukra, Tunis, Tunisia

    R. Ksiksi

  3. University of Tunis, Preparatory Institute for Engineering Studies of Tunis, Montfleury, Tunis, Tunisia

    H. Chebbi

  4. Solid State Laboratory, Faculty of Sciences, University of Sfax, Sfax, Tunis, Tunisia

    M. Graia

Authors
  1. R. Ksiksi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. Jendoubi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Chebbi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Graia
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. F. Zid
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. Ksiksi.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 8, pp. 1331-1338.https://doi.org/10.26902/JSC_id78500

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ksiksi, R., Jendoubi, I., Chebbi, H. et al. SYNTHESIS, CHARACTERIZATION, AND CRYSTAL STRUCTURE OF A NOVEL DECAVANADATE Mg(H2O)6(C6H14N2)2V10O28·8H2O. J Struct Chem 62, 1243–1250 (2021). https://doi.org/10.1134/S0022476621080102

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476621080102

Keywords

Search

Navigation