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Thermal, linear and nonlinear optical properties of PVA/PVP/PEG blends loaded with nanovanadium-doped nano tin disulfide

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Abstract

Nanocomposite PVA/PEG/PVP/SnS2/V films were created via thermolysis and casting procedures. X-ray diffraction and scanning electron microscope devices were applied to inspect the microstructure parameters of the nanofiller and its distribution throughout the blend matrix. The thermal stability of the blend was improved upon loading it with the nanofiller. The variations in optical parameters and emitted colors of the blend upon doping are explored. The optical band gap was effectively lowered (5.19 → 3.14 eV), while the n and εr values increased. All films displayed nearly a normal dispersion feature. As the percentage of SnS2/V increased in the polymer blend, its nonlinear optical parameters effectively improved. The FL intensity was greatly lowered with increasing the nano-SnS2/V dopant in the blend matrix, nominating the formed blends for photocatalytic applications.

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References

  1. Z.K. Heiba, A.M. El-naggar, M.B. Mohamed, Y. Altowairqi, A.M. Kamal, O.H. Abd-Elkader, Opt. Mater. 123, 111938 (2022)

    Article  CAS  Google Scholar 

  2. Z.K. Heiba, A.M. El-naggar, M.B. Mohamed, Y. Altowairqi, A.M. Kamal, Appl. Phys. A 127(12), 1 (2021)

    Article  Google Scholar 

  3. Z.K. Heiba, M.B. Mohamed, A.M. El-naggar, Y. Altowairqi, A.M. Kamal, J. Polym. Res. 28(12), 1 (2021)

    Article  Google Scholar 

  4. E. Sheha, H. Khoder, T.S. Shanap, M.G. El-Shaarawy, M.K. El Mansy, Optik 123(13), 1161 (2012)

    Article  CAS  Google Scholar 

  5. E.M. Abdelrazek, A.M. Abdelghany, S.I. Badr, M.A. Morsi, J. Mater. Res. Technol. 7(4), 419 (2018)

    Article  CAS  Google Scholar 

  6. E. Mousa, Y. Hafez, G.M. Nasr, J. Electron. Mater. 50, 2594 (2021)

    Article  CAS  Google Scholar 

  7. Z.K. Heiba, M.B. Mohamed, M.H. Abdel Kader, J. Electron. Mater. 47(5), 2945 (2018)

    Article  CAS  Google Scholar 

  8. P. Wahnón, J.C. Conesa, P. Palacios, R. Lucena, I. Aguilera, Y. Seminovski, F. Fresno, Phys. Chem. Chem. Phys. 13, 20401–20407 (2011)

    Article  Google Scholar 

  9. S.S. Devangamath, B. Lobo, S.P. Masti, S. Narasagoudr, J. Electron. Mater. 31, 2904 (2020)

    Article  CAS  Google Scholar 

  10. M.R. Dilshad, A. Islam, B. Haider, M. Sajid, A. Ijaz, R.U. Khan, W.G. Khan, Chem. Pap. 75, 3131 (2021)

    Article  CAS  Google Scholar 

  11. W.M. Elwekeel, A. Salah, T. Ismail, H. Selmy, M. Alshershby, Y.A. Badr, B. Anis, Opt. Mater. 122, 111732 (2021)

    Article  CAS  Google Scholar 

  12. D.M. Fernandes, J.L. Andrade, M.K. Lima, M.F. Silva, L.H.C. Andrade, S.M. Lima, A.A.W. Hechenleitner, E.A.G. Pineda, Polym. Degrad. Stab. 98(9), 1862 (2013)

    Article  CAS  Google Scholar 

  13. M.M. Khalil, A.H. El-Sayed, M.S. Masoud, E.M. Mahmoud, M.A. Hamad, J. Market. Res. 11, 33 (2021)

    CAS  Google Scholar 

  14. T.S. Soliman, M.M. Hessien, Sh.I. Elkalashy, J. Non-Cryst. Solids 580, 121405 (2022)

    Article  CAS  Google Scholar 

  15. M.B. Mohamed, Z.K. Heiba, N.G. Imam, J. Mol. Struct. 1163, 442 (2018)

    Article  CAS  Google Scholar 

  16. A. Hashim, I.R. Agool, K.J. Kadhim, J. Mater. Sci. 29, 10369 (2018)

    CAS  Google Scholar 

  17. A.M. El-naggar, Z.K. Heiba, M.B. Mohamed, A.M. Kamal, M.M. Osman, A.A. Albassam, G. Lakshminarayana, Appl. Phys. A 127(10), 1 (2021)

    Article  Google Scholar 

  18. A.M. El-naggar, Z.K. Heiba, M.B. Mohamed, A.M. Kamal, M.M. Osman, A.A. Albassam, G. Lakshminarayana, J. Vinyl Addit. Technol. (2021). https://doi.org/10.1002/vnl.21868

