Abstract
BaTiO3/(WO3)x ceramics (where x = 0, 0.5, 1, 2 and 5 wt%) were prepared by solid state reaction. X-ray powder diffraction, scanning electron microscope, Fourier transform-infrared spectroscopy and ultraviolet–visible diffuse reflectance spectrophotometry were used to investigate the structure, morphology and optical properties, respectively. The electrical and dielectric properties were also performed for different synthesized ceramics. A pure phase was obtained for x = 0.5 wt% ceramic, nevertheless a secondary phase was detected for x ≥ 1 wt% ceramics. The grains size increases for x = 0.5 wt% ceramic and then reduces abruptly with further increasing WO3 content. The increase of grains size and the absence of impurities were all efficient to enhance the dielectric properties. A suitable WO3 content leads to obtain ceramics having high dielectric constant and low tangent loss, which is encouraging for radio frequencies and microwaves applications.
Similar content being viewed by others
References
C.D. Chandler, C. Roger, M.J. Hampden-Smith, Chemical aspects of solution routes to perovskite-phase mixed-metal. Chem. Rev. 93, 1205–1241 (1993)
M.A. Pena, J.L.G. Fierro, Chemical structures and performance of perovskite oxides. Chem. Rev. 101, 1981–2017 (2001)
S. Royer, D. Duprez, F. Can, X. Courtois, C. Batiot-Dupeyrat, S. Laassiri, H. Alamdari, Perovskites as substitutes of noble metals for heterogeneous catalysis: dream or reality. Chem. Rev. 114, 10292–10368 (2014)
H.F. Kay, H.J. Vellard, P. Vousden, Atomic positions and optical properties of barium titanate. Nature 163, 636 (1949)
J. Harada, T. Pedersen, Z. Barnea, X-ray and neutron diffraction study of tetragonal barium titanate. Acta Cryst. B 26, 336 (1970)
M. Wongduan, K. Reinhard, B.H. Robert, P. Simon, Structural and dielectric properties of Ba0.8La0.133Ti0.90Sn0.1O3. J. Eur. Ceram. Soc. 23, 127 (2003)
M.Z.-C. Hu, G.A. Miller, E.A. Payzant, C.J. Rawn, Homogeneous (co)precipitation of inorganic salts for synthesis of monodispersed barium titanate particles. J. Mater. Sci. 35, 2927–2936 (2000)
S. Dudley, T. Kalem, M. Akinc, Conversion of SiO2 diatom frustules to BaTiO3 and SrTiO3. J. Am. Ceram. Soc. 89, 2434–2439 (2006)
Y. Luo, P. Yongping, P. Zhang, J. Zhao, W. Yurong, Y. Liu, Study on dielectric properties of SiO2-doped BaTiO3 ceramics. Ferroelectrics 492, 10–16 (2016)
E.P. Gorzkowski, M.J. Pan, B. Bender, C.C.M. Wu, Glass-ceramics of barium strontium titanate for high energy density capacitors. J. Electroceram. 18, 269–276 (2007)
J.S. Park, Y.H. Han, Nano size BaTiO3 powder coated with silica. Ceram. Int. 31, 777–782 (2005)
M. Cernea, B.S. Vasile, A. Boni, A. Iuga, Synthesis, structure characterization and dielectric properties of Nb doped BaTiO3/SiO2 core-shell heterostructure. J. Alloys Compd. 587, 553–559 (2014)
Y. Zhang, M. Cao, Z. Yao, Z. Wang, Z. Song, A. Ullah, H. Hao, H. Liu, Effects of silica coating on the microstructures and energy storage properties of BaTiO3 ceramics. Mater. Res. Bull. 67, 70–76 (2015)
