Skip to main content
SpringerLink
Log in

Nanosecond laser-irradiation assisted the improvement of structural, optical and thermal properties of polyvinyl pyrrolidone/carboxymethyl cellulose blend filled with gold nanoparticles

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Gold nanoparticles (Au NPs) supported within the polymeric matrix of polyvinyl pyrrolidone/carboxymethyl cellulose (PVP/CMC) were successfully prepared through the novel in situ method. These (PVP/CMC)/Au hybrid nanocomposites were exposed to nanosecond laser-irradiation with different powers. These nanocomposite samples were investigated before and after the irradiation process through various techniques such as X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FT-IR), ultraviolet/visible spectroscopy (UV/Vis), transmission electron microscope (TEM), differential thermal analysis (DTA) and thermogravimetric analysis (TGA) techniques. The XRD analysis depicted the amorphous nature for PVP/CMC blend and showed the characterizing peaks of Au NPs for the nanocomposite spectrum, where the intensity of these peaks was largely decreased after irradiation process. The FT-IR spectra showed that the blend components were miscible via showing the functional groups of two polymers that were interacted through the formation of a hydrogen bond and the FT-IR spectra of nanocomposite and irradiated samples were affected. Also, the mechanism of interactions between blend and Au NPs was proposed. The UV/Vis. spectra depicted the formation of Au NPs within the PVP/CMC matrix through showing the surface plasmon resonance peak (SPR) of Au NPs at 546 nm. The UV/Vis. the absorbance of this peak was increased and its position was red-shifted after the irradiation process implying the formation of smaller NPs and the narrow size distribution as confirmed by TEM micrographs. The thermal properties for prepared samples were determined through DTA and TGA techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Scheme 1
Scheme 2
Scheme 3
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. M.A. Morsi, S.A. El-Khodary, A. Rajeh, Enhancement of the optical, thermal and electrical properties of PEO/PAM: Li-polymer electrolyte films doped with Ag nanoparticles. Physica B 539, 88–96 (2018)

    Article  CAS  Google Scholar 

  2. S. Choudhary, R. Sengwa, ZnO nanoparticles dispersed PVA-PVP blend matrix based high-performance flexible nanodielectrics for multifunctional microelectronic devices. Curr. Appl. Phys. 18(9), 1041–1058 (2018)

    Article  Google Scholar 

  3. A.M. Abdelghany, M.A. Morsi, A. Abdelrazek, M.T. Ahmed, Role of silica nanoparticles on structural, optical and morphological properties of poly (vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate) copolymer. Silicon 10, 519–524 (2018)

    Article  CAS  Google Scholar 

  4. A. Abdelghany, E. Abdelrazek, S. Badr, M. Abdel-Aziz, M. Morsi, Effect of Gamma-irradiation on biosynthesized gold nanoparticles using Chenopodium murale leaf extract. J. Saudi Chem. Soc. 21(5), 528–537 (2017)

    Article  CAS  Google Scholar 

  5. M. Morsi, A. Abdelghany, UV-irradiation assisted control of the structural, optical and thermal properties of PEO/PVP blended gold nanoparticles. Mater. Chem. Phys. 201, 100–112 (2017)

    Article  CAS  Google Scholar 

  6. A. Abdelghany, E. Abdelrazek, S. Badr, M. Morsi, Effect of gamma-irradiation on (PEO/PVP)/Au nanocomposite: materials for electrochemical and optical applications. Mater. Design 97, 532–543 (2016)

    Article  CAS  Google Scholar 

  7. E.M. Abdelrazek, I.S. Elashmawi, A.M. Hezma et al., Effect of an encapsulate carbon nanotubes (CNTs) on structural and electrical properties of PU/PVC nanocomposites. Physica B 502, 48–55 (2016)

    Article  CAS  Google Scholar 

  8. A. Rajeh, M. Morsi, I.S. Elashmawi, Enhancement of spectroscopic, thermal, electrical and morphological properties of polyethylene oxide/carboxymethyl cellulose blends: combined FT-IR/DFT. Vacuum 159, 430–440 (2019)

