Abstract
Newly phosphate-based glasses containing cadmium with the form 40P2O5–10Li2O–(50–x)ZnO–xCdO (x = 0, 10, 20, 30, 40 mol%) were synthesized via a conventional melt quenching procedure. The synthesized glasses were coded as PLZC00–PLZC40. The nature structure, physical, FTIR measurements, dielectric properties, and gamma-ray shielding competences of these glasses have been investigated. Dielectric spectroscopy parameters of investigated glass sample were measured throughout frequency range from 50 Hz to 5 MHz. XRD measurements confirmed that the synthesized glasses were in non-crystalline nature. Density increased with the increase of CdO concentration in mol% from 3.0949 g/cm3 for PLZC00 glasses (free with CdO) to 3.4989 g/cm3 for PLZC40 glasses (with 40 mol% of CdO). The dielectric constant \(\varepsilon^{\prime}\) was decreased for CdO concentration up to 20 mol% referring to creation cross-linkage with other elements, while the bonding defect is formed for CdO concentration greater than 20 mol% and increases the \(\varepsilon^{\prime}\) value. The PLZC40 glass sample possesses higher linear attenuation coefficient (LAC) values than the other prepared samples. Consequently, PLZC40 glass sample achieved the minimum half value layer (HVL) and mean free path (MFP) values among all PLZC-prepared glasses. The highest Zeff values are found around 0.03 MeV and varied from 43.82 to 32.78, while the lowest Zeff values were found at 1.5 MeV and varied between 17.16 and 12.19. The deviation which was found between Zeff values may be due to the difference in the composition of each prepared sample. Finally, one can conclude that the PLZC40 glass sample (with 40 mol% of CdO) has the best shielding capacity among all other studied glasses.
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References
J. Siegel, J.M.F. Navarro, A.G. Navarro, V.D. Blanco, O. Sanz, J. Solis, F. Vega, J. Armengol, Waveguide structures in heavy metal oxide glass written with femtosecond laser pulses above the critical self-focusing threshold. Appl. Phys. Lett. 86, 121109 (2005)
W. Yang, C. Corbari, P.G. Kazansky, K. Sakaguchi, I.C.S. Carvalho, Low loss photonic components in high index bismuth borate glass by femtosecond laser direct writing. Opt. Express. 16, 16215–16226 (2008)
J. Ashok, N. Purnachand, J. SureshKumar, M.S. Reddy, B. Suresh, M.P.F. Graça, N. Veeraiah, Studies on dielectric dispersion, relaxation kinetics and a.c. conductivity of Na2O-CuO-SiO2 glasses mixed with Bi2O3-influence of redox behavior of copper ions. J. Alloys Compd. 696, 1260–1268 (2017)
V. Gancheva, N.D. Yordanov, Y. Karakirov, EPR investigation of the gamma radiation response of different types of glasses. Spectrochim. Acta A. 63, 875–878 (2006)
L.V.E. Caldas, V.A.C. Quezada, Influence of thermal treatments on the response decay of glass radiation detectors. Radiat. Prot. Dosim. 100, 433–436 (2002)
V.M. Sglavo, E. Mura, D. Milanese, J. Lousteau, Mechanical properties of phosphate glass optical fibers. Int. J. Appl Glass Sci. 5(1), 57–64 (2014)
R.K. Brow, Review: the structure of simple phosphate glasses. J. Non-Cryst. Solids. 263 & 264, 1–28 (2000)
K. Meyer, Characterisation of the structure of binary calcium ultraphosphate glasses by infrared and Raman spectroscopy. Phys. Chem. Glasses 39, 108 (1998)
R.K. Brow, Review the structure of simple phosphate glasses. J. Non-Cryst. Solids. 263–264, 1–28 (2000)
N. Vedeanu, O. Cozar, I. Ardelean, B. Lendl, D.A. Magdas, Raman spectroscopic study of CuO–V2O5–P2O5–CaO glass system. Vibr. Spectrosc. 48, 259 (2008)
D.A. Magdas, O. Cozar, I. Ardelean, L. David, Spectroscopic studies of some phosphate glasses with molybdenum ions. J. Opt. Adv. Mater. 9, 729 (2007)
