Abstract
Bi5Yb3O12 (BYO) ceramic was synthesized utilizing a cost-effective chemical route method. XRD analysis as well as Le-Bail fitting was positively confirmed the single phase formation of BYO ceramic with cubic crystal system belonging to the space group of F m -3m. XPS analysis verified the correct oxidation states of various elements. Elemental composition was determined using EDS. The dielectric constant of BYO ceramic reached its peak at 337, measured at 382 K and 1 kHz. In contrast, its lowest recorded value was 238 at 523 K and 1 kHz. The tangent loss value of the BYO ceramic was noted as 0.2 at 293 K and 1 kHz, and 0.37 at 293 K and 1 MHz.
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M.A. Peña, J.L.G. Fierro, Chemical structures and performance of perovskite oxides. Chem. Rev. 101(7), 1981–2018 (2001)
E. Swatsitang, A. Niyompan, T. Putjuso, Giant dielectric, low dielectric loss and non-ohmic properties of nanocrystalline CaCu3Ti4O12. J. Mater. Sci. Mater. Electron. 24, 3514–3520 (2013)
V. Brizé, G. Gruener, J. Wolfman, K. Fatyeyeva, M. Tabellout, M. Gervais, F. Gervais, Grainsize effects on the dielectric constant of CaCu3Ti4O12 ceramics. Mater. Sci. Eng. B 129, 135–138 (2006)
S. Jesurani, S. Kanagesan, R. Velmurugan, C. Thirupathi, M. Sivakumar, T. Kalaivani, Nanoparticles of the giant dielectric material, calcium copper titanate from a sol–gel technique. Mater. Lett. 65, 3305–3308 (2011)
F. Luo, J. He, J. Hu, Y.H. Lin, Electric and dielectric behaviors of Y-doped calcium copper titanate. J. Am. Ceram. Soc. 93, 3043–3045 (2010)
H. Ma, A. Narayanaswamy, P. Riley, L. Li, Evolving symbolic density functionals. Sci. Adv. 8, 36 (2022)
P. Kanhere, Z. Chen, A review on visible light active perovskite-based photocatalysts. Molecules 19, 19995–20022 (2014)
M.A. Subramanian, A.W. Sleight, ACu3Ti4O12 and ACu3Ru4O12 perovskites: high dielectric constants and valence degeneracy. Solid State Sci. 4, 347–351 (2002)
R.N.P. Choudhary, U. Bhunia, Structural, dielectric and electrical properties of ACu3Ti4O12 (A = Ca, Sr and Ba). J. Mater. Sci. 37, 5177–5182 (2002)
Z. Yang, P. Liang, L. Yang, P. Shi, X. Chao, Z. Yang, Synthesis, dielectric properties of Bi2/3Cu3Ti4O12, ceramics by the sol-gel method. J. Mater. Sci. Mater. Electron. 26, 1959–1968 (2015)
A. Kumar, V. Kumar, M.K. Verma, V.S. Rai, D. Prajapati, B. Jena, Dielectric and electrical properties measurement of BCTO and Co & V-doped BCTO synthesized via semi-wet route method. J. Mater. Sci. Mater. Electron. 34, 1755 (2023)
U. Holzwarth, N. Gibson, The Scherrer equation versus the ‘Debye-Scherrer equation.’ Nat. Nanotechnol. 6, 534 (2011)
V. Kumar, S. Kumari, P. Kumar, M. Kar, L. Kumar, Structural analysis by Rietveld method and its correlation with optical properties of nanocrystalline zinc oxide. Adv. Mater. Lett. 6(139–147), 91 (2015)
M. Toubane, R. Tala-Ighil, F. Bensouici, M. Bououdina, W. Cai, S. Liu, M. Souier, A. Iratni, Structural, optical and photocatalytic properties of ZnO nanorods: effect of aging time and number of layers. Ceram. Int. 42, 9673–9685 (2016)
M. George, Finite size effects on the electrical properties of sol–gel synthesized CoFe2O4 powders: deviation from Maxwell-Wagner theory and evidence of surface polarization effects. J. Phys. D 40, 1593 (2007)
