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Preparation and dielectric properties of a polyurethane elastomer filled with resol-derived ordered mesoporous carbon

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Abstract

This study deals with the preparation and dielectric properties of polyurethane (PU) elastomer films by resol-derived ordered mesoporous carbon (OMC) nanopowder incorporation in the PU polymer matrix. Resol-derived OMC with a 2D hexagonal mesoporous carbon framework is used as conducting fillers to achieve homogeneous dispersion and favorable interfacial interactions in the polymer matrix. The dielectric properties depend on the applied field frequency and the carbon filler weight fraction. The carbon fraction has little effect on the relative permittivity. The relative permittivity of all the PU-OMC composites increases with the decline of frequency. Incorporating a small amount of OMC into the PU polymer had no influence on the dielectric loss. Along with the increasing carbon fraction above the percolation threshold, dielectric loss of PU-OMC composites increases exponentially in the low frequency range. PU-0.75 wt% OMC composite possesses the best dielectric properties, and the obtained relative permittivity and dielectric loss at 1 kHz is 9.59 and 0.03018, respectively.

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References

  1. S.H. Zhang, C. Huang, R.J. Klein, F. Xia, Q.M. Zhang, Z.Y. Cheng, J. Intell. Mater. Syst. Struct. 18, 133–145 (2007)

    Article  Google Scholar 

  2. C. Huang, Q.M. Zhang, J. Appl. Phys. Lett. 82, 3502–3504 (2003)

    Article  CAS  Google Scholar 

  3. C. Huang, Q.M. Zhang, G.D. Botton, K. Bhattacharya, Appl. Phys. Lett. 84, 4391–4393 (2004)

    Article  CAS  Google Scholar 

  4. K. Yuse, D. Guyomar, M. Kanda, L. Seveyrat, B. Guiffard, Sensor. Actuat. A Phys. 165, 147–154 (2011)

    Article  CAS  Google Scholar 

  5. K. Wongtimnoi, B. Guiffard, A. Bogner-Van de Moortèle, L. Seveyrat, C. Gauthier, J.Y. Cavaillé, Compos. Sci. Technol. 71, 885–892 (2011)

    Article  CAS  Google Scholar 

  6. Z.D. Zhao, W.X. Yu, X.J. He, X.F. Chen, Mater. Lett. 57, 3082–3088 (2003)

    Article  CAS  Google Scholar 

  7. Y. Konishi, M. Cakmak, Polymer 47, 5371–5391 (2006)

    Article  CAS  Google Scholar 

  8. B. Guiffard, L. Seveyrat, G. Sebald, D. Guyomar, J. Phys. D Appl. Phys. 39, 3053–3057 (2006)

    Article  CAS  Google Scholar 

  9. L. Petit, B. Guiffard, L. Seveyrat, D. Guyomar, Sens. Actuators A Phys. 148, 105–110 (2008)

    Article  CAS  Google Scholar 

  10. N. Hu, Z. Masuda, G. Yamamoto, H. Fukunaga, T. Hashida, J.H. Qiu, Compos. A 39, 893–903 (2008)

    Article  Google Scholar 

  11. N. Hu, Z. Masuda, C. Yan, G. Yamamoto, H. Fukunaga, T. Hashida, Nanotechnology 19, 215701 (2008)

    Article  Google Scholar 

  12. N. Hu, Y. Karube, C. Yan, Z. Masuda, H. Fukunag, Acta Mater. 56, 2929–2936 (2008)

    Article  CAS  Google Scholar 

  13. N. Hu, Y. Karube, M. Arai, T. Watanabe, C. Yan, Y. Li et al., Carbon 48, 680–687 (2010)

    Article  CAS  Google Scholar 

  14. H.F. Leea, H.H. Yu, Soft Matter 7, 3801–3807 (2011)

    Article  Google Scholar 

  15. M. Raja, A.M. Shanmugharaj, S.H. Ryu, J. Subha, Mater. Chem. Phys. 129, 925–931 (2011)

    Article  CAS  Google Scholar 

  16. G.D. Liang, S.C. Tjong, Mater. Chem. Phys. 100, 132–137 (2006)

    Article  CAS  Google Scholar 

  17. Z.M. Dang, J.P. Wu, H.P. Xu, S.H. Yao, M.J. Jiang, J. Bai, Appl. Phys. Lett. 91, 072912 (2007)

    Article  Google Scholar 

  18. Z.M. Dang, C.W. Nan, J. Appl. Phys. 93, 5543–5545 (2003)

    Article  CAS  Google Scholar 

  19. Z.M. Dang, B. Xia, S.H. Yao, M.J. Jiang, H.T. Song, L.Q. Zhang et al., Appl. Phys. Lett. 94, 042902 (2009)

    Article  Google Scholar 

  20. H.P. Xu, Z.M. Dang, Chem. Phys. Lett. 438, 196–202 (2007)

    Article  CAS  Google Scholar 

  21. L. Viry, C. Mercader, P. Miaudet, C. Zakri, A. Derre, A. Kuhn et al., J. Mater. Chem. 20, 3487–3495 (2010)

    Article  CAS  Google Scholar 

  22. P. Costa, J. Silva, V. Sencadas, C.M. Costa, F.W.J. van Hattum, J.G. Rocha et al., Carbon 47, 2590–2599 (2009)

    Article  CAS  Google Scholar 

  23. R.K. Layek, S. Samanta, D.P. Chatterjee, A.K. Nandi, Polymer 51, 5846–5856 (2010)

    Article  CAS  Google Scholar 

  24. A. Javadi, Y.L. Xiao, W.J. Xu, S.Q. Gong, J. Mater. Chem. 22, 830–834 (2012)

    Article  CAS  Google Scholar 

  25. J.W. Shang, Y.H. Zhang, L. Yu, B. Shen, F.Z. Lv, P.K. Chu, Mater. Chem. Phys. 134, 867–874 (2012)

    Article  CAS  Google Scholar 

  26. Y. Meng, D. Gu, F.Q. Zhang, Y.F. Shi, H.F. Yang, F. Li et al., Angew. Chem. Int. Ed. 44, 7053–7059 (2005)

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by PAPD, NSFC (90923029), NSF of Jiangsu Province (BK2009020), the Program for Changjiang Scholars and Innovative Research Team in University (IRT0968), the Funding of Jiangsu Innovation Program for Graduate Education (CXZZ11-0194), the Funding for Outstanding Doctoral Dissertation in NUAA (BCXJ11-02), and NUAA Research Fund for Fundamental Research.

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Authors and Affiliations

  1. State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China

    Tian Chen, Jinhao Qiu, Kongjun Zhu & Hongli Ji

  2. College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China

    Tian Chen, Changhui Fan & Qinxue Chen

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  1. Tian Chen
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  2. Jinhao Qiu
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  3. Kongjun Zhu
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  4. Hongli Ji
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  5. Changhui Fan
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Correspondence to Jinhao Qiu.

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Chen, T., Qiu, J., Zhu, K. et al. Preparation and dielectric properties of a polyurethane elastomer filled with resol-derived ordered mesoporous carbon. J Mater Sci: Mater Electron 24, 2013–2018 (2013). https://doi.org/10.1007/s10854-012-1050-9

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  • DOI: https://doi.org/10.1007/s10854-012-1050-9

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