Skip to main content
Log in

Effect of treatment by electrostatic field and 532-nm laser irradiation on optical and thermo-optical properties of graphene oxide colloids

  • Original Paper
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

It is possible to change the optical properties of graphene oxide colloids by modifying their oxygen bond. We report here the use of laser irradiation and electrostatic field to change the properties of graphene oxide colloids. UV–Visible and Fourier transform infrared spectroscopes clearly demonstrate that graphene oxide is successfully modified by laser irradiation and electrostatic field. It is shown that significant enhancement in optical properties of graphene oxide colloids can be achieved by modification with the electric field and laser irradiation. Compared to the effect of the laser irradiation on the graphene oxide colloids, the result of treatment by DC electric field shows a better reduction performance and larger optical responses. In addition, it is observed that treatment of the graphene oxide colloids by electrostatic field in the presence of the 532-nm laser irradiation leads to scale down the reduction level of the sample. Results show that by using different reduction processes, we can modify the physical properties of graphene oxide for achieving tunable optical responses.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9

Similar content being viewed by others

References

  1. Compton OC, Nguyen ST (2010) Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials. Small 6:711–723

    Article  Google Scholar 

  2. Wang Y, Chen X, Zhong Y, Zhu F, Loh KP (2009) Large area, continuous, few-layered graphene as anodes in organic photovoltaic devices. ApplPhysLett 95:063302

    Google Scholar 

  3. Bonaccorso F, Sun Z, Hasan T, Ferrari AC (2010) Graphene photonics and optoelectronics. Nat Photonics 4:611–622

    Article  Google Scholar 

  4. Shang N, Papakonstantinou P, Wang P, Silva SRP (2010) Platinum integrated graphene for methanol fuel cells. J PhysChem C 114:15837–15841

    Google Scholar 

  5. Zhu Y, Murali S, Cai W, Li X, Suk JW, Potts JR, Ruoff RS (2010) Graphene and grapheneoxide: synthesis, properties, and applications. Adv Mater 22:3906–3924

    Article  Google Scholar 

  6. Young RJ, Kinloch IA, Gong L, Novoselov KS (2012) The mechanics of graphene nanocomposites: a review. Compos Sci Technol 72:1459–1476

    Article  Google Scholar 

  7. Verdejo R, Bernal MM, Romasanta LJ, Lopez-Manchado MA (2011) Graphene filled polymer nanocomposites. J Mater Chem 21:3301–3310

    Article  Google Scholar 

  8. Singh V, Joung D, Zhai L, Das S, Khondaker SI, Seal S (2011) Graphene based materials: past, present and future. Prog Mater Sci 56:1178–1271

    Article  Google Scholar 

  9. Terrones M, Botello-Méndez AR, Campos-Delgado J, López-Urías F, Vega-Cantú YI, Rodríguez-Macías FJ, Elias AL, Mũnoz-Sandova E, Cano-Márquez AG, Charlier J, Terrones H (2010) Graphene and graphite nanoribbons: morphology, properties, synthesis, defects and applications. Nano Today 5:351–372

    Article  Google Scholar 

  10. Kuila T, Mishra AK, Khanra P, Kim NH, Lee JH (2013) Recent advances in the efficient reduction of graphene oxide and its application as energy storage electrode materials. Nanoscale 5:52–71

    Article  Google Scholar 

  11. Li F, Kou L, Chen W, Wu C, Guo T (2013) Enhancing the short-circuit current and power conversion efficiency of polymer solar cells with graphene quantum dots derived from double-walled carbon nanotubes. NPG Asia Mater 5:e60

    Article  Google Scholar 

  12. Fringes S, Volk C, Norda C, Terrés B, Dauber J, Engels S, Trellenkamp S, Stampfer C (2011) Charge detection in a bilayer graphene quantum dot. Phys Status Solidi B 248:2684–2687

    Article  Google Scholar 

  13. Zhang Y, Wu C, Zhou X, Wu X, Yang Y, Wu H, Guo S, Zhang J (2013) Graphene quantum dots/gold electrode and its application in living cell H2O2 detection. Nanoscale 5:1816–1819