C. Ivascu, I.B. Cozar, L. Daraban, G. Damian, Spectroscopic investigation of P2O5–CdO–Li2O glass system. J. Non-Cryst. Sol. 359, 60–64 (2013)
Y. Al-Hadeethi, M.I. Sayyed, Y.S. Rammah, Fabrication, optical, structural and gamma radiation shielding characterizations of GeO2-PbO-Al2O3–CaO glasses. Ceram. Int. 46, 2055–2062 (2020)
O. Kilicoglu, H.O. Tekin, Bioactive glasses and direct effect of increased K2O additive for nuclear shielding performance: a comparative investigation. Ceram. Int. 46(2), 1323–1333 (2020)
M.I. Sayyed, H.O. Tekin, E.E. Altunsoy, S.S. Obaid, M. Almatari, addition shielding study of tellurite tungsten glasses with different antimony oxide as transparent shielding materials using MCNPX code. J. Non-Cryst. Solids. 498, 167–172 (2018)
M.S. Al-Buriahi, Y.S. Rammah, Electronic polarizability, dielectric, and gamma-ray shielding properties of some tellurite-based glasses. Appl. Phys. A. 125(10), 678 (2019)
Y.S. Rammah, M.S. Al-Buriahi, A.S. Abouhaswa, B2O3–BaCO3–Li2O3 glass system doped with Co3O4: structure, optical, and radiation shielding properties. Phys. B Condens. Matter 576, 411717 (2020)
M.R. Ahmed, B. Ashok, Sh.K. Ahmmad, A. Hameed, M.N. Chary, Md. Shareefuddin, Infrared and Raman spectroscopic studies of Mn2+ ions doped in strontium alumino borate glasses: describes the role of Al2O3. Spectrochim. Acta Part A 210, 308–314 (2019)
M.R. Ahmed, Md. Shareefuddin, EPR, optical, physical and structural studies of strontium alumino-borate glasses containing Cu2+ ions. SN Appl. Sci. 1, 209 (2019)
M.R. Ahmed, KCh. Sekhar, A. Hameed, M.N. Chary, Md. Shareefuddin, Role of aluminum on the physical and spectroscopic properties of chromium-doped strontium alumino borate glasses. Int. J. Mod. Phys. 32(8), 1850095 (2018)
E. Kavaz, F.I. El-Agawany, H.O. Tekin, U. Perisanoglu, Y.S. Rammah, Nuclear radiation shielding using barium borosilicate glass ceramics. J. Phys. Chem. Sol. 142, 109437 (2020)
Y.S. Rammah, E. Kavaz, H. Akyildirim, F.I. El-Agawany, Evaluation of photon, neutron, and charged particle shielding competences of TeO2-B2O3-Bi2O3-TiO2 glasses. J. Non-Cryst. Solids. 535, 119960 (2020)
Y.S. Rammah, A.A. Ali, R. El-Mallawany, F.I. El-Agawany, Fabrication, physical, optical characteristics and gamma-ray competence of novel bismo-borate glasses doped with Yb2O3 rare earth. Phys. B 583, 412055 (2020)
Y.S. Rammah, G. Kilic, R. El-Mallawany, U. Gökhan Issever, F.I. El-Agawany, Investigation of optical, physical, and gamma-ray shielding features of novel vanadyl boro-phosphate glasses. J. Non-Cryst. Solids. 533, 119905 (2020)
A.S. Abouhaswa, M.S. Al-Buriahi, M. Chalermpon, Y.S. Rammah, Influence of ZrO2 on gamma shielding properties of lead borate glasses. Appl. Phy. A. 126, 7 (2020)
E. Şakar, Ö.F. Özpolat, B. Alım, M.I. Sayyed, M. Kurudirek, Phy-X/PSD: development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry. Rad. Phy. Chem. 166, 108496 (2020)
Y. Zhou, D. Yin, S. Zheng, S. Peng, Y. Qi, F. Chen, G. Yang, Improvement of 1.53 µm emission and energy transfer of Yb3+/Er3+ co-doped tellurite glass and fiber. Opt. Fib. Technol. 19, 507–513 (2013)
A.S. Abouhaswa, Y.S. Rammah, M.I. Sayyed, H.O. Tekin, Synthesis, structure, optical and gamma radiation shielding properties of B2O3-PbO2-Bi2O3 glasses. Composites B 172, 218–225 (2019)
R. El-Mallawany, Y.S. Rammah, A. El Adawy, Z. Wassel, Optical and thermal properties of some tellurite glasses. Am. J. Opt. Photon. 5(2), 11–18 (2017)
A.A. Ali, Y.S. Rammah, R. El-Mallawany, D. Souri, FTIR and UV spectra of pentaternary borate glasses. Measurement 105, 72–77 (2017)