    Article  CAS  Google Scholar 

  9. W.H. Eisa, Y.K. Abdel-Moneam, A. Shabaka, A.E.M. Hosam, In situ approach induced growth of highly monodispersed Ag nanoparticles within free standing PVA/PVP films. Spectrochim. Acta A 95, 341–346 (2012)

    Article  CAS  Google Scholar 

  10. M. Morsi, M. Abdelaziz, A.H. Oraby, I. Mokhles, Structural, optical, thermal, and dielectric properties of polyethylene oxide/carboxymethyl cellulose blend filled with barium titanate. J. Phys. Chem. Solids 125, 103–114 (2019)

    Article  CAS  Google Scholar 

  11. N.H. El Fewaty, A. El Sayed, R. Hafez, Synthesis, structural and optical properties of tin oxide nanoparticles and its CMC/PEG–PVA nanocomposite films. Polym. Sci. A 58(6), 1004–1016 (2016)

    Article  CAS  Google Scholar 

  12. M. El-Bana, G. Mohammed, A.M. El Sayed, S. El-Gamal, Preparation and characterization of PbO/carboxymethyl cellulose/polyvinylpyrrolidone nanocomposite films. Polym. Compos. 39, 3712–3725 (2017)

    Article  CAS  Google Scholar 

  13. M. Morsi, M. Abdelaziz, A. Oraby, I. Mokhles, Effect of lithium titanate nanoparticles on the structural, optical, thermal and electrical properties of polyethylene oxide/carboxymethyl cellulose blend. J. Mater. Sci.: Mater. Electron. 29(18), 15912–15925 (2018)

    CAS  Google Scholar 

  14. E. Abdelrazek, A. Abdelghany, S. Badr, M. Morsi, Morphological, thermal and electrical properties of (PEO/PVP)/Au nanocomposite before and after gamma-irradiation. J. Res. Updates Polym. Sci. 6(2), 45–54 (2017)

    Article  CAS  Google Scholar 

  15. F.A. El-Kader, N. Hakeem, I. Elashmawi, A. Menazea, Synthesis and characterization of PVK/AgNPs nanocomposites prepared by laser ablation. Spectrochim. Acta A 138, 331–339 (2015)

    Article  CAS  Google Scholar 

  16. M. Mendivil, S. Shaji, G. Castillo, B. Krishnan, Transmission electron microscopic studies on noble metal nanoparticles synthesized by pulsed laser ablation in liquid. In Microscopy: advances in scientific research and education center, 1st edn, ed. by A. Méndez-Vilas (Formatex Research Center, 2014), pp. 911–920

  17. M.I. Mendivil Palma, B. Krishnan, G.A.C. Rodriguez, T.K. Das Roy, D.A. Avellaneda, S. Shaji, Synthesis and properties of platinum nanoparticles by pulsed laser ablation in liquid. J. Nanomater. (2016). https://doi.org/10.1155/2016/9651637

    Article  Google Scholar 

  18. J.P. Goud, M.S. Alkathy, K. Sandeep, S. Ramakanth, K.J. Raju, Influence of laser fluence on structural, optical and microwave dielectric properties of pulsed laser deposited Ba0.6Sr0.4TiO3 thin films. J. Mater. Sci.: Mater. Electron. 29(18), 15973–15982 (2018)

    CAS  Google Scholar 

  19. D. Garza, G.G. García, M.M. Palma, D. Avellaneda, G. Castillo, T.D. Roy, B. Krishnan, S. Shaji, Nanoparticles of antimony sulfide by pulsed laser ablation in liquid media. J. Mater. Sci. 48(18), 6445–6453 (2013)

    Article  CAS  Google Scholar 

  20. B. Gupta, R. Agarwal, M. Sarwar Alam, Preparation and characterization of polyvinyl alcohol-polyethylene oxide-carboxymethyl cellulose blend membranes. J. Appl. Polym. Sci. 127(2), 1301–1308 (2013)

