Abstract
A semi organic crystal, aquachloro (l-prolinato) copper(II) (ACLPC) has been grown by reacting l-proline and copper(II) chloride in equimolar ratio. It crystallizes in monoclinic noncentrosymmetric space group P21 with lattice parameters a = 8.1965(14) Å, b = 5.2142(9) Å, c = 9.5206(17) Å, and β = 109.411(5)°. The powder X-ray diffraction pattern of ACLPC was recorded and indexed. Elemental analysis has been carried out by energy dispersive spectrometry. The Fourier transform infrared and FT–Raman analysis were used to assign the functional group vibrations. The 1H and 13C NMR spectra were recorded to confirm the molecular structure. The optical transmittance region of the crystal is from 280 to 1100 nm. The second harmonic generation efficiency of the crystal was estimated by using Kutrz–Perry powder technique.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-019-00805-3/MediaObjects/10854_2019_805_Fig1_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-019-00805-3/MediaObjects/10854_2019_805_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-019-00805-3/MediaObjects/10854_2019_805_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-019-00805-3/MediaObjects/10854_2019_805_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-019-00805-3/MediaObjects/10854_2019_805_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-019-00805-3/MediaObjects/10854_2019_805_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-019-00805-3/MediaObjects/10854_2019_805_Fig7_HTML.png)
Similar content being viewed by others
References
X.Q. Wang, D. Xu, D.R. Yuan, Y.P. Tian, W.T. Yu, S.Y. Sun, Z.H. Yang, Q. Fang, M.K. Lu, Y.X. Yan, F.Q. Meng, S.Y. Guo, G.H. Zhang, M.H. Jiang, Synthesis, structure and properties of a new nonlinear optical material: zinc cadmium tetrathiocyanate. Mater. Res. Bull. 34, 2003–2011 (1999)
D.R. Yuan, D.X.U.N. Zhang, M.G. Liu, M.H. Jiang, Organic nonlinear optical crystal MHBA for compact blue-violet laser. Chin. Phys. Lett. 13, 841–846 (1996)
M. Iwali, T. Kobayashel, H. Furya, T. Sasaki, Crystal growth and optical characterization of rare-earth (Re) calcium oxyborate ReCa4O (BO3)3 (Re = Y or Gd) as new nonlinear optical material. J. Appl. Phys. 36, 276–279 (1997)
R.A. Hann, D. Bloor (eds.), Organic Materials for Nonlinear Optics (The Royal Society of Chemistry, London, 1989)
A. Ferrier, M. Velazquez, O. Perez, D. Grebille, X. Portier, R. Moncorge, Crystal growth and characterization of the non-centrosymmetric compound Tl3PbCl5. J. Cryst. Growth 291, 375–384 (2006)
L. Misoguti, V.S. Bagnato, S.C. Zilio, A.T. Varela, F.D. Nunes, F.E.A. Melo, J. Mendes Fillho, Optical properties of L-alanine organic crystals. Opt. Mater. 6, 147–152 (1996)
M.N. Bhat, S.M. Dharmaprakash, Growth of nonlinear optical γ-glycine crystals. J. Cryst. Growth 236, 376–380 (2002)
G.M. Frankenbach, M.C. Etter, Relationship between symmetry in hydrogen-bonded benzoic acids and the formation of acentric crystal structures. Chem. Mater. 4, 272–278 (1992)
M.C. Etter, K.S. Huang, Induction of noncentrosymmetry by polar hydrogen-bonded chains in nitroaniline crystals. Chem. Mater. 4, 824–827 (1992)
J.A.R.P. Sarma, M.S.K. Dhurjati, I.C. Ravikumar, K. Bhanuprakash, Molecular and crystal engineering studies of two 2,4-dinitroalkoxystilbenes: an endeavor to generate efficient SHG crystal. Chem. Mater. 6, 1369–1377 (1994)
