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Studies on electrical & dielectric properties of rare-earth-based complex perovskite oxide Bi5Yb3O12 ceramic material synthesized via chemical route

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Abstract

Bi5Yb3O12 (BYO) ceramic was synthesized utilizing a cost-effective chemical route method. XRD analysis as well as Le-Bail fitting was positively confirmed the single phase formation of BYO ceramic with cubic crystal system belonging to the space group of F m -3m. XPS analysis verified the correct oxidation states of various elements. Elemental composition was determined using EDS. The dielectric constant of BYO ceramic reached its peak at 337, measured at 382 K and 1 kHz. In contrast, its lowest recorded value was 238 at 523 K and 1 kHz. The tangent loss value of the BYO ceramic was noted as 0.2 at 293 K and 1 kHz, and 0.37 at 293 K and 1 MHz.

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Acknowledgements

Anup Kumar thanks the Head, Department of Chemistry, IIT (BHU) Varanasi, India, for providing financial assistance as a Teaching Assistantship. The authors express their gratitude to the Head of the Central Instrumentation Facility Centre at the Indian Institute of Technology (Banaras Hindu University), Varanasi, for granting access to XRD, XPS, FE SEM.

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Correspondence to K. D. Mandal.

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Kumar, A., Kumar, V., kumar, A. et al. Studies on electrical & dielectric properties of rare-earth-based complex perovskite oxide Bi5Yb3O12 ceramic material synthesized via chemical route. J Mater Sci: Mater Electron 35, 664 (2024). https://doi.org/10.1007/s10854-024-12423-9

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