    Article  Google Scholar 

  14. Li LL, Ji J, Fei R, Wang CZ, Lu Q, Zhang JR, Jiang LP, Zhu JJ (2012) A facile microwave avenue to electrochemiluminescent two-color graphene quantum dots. Adv Funct Mater 22(14):2971–2979

    Article  Google Scholar 

  15. Zhu C, Dong S (2013) Synthesis of graphene-supported noble metal hybrid nanostructures and their applications as advanced electro catalysts for fuel cells. Nanoscale 5:10765–10775

    Article  Google Scholar 

  16. Chen D, Zhao Y, Peng X, Wang X, Hu W, Jing C, Tian S, Tian J (2015) Star-like PtCu nanoparticles supported on graphene with superior activity for methanol electro-oxidation. Electrochim Acta 177:86–92

    Article  Google Scholar 

  17. Eda G, Lin YY, Mattevi C, Yamaguchi H, Chen HA, Chen IS, Chen CW, Chhowalla M (2010) Blue photoluminescence from chemically derived graphene oxide. Adv Mater 22:505–509

    Article  Google Scholar 

  18. Eda G, Mattevi C, Yamaguchi H, Kim H, Chhowalla M (2009) Insulator to semimetal transition in graphene oxide. J Phys Chem C 113:15768–15771

    Article  Google Scholar 

  19. Kotov NA (2006) Materials science: carbon sheet solutions. Nature 442:254–255

    Article  Google Scholar 

  20. Paredes JI, Villar-Rodil S, Martínez-Alonso A, Tascón JMD (2008) Graphene oxide dispersions in organic solvents. Langmuir 24:10560–10564

    Article  Google Scholar 

  21. Song M, Cai D (2012) Graphene functionalization? a review. In: Mittal V (ed) Polymer nanocomposites. Royal Society of Chemistry, Cambridge, pp 1–51

    Google Scholar 

  22. Wang J, Hernandez Y, Lotya M, Coleman JN, Blau WJ (2009) Broadband nonlinear optical response of graphene dispersions. Adv Mater 21:2430–2435

    Article  Google Scholar 

  23. Krishna MBM, Venkatramaiah N, Venkatesan R, Rao DN (2012) Synthesis and structural, spectroscopic and nonlinear optical measurements of graphene oxide and its composites with metal and metal free porphyrins. J Mater Chem 22:3059–3068

    Article  Google Scholar 

  24. Jiang X-F, Polavarapu L, Neo ST, Venkatesan T, Xu Q-H (2012) Graphene oxides as tunable broadband nonlinear optical materials for femtosecond laser pulses. J Phys Chem Lett 3:785–790

    Article  Google Scholar 

  25. Liaros N, Aloukos P, Kolokithas-Ntoukas A, Bakandritsos A, Szabo T, Zboril R, Couris S (2013) Nonlinear optical properties and broadband optical power limiting action of graphene oxide colloids. J Phys Chem C 117:6842–6850

    Article  Google Scholar 

  26. Liaros N, TucekJ Dimos K, Bakandritsos A, Andrikopoulos KS, GournisD Zboril R, Couris S (2016) The effect of the degree of oxidation on broadband nonlinear absorption and ferromagnetic ordering in graphene oxide. Nanoscale 8:2908–2917

    Article  Google Scholar 

  27. Feng M, Zhan HB, Chen Y (2010) Nonlinear optical and optical limiting properties of graphene families. Appl Phys Lett 96:033107

    Article  Google Scholar 

  28. Zhang XL, Zhao X, Liu ZB, Shi S, Zhou WY, Tian JG, Xu YF, Chen YS (2011) Nonlinear optical and optical limiting properties of graphene oxide-Fe3O4 hybrid material. J Opt 13:075202

    Article  Google Scholar 

  29. Zhang XL, Liu ZB, Li X, Ma Q, Chen X, Tian J, Xu Y, Chen Y (2013) Transient thermal effect, nonlinear refraction and nonlinear absorption properties of graphene oxide sheets in dispersion. Opt Express 21:7511–7520

