Abstract
The Cadmium Sulfide (CdS) cauliflower-like thin films were prepared on glass substrates by using chemical bath deposition at 80 °C. The films were annealed at different temperatures (373, 473, 573, 673 and 773 K) for 1 h at ambient air. The XRD results showed that these films were both in cubic and hexagonal structure and there was no structural alteration among films at different annealing temperatures. The SEM images depicted that the as-deposited film and the film annealed at 373 K had a conifer-like structure; at higher annealing temperatures, the conifer-like structures combined and formed cauliflower-like structures. Also, it was found that the optical band gap decreased from 2.42 to 2.39 eV, with the increase of annealing temperature. The electrical measurements (resistivity, carrier concentration and mobility) of the CdS films were carried out by means of Hall Effect at room temperatures.
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X. Wu, J.C. Keane, R.G. Dhere, C. DeHart, D. S. Albin, A. Duda, T.A. Gessert, S. Asher, D.H. Levi, P. Sheldon, in Proceedings of the 17th European PVSEC, Munich, Germany, 22–26 October 2001
B.L. Williams, A.A. Taylor, B.G. Mendis, L. Phillips, L. Bowen, J.D. Major, K. Durose, Appl. Phys. Lett. 104, 053907 (2014)
L. Kosyachenko, T. Toyama, Sol. Energy Mater. Sol. Cells 120, 512 (2014)
N. Maticiuc, N. Spalatu, V. Mikli, J. Hiie, Appl. Surf. Sci. 350, 14 (2005)
M.M. Momeni, M. Mirhosseini, M. Chavoshi, Ceramics Int. 42, 9133 (2016)
M.M. Momeni, M. Mirhosseini, A. Kazempour, Ceramics Int. 41, 13692 (2015)
M.M. Momeni, Y. Ghayeb, J. Alloys Compd. 637, 393 (2015)
M.M. Momeni, Y. Ghayeb, J. Appl. Electrochem. 45, 557 (2015)
S.M.H. Mashkani, M. Ramezani, A.S. Nasab, M.E. Zare, J. Mater. Sci.: Mater. Electron. 26, 6086 (2015)
S.M.H. Mashkani, M. Maddahfar, A.S. Nasab, J. Electron. Mater. 45, 3612 (2016)
D. Wang, D. Li, L. Guo, F. Fu, Z. Zhang, Q. Wei, J. Phys. Chem. C 113, 5984 (2009)
G. Song, H. Zhang, J. Li, Z. Peng, X. Li, L. Chen, Polym. Bull. 68, 2061 (2012)
V.B. Patil, P.D. More, D.S. Sutrave, G.S. Shahane, R.N. Mulik, L.P. Deshmukh, Mater. Chem. Phys. 65, 282 (2000)
S. Deivanayaki, P. Jayamurugan, R. Mariappan, V. Ponnuswamy, Chalcogenide Lett. 7, 159 (2010)
R.W. Birkmire, B.E. McCandless, S.S. Hegedus, Sol. Energy 12, 45 (1992)
H.C. Chou, A.R. Ohatgi, J. Electron. Mater. 23, 278 (1994)
M. Okajima, T. Tohda, J. Cryst. Growth 117, 810 (1992)
R. Ahmed, G. Will, J. Bell, H. Wang, J. Nanopart. Res. 14, 1 (2012)
S. Chandra, R.K. Pandey, R.C. Agarwal, J. Phys. D 13, 1757 (1980)
D.G. Diso, G.E.A. Muftah, V. Patel, I.M. Dharmadasa, J. Electrochem. Soc. 157, H647 (2010)
A. Rakhshani, A. Al-Azab, J. Phys.: Condens. Matter 12, 8745 (2000)
M. Kostoglou, N. Andritsos, A.J. Karabelas, Thin Solid Films 387, 115 (2001)
L. Wenyi, C. Xun, C. Qiulong, Z. Zhibin, Mater. Lett. 59, 1 (2005)