G.C. Bjorklund, S. Ducharme, W. Fleming, D. Jungbauer, W.E. Moerner, J.D. Swalen, R.J. Twieg, C.G. Willson, Do Y. Yoon, Applications of organic second-order nonlinear optical materials. Mater. Nonlinear Opt. 455, 216–225 (1991)
T. Mallik, T. Kar, Optical, thermal and structural characterization of an NLO crystal, l-arginine perchlorate. J. Cryst. Growth 274, 251 (2005)
T. Pal, T. Kar, W. Xin Qiang, Z. Guang Ying, W. Dong, C. Xiu Feng, Y. Zhao He, Growth and characterization of nonlinear optical material, LAHClBr—a new member of l-arginine halide family. J. Cryst. Growth 235, 523 (2002)
M. K. Gupta, N. Sinha, B. Kumar, Growth and characterization of new semi-organic L-proline strontium chloride mono hydrate single crystals. Physica B 406, 63–67 (2011)
Y. Yukawa, Structures and properties of (L-prolinato) copper (II) complexes prepared from different solvents. J. Chem. Soc. Dalton Trans. 0, 3217–3221 (1992)
B. Milton Boaz, B. Varghese, C. Justin Raj, S. Jerome Das, Growth, microhardness, dielectric and photoconductivity studies on NPNaLi a promising crystal for NLO application. Mater. Sci. Eng. B 136, 57–61 (2007)
Y. Sheena Mary, L. Ushakumari, B. Harikumar, H. Tresa Varghese, C. Yohannan Panicker, FT–IR, FT–Raman and SERS spectra of L-proline. J. Iran. Chem. Soc. 6, 138–144 (2009)
C.C. Wagner, M.H. Torre, E.J. Baran, Vibrational spectra of copper(II) complexes of L-Proline. Lat. Am. J. Pharm. 27(2), 197–202 (2008)
A.J. Downs (ed.), Essays, in Structural Chemistry (Macmillan, London, 1971)
C.C. Wagner, E.J. Baran, Vibrational spectra of bis (L-methioninato) copper(II). Acta Farm. Bonaer. 21(4), 287–290 (2002)
C.C. Wagner, E.J. Baran, Spectroscopic and magnetic behaviourof the copper (II) complex of L-tryptophan. Acta Farm. Bonaer. 23(3), 339–342 (2004)
E.Z. Baran, Structural data and vibrational spectra of the copper(II) complex of L-selenomethionine. Z. Für Nat. B 60, (2005) 663–666
D. Aydin-Canturk and H.N. Max-Planck, Synthesis, structure determination, and magnetic properties of [Cr3(dpa)4Cl2][CuCl2], a compound comprising a trinuclear chain cation. Z. Für Nat. B 67, 759–764 (2012)
H. Tanaka, J. Henning, H.D. Lutz, G. Kliche, Infrared and Raman spectra of CuCl2·2(H,D)2O and K2CuCl4·2(H,D)2O. Vibrational modes, assignment and coupling of the water librations. Spectrochim. Acta A 43(3), 395–400 (1987)
S.K. Kurtz, T.T. Perry, A powder technique for the evaluation of nonlinear opticalmaterials. J. Appl. Phys. 39, 3798–3814 (1968)
Acknowledgements
The authors acknowledge Prof. P.K. Das, Indian Institute of Science (IISc), Bangalore, India for SHG measurements. The authors thank the authorities of Sophisticated Analytical Instrument Facility (SAIF), IIT, Chennai, India for single crystal data collection and SASTRA University, Thanjavur, for having provided FTIR and NMR spectral facilities. The authours also thank Gandhigram Rural Institute, Dindigul for EDS spectrum. We also thank Dr. V. Ramanathan of SASTRA University for the Raman spectrum which was recorded in his lab for having used the Raman spectrometer purchased from the DST SERB (Grant No. SB/FT/CS-007/2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Prabu, P., Vijayabhaskaran, B., Antony Joseph, A. et al. Structural, spectral and nonlinear optical analysis of aquachloro (l-prolinato) copper(II) crystal. J Mater Sci: Mater Electron 30, 5074–5080 (2019). https://doi.org/10.1007/s10854-019-00805-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-00805-3