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Layer-by-layer preparation and characterization of recyclable nanocomposite (CoxNi1−xFe2O4; X = 0.9/SiO2/TiO2)

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Abstract

Titanium dioxide (TiO2) nanocomposites have been extensively employed in many fundamental optoelectronic and photocatalytic applications due to their outstanding optical, electronic and chemical properties. In the present work, we introduce a simple layer-by-layer approach to design a magnetic TiO2 nanocomposite that could be easily recycled using an external magnetic field without affecting its quantum efficiency. The crystallinity, size, surface area, stability, morphology, purity and other optical, thermal and magnetic properties of the composite have been investigated. Surface topology, thickness and thermal conduction were also demonstrated by AC conductivity measurements at a specific temperature (55 °C). Our results revealed that the prepared composite has a semi-spherical concentric shape with an average size of about (123.4 nm), surface area of (46.13 m2/g) and zeta potential of (− 24.3 mV) as confirmed by HRTEM, surface area analyzer and zeta potential measurements. TGA and DSC analysis recorded the thermal stability of the composite up to (500 °C) while a band gap of about (3.35 eV) has been calculated. VSM analysis showed that the composite has good magnetic properties. Atomic force microscopy recorded a surface roughness of the composite of about (125 nm) while the average thickness was approximately (10.3 nm). Significant responses of the capacitance–voltage profiles in the employed Preisach model, have been also recorded.

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Acknowledgements

The authors would like to acknowledge the technical support from Nile University, Egypt Egyptian Atomic Energy Authority and Bharath Institute of Higher Education and Research, Department of Nanotechnology, Chennai (India). The authors also appreciate the efforts exerted by Prof. Dr. Ahmed Radwan, Director of Research at Nile University, Egypt for providing us a friendly environment for research and the success of this work.

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Authors and Affiliations

  1. School of Engineering and Applied Sciences, Center for Nanotechnology (CNT), Nile University, Sheikh Zayed, Giza, Egypt

    M. Abd Elkodous

  2. Drug Microbiology Lab, Drug Radiation Research Department, National Center for Radiation Research and Technology (NCRRT), Atomic Energy Authority, Cairo, Egypt

    Gharieb S. El-Sayyad, Farag M. Mosallam & Ahmed I. El-Batal

  3. Chemistry Department, Faculty of Science, Ain Shams University, Cairo, Egypt

    AbdElrahman E. Mohamed

  4. Department of Nanotechnology, BIHER Research Park, Bharath University, 173 Agharam Road, Selaiyur, Chennai, Tamil Nadu, 600073, India

    K. Pal

  5. National Centre of Exp. Mineralogy and Petrology, University of Allahabad, Allahabad, India

    N. Asthana

  6. Instituto de Macromoléculas: Professora Eloisa Mano, Centro de Tecnologia- CidadeUniversitária, Universidade Federal Rio de Janeiro, av.HoracioMacedo, 2030, bloco J, Rio de Janeiro, Brazil

    F. Gomes de Souza Junior

  7. Chemical Engineering Department, Military Technical College, Egyptian Armed Forces, Cairo, Egypt

    Mohamed Gobara

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  1. M. Abd Elkodous
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Elkodous, M.A., El-Sayyad, G.S., Mohamed, A.E. et al. Layer-by-layer preparation and characterization of recyclable nanocomposite (CoxNi1−xFe2O4; X = 0.9/SiO2/TiO2). J Mater Sci: Mater Electron 30, 8312–8328 (2019). https://doi.org/10.1007/s10854-019-01149-8

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