    Article  CAS  Google Scholar 

  21. A.M. Hezma, I.S. Elashmawi, A. Rajeh, M. Kamal, Change spectroscopic, thermal and mechanical studies of PU/PVC blends. Physica B 495, 4–10 (2016)

    Article  CAS  Google Scholar 

  22. M.S. Abdel-Aziz, A. Hezma, Spectroscopic and antibacterial evaluation of nano-hydroxapatite polyvinyl alcohol biocomposite doped with microbial-synthesized nanogold for biomedical applications. Polym. Plast. Technol. Eng. 52(14), 1503–1509 (2013)

    Article  CAS  Google Scholar 

  23. A. Abdelghany, M.S. Mekhail, E. Abdelrazek, M. Aboud, Combined DFT/FTIR structural studies of monodispersed PVP/Gold and silver nano particles. J. Alloy. Compd. 646, 326–332 (2015)

    Article  CAS  Google Scholar 

  24. A.Y. Yassin, A.-R. Mohamed, E.M. Abdelrazek, M.A. Morsi, A.M. Abdelghany, Structural investigation and enhancement of optical, electrical and thermal properties of poly (vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate)/graphene oxide nanocomposites. J. Mater. Res. Technol. (2018). https://doi.org/10.1016/j.jmrt.2018.08.005

    Article  Google Scholar 

  25. A. Abdelghany, E. Abdelrazek, A. Oraby, M. Morsi, Role of LiBr inorganic filler on physical properties of polyether sulfone thermoplastic polymer. Quantum Matter 5(2), 233–242 (2016)

    Article  Google Scholar 

  26. E. Abdelrazek, I. Elashmawi, Characterization and physical properties of CoCl2 filled polyethyl-methacrylate films. Polym. Compos. 29(9), 1036–1043 (2008)

    Article  CAS  Google Scholar 

  27. M. Wang, L. Xu, H. Hu, M. Zhai, J. Peng, Y. Nho, J. Li, G. Wei, Radiation synthesis of PVP/CMC hydrogels as wound dressing. Nucl. Instrum. Methods Phys. Res. B 265(1), 385–389 (2007)

    Article  CAS  Google Scholar 

  28. K.K. Kumar, M. Ravi, Y. Pavani, S. Bhavani, A. Sharma, V.V.R.N. Rao, Investigations on PEO/PVP/NaBr complexed polymer blend electrolytes for electrochemical cell applications. J. Membr. Sci. 454, 200–211 (2014)

    Article  CAS  Google Scholar 

  29. K.N. Kumar, K. Sivaiah, S. Buddhudu, Structural, thermal and optical properties of Tb3+, Eu3+ and co-doped (Tb3++Eu3+): PEO + PVP polymer films. J. Lumin. 147, 316–323 (2014)

    Article  CAS  Google Scholar 

  30. K. Kumar, M. Ravi, Y. Pavani, S. Bhavani, A. Sharma, V.V.R.N. Rao, Electrical conduction mechanism in NaCl complexed PEO/PVP polymer blend electrolytes. J. Non-Cryst. Solids 358(23), 3205–3211 (2012)

    Article  CAS  Google Scholar 

  31. A. Abdelghany, E. Abdelrazek, D. Rashad, Impact of in situ preparation of CdS filled PVP nano-composite. Spectrochim. Acta A 130, 302–308 (2014)

    Article  CAS  Google Scholar 

  32. H. Wang, X. Qiao, J. Chen, X. Wang, S. Ding, Mechanisms of PVP in the preparation of silver nanoparticles. Mater. Chem. Phys. 94(2), 449–453 (2005)

    Article  CAS  Google Scholar 

  33. A. Hebeish, M. El-Rafie, F. Abdel-Mohdy, E. Abdel-Halim, H.E. Emam, Carboxymethyl cellulose for green synthesis and stabilization of silver nanoparticles. Carbohydr. Polym. 82(3), 933–941 (2010)