K. Bi, M. Bi, Y. Hao, W. Luo, Z. Cai, X. Wang, Y. Huang, Ultrafine core-shell BaTiO3@SiO2 structures for nanocomposite capacitors with high energy density. Nano Energy 51, 513–523 (2018)
Y. Yan, L. Liu, C. Ning, Y. Yang, C. Xia, Y. Zou, S. Liu, X. Wang, K. Liu, X. Liu, G. Liu, Improved electrical properties of SiO2-added BaTiO3 ceramics by microwave sintering. Mater. Lett. 165, 135–138 (2016)
X. Lu, Y. Tong, H. Talebinezhad, J. Liu, Y. Cai, Z.Y. Cheng, L. Wang, Effects of SiO2 coating on the dielectric and ferroelectric properties of BaTiO3-SiO2 composites, in 2017 Joint IEEE International Symposium on the Applications of Ferroelectric (ISAF)/International Workshop on Acoustic Transduction Materials and Devices (IWATMD)/Piezoresponse Force Microscopy (PFM)
Q. Zhao, X. Wang, H. Gong, B. Liu, B. Luo, L. Li, The properties of Al2O3 coated fine-grain temperature stable BaTiO3-based ceramics sintered in reducing atmosphere. J. Am. Ceram. Soc. 101, 1245–1254 (2018)
H.A. Moghaddam, M.R. Mohammadi, TiO2–BaTiO3 nanocomposite for electron capture in dye-sensitized solar cells. J. Am. Ceram. Soc. 100, 2144–2153 (2017)
R. Li, Q. Li, L. Zong, X. Wang, J. Yang, BaTiO3/TiO2 heterostructure nanotube arrays for improved photoelectrochemical and photocatalytic activity. Electrochim. Acta 91, 30–35 (2013)
L. Zhang, Y. Shi, S. Peng, J. Liang, Z. Tao, J. Chen, Dye-sensitized solar cells made from BaTiO3-coated TiO2 nanoporous electrodes. J. Photochem. Photobiol., A 197, 260–265 (2008)
Z.A. Garmaroudi, M.R. Mohammadi, Design of TiO2 dye-sensitized solar cell photoanode electrodes with different microstructures and arrangement modes of the layers. J. Sol-Gel. Sci. Technol. 76, 666–678 (2015)
H. Asgari Moghaddam, M.R. Mohammadi, S.M. Seyed Reyhani, Improved photon to current conversion in nanostructured TiO2 dye-sensitized solar cells by incorporating cubic BaTiO3 particles deliting incident. Sol. Energy 132, 1–14 (2016)
V. Paunović, L.J. Živković, V. Mitić, Influence of rare-earth additives (La, Sm and Dy) on the microstructure and dielectric properties of doped BaTiO3 ceramics. Sci. Sinter. 42, 69–79 (2010)
W.H. Tzing, W.H. Tuan, H.L. Lin, The effect of microstructure on the electrical properties of NiO-doped BaTiO3. Ceram. Int. 25, 425–430 (1999)
T. Nagai, K. Iijima, H.J. Hwang, M. Sando, T. Sekino, K. Niihara, Effect of MgO doping on the phase transformations of BaTiO3. J. Am. Ceram. Soc. 83, 107–112 (2000)
Y. Sakabe, N. Wada, T. Hiramatsu, T. Tonogaki, Dielectric properties of fine-grained BaTiO3 ceramics doped with CaO. Jpn. J. Appl. Phys. 41, 6922 (2002)
Y.H. Song, J.H. Hwang, Y.H. Han, Effects of Y2O3 on temperature stability of acceptor-doped BaTiO3. Jpn. J. Appl. Phys. 44, 1310 (2005)
A. Shukla, R.N.P. Choudhary, A.K. Thakur, D.K. Pradhan, Structural, microstructural and electrical studies of La and Cu doped BaTiO3 ceramics. Physica B 405, 99–106 (2010)
X. Cheng, M. Shen, Enhanced spontaneous polarization in Sr and Ca co-doped BaTiO3 ceramics. Solid State Commun. 141, 587–590 (2007)
Y.-S. Jung, E.-S. Na, U. Paik, J. Lee, J. Kim, A study on the phase transition and characteristics of rare earth elements doped BaTiO3. Mater. Res. Bull. 37, 1633–1640 (2002)