J.H. Lee, Thin Solid Films 515, 6089 (2007)
B. Pradhan, A.K. Sharma, A.K. Ray, J. Cryst. Growth 304, 388 (2007)
H. Moualkia, S. Hariech, M.S. Aida, N. Attaf, E.L. Laifa, J. Phys. D Appl. Phys. 42, 135404 (2009)
H. Metin, M. Ari, S. Erat, S. Durmuş, M. Bozoklu, A. Braun, J. Mater. Res. 25, 189 (2010)
Q.Q. Wu, G.L. Zhang, G.R. Huang, Mater. Lett. 59, 2625 (2005)
Y.X. Nan, F. Chen, L.G. Yang, H.Z. Chen, J. Phys. Chem. C 114, 11911 (2010)
Z. Zhu, Y. Wu, H. Liu, G. Chen, C. Zhu, Mater. Lett. 107, 90 (2013)
I. Kazeminezhad, N. Hekmat, A. Kiasat, Fibers Polym. 15, 672 (2014)
N. Gao, F. Guo, Mater. Lett. 60, 3697 (2006)
H. Zhang, D.R. Yang, X.Y. Ma, Mater. Lett. 61, 3507 (2006)
H. Zhang, X. Ma, D. Yang, Mater. Lett. 58, 5 (2003)
K.S. Ramaiha, R.D. Pilkington, A.E. Hill, R.D. Tomlinson, A.K. Bhatnagar, Mater. Chem. Phys. 68, 22 (2001)
J. Lee, Appl. Surf. Sci. 252, 1398 (2005)
C. Heske, D. Eich, U. Groh, R. Fink, E. Umbach, T. van Buuren, C. Bostedt, N. Franco, L.J. Terminello, M.M. Grush, T.A. Callcott, F.J. Himpsel, D.L. Ederer, R.C.C. Perera, W. Riedl, F. Karg, Thin Solid Films 28, 360 (2000)
M.T.S. Nair, P.K. Nair, R.A. Zingaro, E.A. Meyers, J. Appl. Phys. 75, 1557 (1994)
M.E. Calixto, P.J. Sebastian, Sol. Energy Mater. Sol. Cells 59, 65 (1999)
U. Pal, R. Silva-Gonzalez, G. Martinez-Montes, M. Gracia-Jimenez, M.A. Vidal, S. Torres, Thin Solid Films 305, 345 (1997)
J.H. Schon, O. Schenker, B. Batlogg, Thin Solid Films 385, 271 (2001)
J. Levinson, F.R. Shepherd, P.J. Scanlon, W.D. Westwood, G. Este, M. Rider, J. Appl. Phys. 53, 1193 (1982)
H. Metin, R. Esen, J. Cryst. Growth 258, 141 (2003)
G. Bakiyaraj, N. Gopalakrishnan, R. Dhanasekaran, Chalcogenide Lett. 8, 419 (2011)
T. Dhandayuthapani, M. Girish, R. Sivakumar, C. Sanjeeviraja, R. Gopalakrishnan, Appl. Surf. Sci. 353, 449 (2015)
H. Metin, S. Erat, S. Durmuş, M. Ari, Appl. Surf. Sci. 256, 5076 (2010)
N.H. Erdogan, K. Kara, H. Ozdamar, R. Esen, H. Kavak, Appl. Surf. Sci. 271, 70 (2013)
H. Khallaf, I.O. Oladeji, G. Chai, L. Chow, Thin Solid Films 516, 7306 (2008)
F. Liu, Y. Lai, J. Liu, B. Wang, S. Kuang, Z. Zhang, J. Li, Y. Liu, J. Alloys Compd. 493, 305 (2010)
S. Kose, F. Atay, V. Bilgin, I. Akyüz, E. Ketenci, Appl. Surf. Sci. 256, 4299 (2010)
Acknowledgments
This research was supported by Mersin University Scientific Research Unit: (contract nos: BAP-FEF FB (HM) 2004-3 and BAP-FEF FB (GCO) 2014-2 YL). The authors would like to thank to University of Mersin.
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Ozcan, G.C., Metin Gubur, H., Alpdogan, S. et al. The investigation of the annealing temperature for CdS cauliflower-like thin films grown by using CBD. J Mater Sci: Mater Electron 27, 12148–12154 (2016). https://doi.org/10.1007/s10854-016-5368-6
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DOI: https://doi.org/10.1007/s10854-016-5368-6