    Article  Google Scholar 

  19. A.M. El-Naggar, S.Y. El-Zaiat, M.I. Youssif, F.A. Alsaud, Opt. Mater. 35, 2685 (2013)

    Article  CAS  Google Scholar 

  20. E. Nichelatti, J. Opt. A 4, 400 (2002)

    Article  Google Scholar 

  21. J. Tauc, The Optical Properties of Solid (North Holland, Amsterdam, 1972)

    Google Scholar 

  22. Y. Golitsyn, M. Pulst, M.H. Samiullah, K. Busse, J. Kressler, D. Reichert, Polymer 165, 72 (2019)

    Article  CAS  Google Scholar 

  23. H.E. Assender, A.H. Windle, Polymer 39, 4295 (1998)

    Article  CAS  Google Scholar 

  24. W. El Hotaby, H.H.A. Sherif, B.A. Hemdan, W.A. Khalil, S.K.H. Khalil, Acta Phys. Pol. 131(6), 1554 (2017)

    Article  Google Scholar 

  25. Z.I. Ali, W.H. Essa, J. Sci. Res. 6(1), 29 (2014)

    Article  Google Scholar 

  26. F. El-Sayed, M.I. Mohammed, I.S. Yahia, J. Electron. Mater. 31, 10408 (2020)

    Article  CAS  Google Scholar 

  27. P. Singh, D.C. Bharati, P.N. Gupta, A.L. Saroj, J. Non-Cryst. Solids 494, 21 (2015)

    Article  Google Scholar 

  28. X. Jiang, T. Jiang, X. Zhang, H. Dai, Polym. Eng. Sci. 52(10), 2245 (2012)

    Article  CAS  Google Scholar 

  29. B. Zornoza, S. Irusta, C. Tellez, J. Coronas, Langmuir 25, 5903 (2009)

    Article  CAS  Google Scholar 

  30. A.A. Alhazime, M.B. Mohamed, M.H. Abdel-Kader, J. Inorg. Organomet. Polym. Mater. 29, 436 (2019)

    Article  CAS  Google Scholar 

  31. J. Bai, Z. Shi, J. Yin, Polymer 54, 2498 (2013)

    Article  CAS  Google Scholar 

  32. H. Kafashan, M. Azizieh, H.N. Vatan, J. Alloy. Compd. 686, 962 (2016)

    Article  CAS  Google Scholar 

  33. A. Badawi, S.S. Alharthi, M.G. Althobaiti, A.N. Alharbi, J. Vinyl Addit. Technol. 28, 235 (2022)

    Article  CAS  Google Scholar 

  34. H.E. Ali, M.A. Sayed, H. Algarni, Y. Khairy, M.M. Abdel-Aziz, J. Vinyl Addit. Technol. 28, 444 (2022)

    Article  CAS  Google Scholar 

  35. H.R. Rajabi, R. Naghiha, M. Kheirizadeh, H. Sadatfaraji, A. Mirzaei, Z.M. Al-vand, Mater. Sci. Eng. C 78, 1109 (2017)

    Article  CAS  Google Scholar 

  36. K. Tanaka, Thin Solid Films 66, 271 (1980)

    Article  CAS  Google Scholar 

  37. S.B. Aziz, J. Electron. Mater. 45, 736 (2016)

    Article  CAS  Google Scholar 

  38. Z.K. Heiba, M.B. Mohamed, A. Badawi, A.A. Alhazime, Chem. Phys. Lett. 770, 138460 (2021)

    Article  CAS  Google Scholar 

  39. D.L. Wise, Electrical and Optical Polymer Systems: Fundamentals: Methods, and Applications (CRC Press, Boca Raton, 1998)

    Book  Google Scholar 

  40. G.R. Suma, N.K. Subramani, K.N. Shilpa, S. Sachhidananda, S.V. Satyanarayana, J. Mater. Sci. 28(14), 10707 (2017)

    CAS  Google Scholar 

  41. O.G. Abdullah, S.B. Aziz, K.M. Omer, Y.M. Salih, J. Mater. Sci. 26, 5303 (2015)

    CAS  Google Scholar 

  42. N. Sabry, M.I. Mohammed, I.S. Yahia, Mater. Res. Express. 6, 115339 (2019)

    Article  Google Scholar 

  43. G. Raja, S. Gopinath, R. Azhagu, A.K. Shukla, M.S. Alhoshan, K. Sivakumar, J. Phys. E 158, 69 (2016)

    Article  Google Scholar 

  44. M.M.R. Khan, M. Akter, M.K. Amin, M. Younus, N. Chakraborty, J. Polym. Environ. 26, 3371 (2018)

    Article  Google Scholar 

  45. A. Manikandan, J.J. Vijaya, L.J. Kennedy, M. Bououdina, J. Mol. Struct. 1035, 332 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work is supported by Researchers Supporting Project Number (RSP-2021/72), King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Physics & Astronomy Department, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia

    A. M. El-naggar & A. M. Kamal

  2. Physics Department, Faculty of Science, Ain Shams University, Cairo, Egypt

    Zein K. Heiba & Mohamed Bakr Mohamed

  3. Intelligent Construction Automation Center, Kyungpook National University, 80, Daehak-ro, Buk-gu, Daegu, 41566, Republic of Korea

    G. Lakshminarayana

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  1. A. M. El-naggar
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  5. G. Lakshminarayana
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El-naggar, A.M., Heiba, Z.K., Mohamed, M.B. et al. Thermal, linear and nonlinear optical properties of PVA/PVP/PEG blends loaded with nanovanadium-doped nano tin disulfide. J Mater Sci: Mater Electron 33, 25743–25752 (2022). https://doi.org/10.1007/s10854-022-09267-6

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