J. Li, M. Kuwabara, Preparation and luminescent properties of Eu-doped BaTiO3 thin films by sol–gel process. Sci. Technol. Adv. Mater. 4, 143–148 (2003)
H. Zheng, J. Zhen-Ou, M.S. Strano, R.B. Kaner, A. Mitchell, K. Kalantar Zadeh, Nanostructured tungsten oxide—properties, synthesis, and applications. Adv. Funct. Mater. 21, 2175–2196 (2011)
W.J. Lee, Y.K. Fang, J.-J. Ho, W.T. Hsieh, S.F. Ting, D. Huang, F.C. Ho, Effects of surface porosity on tungsten trioxide (WO3) films’ electrochromic performance. J. Electron. Mater. 29, 183–187 (2000)
M.M. El-Nahass, H.A.M. Ali, M. Saadeldin, M. Zaghllol, AC conductivity and dielectric properties of bulk tungsten trioxide (WO3). Physica B 407, 4453–4457 (2012)
R.S. Vemuri, K. Kamala Bharathi, S.K. Gullapalli, C.V. Ramana, Effect of structure and size on the electrical properties of nanocrystalline WO3 films. ACS Appl. Mater. Interfaces. 2, 2623–2628 (2010)
Y. Slimani, M.A. Almessiere, E. Hannachi, A. Baykal, A. Manikandan, M. Mumtaz, F. Ben Azzouz, Influence of WO3 nanowires on structural, morphological and flux pinning ability of YBa2Cu3Oy superconductor. Ceram. Int. 45, 2621–2628 (2019)
Y. Slimani, M.A. Almessiere, E. Hannachi, M. Mumtaz, A. Manikandan, A. Baykal, F. Ben Azzouz, Improvement of flux pinning ability by tungsten oxide nanoparticles added in YBa2Cu3Oy superconductor. Ceram. Int. 45, 6828–6835 (2019)
S. Rajan, P.M. Mohammed-Gazzali, G. Chandrasekaran, Electrical and magnetic phase transition studies of Fe and Mn co-doped BaTiO3. J. Alloys Compd. 656, 98–109 (2016)
B. Deka, S. Ravi, A. Perumal, D. Pamu, Ferromagnetism and ferroelectricity in Fe doped BaTiO3. Physica B 448, 204–206 (2014)
B.D. Cullity, Elements of X-ray diffraction (Addison-Wesley, Boston, 1956)
E. Hannachi, Y. Slimani, A. Ekicibil, A. Manikandan, F. Ben Azzouz, Magneto-resistivity and magnetization investigations of YBCO superconductor added by nano-wires and nano-particles of titanium oxide. J. Mater. Sci. Mater. Electron. 30, 8805–8813 (2019)
S. Lather, A. Gupta, J. Dalal, V. Verma, R. Tripathi, A. Ohlan, Effect of mechanical milling on structural, dielectric and magnetic properties of BaTiO3–Ni0.5Co0.5Fe2O4 multiferroic ceramics. Ceram. Int. 43, 3246–3251 (2017)
G. Arlt, D. Hennings, G. de With, Dielectric properties of fine-grained barium titanate ceramics. J. Appl. Phys. 58, 1619–1625 (1985)
S. Kappadan, T.W. Gebreab, S. Thomas, N. Kalarikkal, Tetragonal BaTiO3 nanoparticles: an efficient photocatalyst for the degradation of organic pollutants. Mater. Sci. Semicond. Process. 51, 42–47 (2016)
S. Adhikari, D. Sarkar, H.S. Maiti, Synthesis and characterization of WO3 spherical nanoparticles and nanorods. Mater. Res. Bull. 49, 325–330 (2014)
Y. Slimani, B. Unal, E. Hannachi, A. Selmi, M.A. Almessiere, M. Nawaz, A. Baykal, I. Ercan, M. Yildiz, Frequency and dc bias voltage dependent dielectric properties and electrical conductivity of BaTiO3-SrTiO3/(SiO2)x nanocomposites. Ceram. Int. 45, 11989–12000 (2019)
Y. Slimani, A. Selmi, E. Hannachi, M.A. Almessiere, A. Baykal, I. Ercan, Impact of ZnO addition on structural, morphological, optical, dielectric and electrical performances of BaTiO3 ceramics. J. Mater. Sci. Mater. Electron. 30, 9520–9530 (2019)