Z. Lu, G. Wang, W. Bao, J. Li, L. Li, A. Mostaed, H. Yang, H. Ji, D. Li, A. Feteira, F. Xu, Superior energy density through tailored dopant strategies in multilayer ceramic capacitors. Energy Environ. Sci. 13(9), 2938–2948 (2022)
J.T. Irvine, D.C. Sinclair, A.R. West, Electroceramics: characterization by impedance spectroscopy. Adv. Mater. 2(3), 132–138 (1990)
Y. Wang, H. Liu, T. Yan, J. Zhao, J. Li, S. Guo, S. Sun, R. Sun, Z. Lu, D. Wang, significantly reduced conductivity in strontium titanate-based lead-free ceramics by excess bismuth. Mater. Lett. 309, 131453 (2022)
C. Rayssi, M. Jebli, S. Bouzidi, J. Dhahri, H. Belmabrouk, A. Bajahzar, Impedance analysis and modulus behavior of Ca0.85Er0.1Ti(1−x)Co4x/3O3 (x = 0.15 and 0.20) ceramic prepared by sol-gel reaction. Appl. Phys. A 128, 435 (2022)
L. Zhang, Z.-J. Tang, Polar on relaxation and variable-range-hopping conductivity in the giant-dielectric-constant material CaCu3Ti4O12. Phys. Rev. B 70, 174306 (2004)
L. Singh, L. Dhavala, R. Bhimireddi, A.A. Ansari, S. Kumar, V. Srivastava, R.N. Rai, Q. Van Le, Y. Lee, Low-cost flame synthesized La2/3Cu3Ti4O12 electro-ceramic and extensive investigation on electrical, impedance, modulus, and optical properties. Ceram. Int. 49(13), 21795–21803 (2023)
P. Liu, Y. Li, H. Xu, L. Shi, J. Kong, X. Lv, J. Zhang, R. Che, Hierarchical Fe-Co@TiO2 with incoherent heterointerfaces and gradient magnetic domains for electromagnetic wave absorption. ACS Nano 18(1), 560–570 (2024)
Z. He, H. Xu, L. Shi, X. Ren, J. Kong, P. Liu, Hierarchical Co2P/CoS2@C@MoS2 composites with hollow cavity and multiple phases toward wideband electromagnetic wave absorption. Nano Micro Small 20(6), 2306253 (2023). https://doi.org/10.1002/smll.202306253
H. Xu, Z. He, Y. Wang et al., Metal–phenolic coordination crystals derived magnetic hollow carbon spheres for ultrahigh electromagnetic wave absorption. Nano Res. 17, 1616–1624 (2024). https://doi.org/10.1007/s12274-023-6132-x
Z. He, R. Sun, H. Xu, W. Geng, P. Liu, Metal-organic-frameworks derived hollow carbon derivatives: controllable configurations and optimized microwave absorption. Carbon 219, 118853 (2024). https://doi.org/10.1016/j.carbon.2024.118853
N. Chen, X.F. Pan, Z.J. Guan, Y.J. Zhang, K.J. Wang, J.T. Jiang, Flower-like hierarchical Fe3O4-based heterostructured microspheres enabling superior electromagnetic wave absorption. Appl. Surf. Sci. 642, 158633 (2024). https://doi.org/10.1016/j.apsusc.2023.158633
Acknowledgements
Anup Kumar thanks the Head, Department of Chemistry, IIT (BHU) Varanasi, India, for providing financial assistance as a Teaching Assistantship. The authors express their gratitude to the Head of the Central Instrumentation Facility Centre at the Indian Institute of Technology (Banaras Hindu University), Varanasi, for granting access to XRD, XPS, FE SEM.
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Kumar, A., Kumar, V., kumar, A. et al. Studies on electrical & dielectric properties of rare-earth-based complex perovskite oxide Bi5Yb3O12 ceramic material synthesized via chemical route. J Mater Sci: Mater Electron 35, 664 (2024). https://doi.org/10.1007/s10854-024-12423-9
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DOI: https://doi.org/10.1007/s10854-024-12423-9