    Article  CAS  Google Scholar 

  34. A. Hebeish, M. Hashem, M.A. El-Hady, S. Sharaf, Development of CMC hydrogels loaded with silver nano-particles for medical applications. Carbohydr. Polym. 92(1), 407–413 (2013)

    Article  CAS  Google Scholar 

  35. R.P. Chahal, S. Mahendia, A. Tomar, S. Kumar, γ-Irradiated PVA/Ag nanocomposite films: materials for optical applications. J. Alloy. Compd. 538, 212–219 (2012)

    Article  CAS  Google Scholar 

  36. N. Misra, J. Biswal, A. Gupta, J. Sainis, S. Sabharwal, Gamma radiation induced synthesis of gold nanoparticles in aqueous polyvinyl pyrrolidone solution and its application for hydrogen peroxide estimation. Radiat. Phys. Chem. 81(2), 195–200 (2012)

    Article  CAS  Google Scholar 

  37. A.D. Dwivedi, K. Gopal, Biosynthesis of silver and gold nanoparticles using Chenopodium album leaf extract. Colloids Surf. A 369(1), 27–33 (2010)

    Article  CAS  Google Scholar 

  38. D. Zhang, B. Gökce, S. Barcikowski, Laser synthesis and processing of colloids: fundamentals and applications. Chem. Rev. 117(5), 3990–4103 (2017)

    Article  CAS  Google Scholar 

  39. D. Zhang, B. Gökce, Perspective of laser-prototyping nanoparticle-polymer composites. Appl. Surf. Sci. 392, 991–1003 (2017)

    Article  CAS  Google Scholar 

  40. Y. Liu, S. Chen, L. Zhong, G. Wu, Preparation of high-stable silver nanoparticle dispersion by using sodium alginate as a stabilizer under gamma radiation. Radiat. Phys. Chem. 78(4), 251–255 (2009)

    Article  CAS  Google Scholar 

  41. W.H. Eisa, Y.K. Abdel-Moneam, Y. Shaaban, A.A. Abdel-Fattah, A.M.A. Zeid, Gamma-irradiation assisted seeded growth of Ag nanoparticles within PVA matrix. Mater. Chem. Phys. 128(1–2), 109–113 (2011)

    Article  CAS  Google Scholar 

  42. T. Tsuji, Y. Okazaki, M. Tsuji, Photo-induced morphological conversions of silver nanoparticles prepared using laser ablation in water-Enhanced morphological conversions using halogen etching. J. Photochem. Photobiol. A 194(2), 247–253 (2008)

    Article  CAS  Google Scholar 

  43. K. Nouneh, M. Oyama, G. Lakshminarayana, I. Kityk, A. Wojciechowski, K. Ozga, Kinetics of picosecond laser treatment of silver nanoparticles on ITO substrate. J. Alloys Compd. 509(40), 9663–9668 (2011)

    Article  CAS  Google Scholar 

  44. M. Noruzi, D. Zare, K. Khoshnevisan, D. Davoodi, Rapid green synthesis of gold nanoparticles using Rosa hybrida petal extract at room temperature. Spectrochim. Acta A 79(5), 1461–1465 (2011)

    Article  CAS  Google Scholar 

  45. G. Mohammed, A.M. El Sayed, W. Morsi, Spectroscopic, thermal, and electrical properties of MgO/polyvinyl pyrrolidone/polyvinyl alcohol nanocomposites. J. Phys. Chem. Solids 115, 238–247 (2017)

    Article  CAS  Google Scholar 

  46. S. El-Sayed, K. Mahmoud, A. Fatah, A. Hassen, DSC, TGA and dielectric properties of carboxymethyl cellulose/polyvinyl alcohol blends. Physica B 406(21), 4068–4076 (2011)

    Article  CAS  Google Scholar 

  47. B. Ghanbarzadeh, H. Almasi, Physical properties of edible emulsified films based on carboxymethyl cellulose and oleic acid. Int. J. Biol. Macromol. 48(1), 44–49 (2011)