P. Wang, C. Fan, Y. Wang, G. Ding, P. Yuan, A dual chelating sol–gel synthesis of BaTiO3 nanoparticles with effective photocatalytic activity for removing humic acid from water. Mater. Res. Bull. 48, 869–877 (2013)
J.-i. Fujisawa, T. Eda, M. Hanaya, Comparative study of conduction-band and valence-band edges of TiO2, SrTiO3, and BaTiO3 by ionization potential measurements. Chem. Phys. Lett. 685, 23–26 (2017)
Y.C. Teh, A.A. Saif, Influence of annealing temperature on structural and optical properties of sol-gel derived Ba0.9Gd0.1TiO3 thin films for optoelectronics. J. Alloys Compd. 703, 407–413 (2017)
M. Ozta, Influence of grain size on electrical and optical properties of InP films. Chin. Phys. Lett. 25, 4090–4092 (2008)
L.V. Maneeshya, P.V. Thomas, K. Joy, Effects of site substitutions and concentration on the structural, optical and visible photoluminescence properties of Er doped BaTiO3 thin films prepared by RF magnetron sputtering. Opt. Mater. 46, 304–309 (2015)
K. Karishma, P. Ashutosh, K. Prasad, Impedance/modulus and conductivity studies on [Bi0.5(Na1-xKx)0.5]0.94Ba0.06TiO3, (0.16 ≤ x ≤ 0.20) lead-free ceramics. Am. J. Mater. Sci. 6, 1–18 (2016)
A. Selmi, O. Khaldi, M. Mascot, F. Jomni, J.C. Carru, Dielectric relaxations in Ba0.85Sr0.15TiO3 thin films deposited on Pt/Ti/SiO2/Si substrates by sol–gel method. J. Mater. Sci. Mater. Electron. 27, 11299–11307 (2016)
T. Gopal Reddy, B. Rajesh Kumar, T. Subba Rao, J. Altaf Ahmad, Structural and dielectric properties of barium bismuth titanate (BaBi4Ti4O15) ceramics. Int. J. Appl. Eng. Res. 6, 571–580 (2011)
A. Jain, A.K. Panwar, A.K. Jha, Effect of ZnO doping on structural, dielectric, ferroelectric and piezoelectric properties of BaZr0.1Ti0.9O3 ceramics. Ceram. Int. 43, 1948–1955 (2017)
X. Dong, H. Chen, M. Wei, W. Kaituo, J. Zhang, Structure, dielectric and energy storage properties of BaTiO3 ceramics doped with YNbO4. J. Alloys Compd. 744, 721–727 (2018)
A.K. Jonscher, The ‘universal’ dielectric response. Nature 267, 673–679 (1977)
L. Singh, U.S. Rai, K. Mandal, B.C. Sin, S.-I. Leed, Y. Lee, Dielectric, AC-impedance, modulus studies on 0.5BaTiO3-0.5CaCu3Ti4O12 nano-composite ceramic synthesized by one-pot, glycine-assisted nitrate-gel route. Ceram. Int. 40, 10073–10083 (2014)
C.R. Cena, A.K. Behera, B. Behera, Structural, dielectric, and electrical properties of lithium niobate microfibers. J. Adv. Ceram. 5, 84–92 (2016)
Acknowledgements
This work was supported by the Institute for Research & Medical Consultations (Projects Nos. 2017-IRMC-S-3 and 2018-IRMC-S-2) and the Deanship for Scientific Research (Projects Nos. 2018-209-IRMC and 2017-576-IRMC) of Imam Abdulrahman Bin Faisal University (IAU – Saudi Arabia).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Slimani, Y., Selmi, A., Hannachi, E. et al. Study of tungsten oxide effect on the performance of BaTiO3 ceramics. J Mater Sci: Mater Electron 30, 13509–13518 (2019). https://doi.org/10.1007/s10854-019-01718-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-01718-x