Abstract
Gd2O2S:Tb phosphors with different alkali-metal compound fluxes were synthesized by molten salt method, showing high luminous intensity, monodispersity and micron size characteristics. The results indicated that from K+ to Na+ and to Li+, the particles mean size tended to grow bigger. K+ could effectively reduce the particle size without depressing the luminescence intensity. Meanwhile, after comparing the strongest emission intensity among different fluxes, it was shown that K+ had most significance on improving the luminescence intensity. Li+ could promote the formation of hexagonal morphology. It was also found that CO3 2−, PO4 3− had prominent effects on optimizing particles size (at 254 nm excitation).
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The project is supported by Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and National Natural Science Foundation of China (51202111).
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Ding, Y., Yang, W., Zhang, Q. et al. Influence of alkali metal compound fluxes on Gd2O2S:Tb particle and luminescence. J Mater Sci: Mater Electron 26, 1982–1986 (2015). https://doi.org/10.1007/s10854-014-2638-z
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DOI: https://doi.org/10.1007/s10854-014-2638-z