    Article  CAS  Google Scholar 

  48. A. Goswami, A. Bajpai, J. Bajpai, B. Sinha, Designing vanadium pentoxide-carboxymethyl cellulose/polyvinyl alcohol-based bionanocomposite films and study of their structure, topography, mechanical, electrical and optical behavior. Polym. Bull. 75(2), 781–807 (2018)

    Article  CAS  Google Scholar 

  49. A. Saroj, R. Singh, S. Chandra, Thermal, vibrational, and dielectric studies on PVP/LiBF4 + ionic liquid [EMIM][BF4]-based polymer electrolyte films. J. Phys. Chem. Solids 75(7), 849–857 (2014)

    Article  CAS  Google Scholar 

  50. C. Lii, P. Tomasik, H. Zaleska, S. Liaw, V.M.F. Lai, Carboxymethyl cellulose-gelatin complexes. Carbohyd. Polym. 50(1), 19–26 (2002)

    Article  CAS  Google Scholar 

  51. W. Tongdeesoontorn, L.J. Mauer, S. Wongruong, P. Sriburi, P. Rachtanapun, Effect of carboxymethyl cellulose concentration on physical properties of biodegradable cassava starch-based films. Chem. Cent. J. 5(1), 6–13 (2011)

    Article  CAS  Google Scholar 

  52. E. Gimeno, C. Moraru, J. Kokini, Effect of xanthan gum and CMC on the structure and texture of corn flour pellets expanded by microwave heating. Cereal Chem. 81(1), 100–107 (2004)

    Article  CAS  Google Scholar 

  53. S. Mir, T. Yasin, H.M. Siddiqi, G. Murtaza, Thermal, rheological, mechanical and morphological behavior of high density polyethylene and carboxymethyl cellulose blend. J. Polym. Environ. 25(4), 1011–1020 (2017)

    Article  CAS  Google Scholar 

  54. E. Abdelrazek, I. Elashmawi, S. Labeeb, Chitosan filler effects on the experimental characterization, spectroscopic investigation and thermal studies of PVA/PVP blend films. Physica B 405(8), 2021–2027 (2010)

    Article  CAS  Google Scholar 

  55. J.-F. Su, Z. Huang, X.-Y. Yuan, X.-Y. Wang, M. Li, Structure and properties of carboxymethyl cellulose/soy protein isolate blend edible films crosslinked by Maillard reactions. Carbohyd. Polym. 79(1), 145–153 (2010)

    Article  CAS  Google Scholar 

  56. M. Loría-Bastarrachea, W. Herrera-Kao, J. Cauich-Rodríguez, J. Cervantes-Uc, H. Vázquez-Torres, A. Ávila-Ortega, A TG/FTIR study on the thermal degradation of poly (vinyl pyrrolidone). J. Therm. Anal. Calorim. 104(2), 737–742 (2011)

    Article  CAS  Google Scholar 

  57. E.M. Abdelrazek, A.M. Abdelghany, S.I. Badr, M.A. Morsi, Structural, optical, morphological and thermal properties of PEO/PVP blend containing different concentrations of biosynthesized Au nanoparticles. J. Mater. Res. Technol. 7(4), 419–431 (2018)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Engineering Basic Science Department, Faculty of Engineering, Egyptian Russian University, Cairo, 11829, Egypt

    M. A. Morsi

  2. Physics Department, Faculty of Science, Sa’adah University, Sa’adah, Yemen

    A. Rajeh

  3. Spectroscopy Department, Physics Division, National Research Centre, 33 El-Behouth St., Cairo, 12311, Egypt

    A. A. Menazea

Authors
  1. M. A. Morsi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Rajeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Menazea
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. A. Morsi.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Morsi, M.A., Rajeh, A. & Menazea, A.A. Nanosecond laser-irradiation assisted the improvement of structural, optical and thermal properties of polyvinyl pyrrolidone/carboxymethyl cellulose blend filled with gold nanoparticles. J Mater Sci: Mater Electron 30, 2693–2705 (2019). https://doi.org/10.1007/s10854-018-0545-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-0545-4

Search

Navigation