W.S. AbuShanab, E.B. Moustafa, A.H. Hammad, R.M. Ramadan, A.R. Wassel, Enhancement the structural, optical and nonlinear optical properties of cadmium phosphate glasses by nickel ions. J. Mater. Sci.: Mater Eletron. 30, 18058–18064 (2019)
P. Bergo, S.T. Reis, W.M. Pontuschka, J.M. Prison, C.C. Motta, Dielectric properties and structural features of barium-iron phosphate glasses. J. Non-Cryst. Solids 336, 159 (2004)
C. Ivascu, I.B. Cozar, L. Daraban, G. Damian, Spectroscopic investigation of P2O5–CdO–Li2O glass system. J. Non-Cryst. Solids. 359, 60–64 (2013)
H. Doweidar, Y.M. Moustafa, K. El-Egili, I. Abbas, Infrared spectra of Fe2O3–PbO–P2O5 glasses. J. Vib. Spectrosc. 37, 91–96 (2005)
A.M. Emara, E.S. Yousef, Structural and optical properties of phosphate zinc-nickel oxide glasses for narrow band pass absorption filters. J. Mod. Opt. 65, 1839–1845 (2018)
G. Venkateswara Rao, H.D. Shashikala, Optical and mechanical properties of calcium phosphate glasses. Glass Phys. Chem. 40, 303–309 (2014)
S. Thomas, R. George, M. Rathaiah, V. Venkatramu, S.K. Nayab Rasool, N.V. Unnikrishnan, Structural, vibrational and dielectric studies of Sm3+-doped K-Mg–Al zincfluorophosphate glasses. Phys. B 431, 69–74 (2013)
M. Abid, M. Et-tabirou, M. Taibi, Structure and DCconductivity of lead sodium ultraphosphate glasses. Mater. Sci. Eng. B 97, 20–24 (2003)
A.N. Regos, R.C. Lucacel, I. Ardelean, Structural study of xK2O·(100–x)[P2O5·CaO] glass system. J. Mater. Sci. 46, 7313–7318 (2011)
H.A. ElBatal, A.M. Abdelghany, F.H. ElBatal, Kh.M. ElBadry, F.A. Moustaffa, UV–visible and infrared absorption spectra of gamma irradiated CuO-doped lithium phosphate, lead phosphate and zinc phosphate glasses. A comparative study. Phys. B 406, 3694–3703 (2011)
F.A. Miller, C.H. Wilkins, Infrared spectra and characteristic frequencies of inorganic ions. Anal. Chem. 24, 1253–1294 (1952)
H. Scholze, Der Einbau des Wassers in Glfisern. Glastech Ber 32, 81–88 (1959)
P. Znasik, M. Jamnicky, Preparation, infrared spectra and structure of glasses in the system CuCl−Cu2O−(P2O5 + MoO3). J. Non-Cryst. Solids. 146, 74–80 (1992)
S.V.G.A. Prasad, G.S. Baskaran, N. Veeraiah, Spectroscopic, magnetic and dielectric investigations of BaO–Ga2O3–P2O5 glasses doped by Cu ions. Phys. Status Solidi. 202, 2812–2828 (2005)
A.S. Abouhaswa, Y.S. Rammah, S.E. Ibrahim, R. El-Mallawany, Optical and electrical properties of lead borate glasses. Electr. Mater. 48, 5624–5631 (2019)
M.S. Reddy, S.V.G.V.A. Prasad, N. Veeraiah, Valence and coordination of chromium ions in ZnO–Sb2O3–B2O3 glass system by means of spectroscopic and dielectric relaxation studies. Phys. Status Solidi 204, 816–832 (2007)
G. MuraliKrishna, N. Veeraiah, N. Venkatramaiah, R. Venkatesan, Induced crystallization and physical properties of Li2O–CaF2–P2O5:TiO2 glass system: Part II. Electrical, magnetic and optical properties. J. Alloys Compd. 450, 486–493 (2008)
G. Srinivasarao, N. Veeraiah, Characterization and physical properties of PbO–As2O3 glasses containing molybdenum ions. J. Solid Chem. 166, 104–117 (2002)
P.S. Sawadh, D.K. Kulkarni, Structural and magnetic properties of CaMg2Fe16O27. J. Bull. Mater. Sci. 24, 47–50 (2001)
A.R. James, C. Prakash, G. Prasad, Structural properties and impedance spectroscopy of excimer laser ablated Zr substituted BaTiO3 thin films. J. Phys. D Appl. Phys. 39, 1635–1641 (2006)
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Shams, M.S., Rammah, Y.S., El-Agawany, F.I. et al. Synthesis, structure, physical, dielectric characteristics, and gamma-ray shielding competences of novel P2O5–Li2O–ZnO–CdO glasses. J Mater Sci: Mater Electron 32, 1877–1887 (2021). https://doi.org/10.1007/s10854-020-04956-6
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DOI: https://doi.org/10.1007/s10854-020-04956-6