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Investigation of the synergic effect of silver on the photodegradation behavior of copper chromite nanostructures

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Abstract

Pure copper chromite nanoparticles were prepared through an efficient route using copper nitrate and chromium nitrate. For the first time, various amino acids were employed as capping agents in the presence of propylene glycol and ethylene glycol in order to prepare these nanostructures. A number of experiments were performed to examine the effect of stabilization agents, alkaline agents and connecting agents on the shape, grain size and photodegradation behavior of CuCr2O4. The results showed that the type of stabilization agent and reducing agent creates numerous changes in terms of the size and photocatalytic performance of copper chromite. The effects of several factors, including the type of pollutant, grain size of CuCr2O4 nanostructures, pH and dosage of dye, on the photocatalytic behavior of copper chromite nanostructure were evaluated. Solutions of methylene blue, methyl orange and rhodamine B were employed as model contaminants. The maximum photocatalytic activity of the CuCr2O4 nanostructure was achieved for the rhodamine B contaminant under UV irradiation. When the CuCr2O4/Ag nanostructure was used instead of CuCr2O4 nanoparticles, the photocatalytic activity during the degradation of rhodamine B increased from 76 to 91%.

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Acknowledgements

The authors gratefully acknowledge the financial support provided by Iran National Science Foundation (Project 94019559) and by DFG Project HE 394/3-2 (Germany). This work was also partially supported by Polish Ministry of Science and Higher Education No. 03/32/BSUB/910. M.W. receives funding from DAAD, Ref. No. 91528917.

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Authors and Affiliations

  1. Molecular Biology Research Center, Systems Biology and Poisonings Institute, Baqiyatallah University of Medical Sciences, Tehran, Iran

    Ali Abbasi, Amir Homayoun Keihan, Mehdi Rahimi-Nasrabadi & Seyed Milad Safar Sajadi

  2. Faculty of Pharmacy, Baqiyatallah University of Medical Sciences, Tehran, Iran

    Mehdi Rahimi-Nasrabadi

  3. Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Poznan University of Technology, Poznan, Poland

    Marcin Wysokowski & Teofil Jesionowski

  4. Institute of Electronic and Sensor Materials, TU Bergakademie Freiberg, Freiberg, Germany

    Marcin Wysokowski, Yvonne Joseph & Hermann Ehrlich

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  1. Ali Abbasi
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Abbasi, A., Keihan, A.H., Rahimi-Nasrabadi, M. et al. Investigation of the synergic effect of silver on the photodegradation behavior of copper chromite nanostructures. J Mater Sci: Mater Electron 30, 13994–14006 (2019). https://doi.org/10.1007/s10854-019-01750-x

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