    Article  Google Scholar 

  30. Bourlinos AB, Bakandritsos A, Liaros N, Couris S, Safarova K, Otyepka M, Zboril R (2012) Water dispersible functionalized graphene fluoride with significant nonlinear optical response. Chem Phys Lett 543:101–105

    Article  Google Scholar 

  31. Zhang H, Virally S, Bao Q, Ping LK, Massar S, Godbout N, Kockaert P (2012) Z-scan measurement of the nonlinear refractive index of graphene. Opt Lett 37:1856–1858

    Article  Google Scholar 

  32. Karimzadeh R, Arandian A (2015) Unusual nonlinear absorption response of graphene oxide in the presence of a reduction process. Laser Phys Lett 12:025401

    Article  Google Scholar 

  33. Becerril HA, Mao J, Liu ZF, Stoltenberg RM, Bao ZN, Chen YS (2008) Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2:463–470

    Article  Google Scholar 

  34. Dato A, Lee Z, Jeon K-J, Erni R, Radmilovic V, Richardsonc TJ, Frenklachd M (2009) Clean and highly ordered graphene synthesized in the gas phase. Chem Commun 2009:6095–6097

    Article  Google Scholar 

  35. Wang X, Jin J, Song M (2012) Cyanate ester resin/graphene nanocomposite: curing dynamics and network formation. Eur Polym J 48:1034–1041

    Article  Google Scholar 

  36. Chen J, Yao B, Li C, Shi G (2013) An improved Hummers method for eco-friendly synthesis of graphene oxide. Carbon 64:225–229

    Article  Google Scholar 

  37. Li M, Cushing SK, Zhou X, Guo S, Wu N (2012) Finger printing photoluminescence of functional groups in graphene oxide. J Mater Chem 22:23374–23379

    Article  Google Scholar 

  38. Zhang L, Liang J, Huang Y, MaY WangY, Chen Y (2009) Size-controlled synthesis of graphene oxide sheets on a large scale using chemical exfoliation. Carbon 47:3365–3380

    Article  Google Scholar 

  39. Sun X, Liu Z, Welsher K, Robinson JT, Goodwin A, Zaric S, Dai H (2008) Nano-graphene oxide for cellular imaging and drug delivery. Nano Res 1:203–212

    Article  Google Scholar 

  40. ZhouY Bao Q, Tang LAL, Zhong Y, Loh KP (2009) Hydrothermal dehydration for the “green” reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties. Chem Mater 21:2950–2956

    Article  Google Scholar 

  41. Jin SH, Kim DH, Jun GH, Hong SH, Jeon S (2013) Tuning the photoluminescence of graphene quantum dots through the charge transfer effect of functional groups. ACS Nano 7:1239–1245

    Article  Google Scholar 

  42. Carter CA, Harris JM (1984) Comparison of models describing the thermal lens effect. Appl Opt 23:476–481

    Article  Google Scholar 

  43. Cuppo FLS, Neto AMF, Gomez SL (2002) Thermal-lens model compared with the Sheik-Bahae formalism in interpreting Z-scan experiments on lyotropic liquid crystals. J Opt Soc Am B 19:1342–1348

    Article  Google Scholar 

  44. Falconieri M (1999) Thermo-optical effects in Z-scan measurements using high- repetition-rate lasers. J Opt A 1999:662–667

    Article  Google Scholar 

  45. ZamirAnvari J, Karimzadeh R, Mansour N (2010) Thermo-optic properties and nonlinear responses of copper nanoparticles in polysiloxane oil. J Opt 12:035212

    Article  Google Scholar 

Download references

Acknowledgement

This work was supported by the Iran National Science Foundation under Grant No. 93039242.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rouhollah Karimzadeh.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yadi, M., Karimzadeh, R. & Abbasi, A. Effect of treatment by electrostatic field and 532-nm laser irradiation on optical and thermo-optical properties of graphene oxide colloids. J Mater Sci 52, 4532–4542 (2017). https://doi.org/10.1007/s10853-016-0698-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-016-0698-6

Keywords

Navigation