Abstract
In this article, we investigate the effect of modified carbon fiber-reinforced polymer (CFRP) composites when galvanically coupled with AISI 1018 carbon steel. Two different resins were used to manufacture the CFRPs: neat epoxy resin, and epoxy resin modified with multi-walled carbon nanotubes (MWCNTs). The specimens of composite (the cathode of the galvanic cell) and metal (the anode of the galvanic cell) were paired and immersed in electrolyte (NaCl solution, 2 % by weight) at 40 °C, to simulate a corrosive environment and accelerate the electrochemical reaction. Results of corrosion rate (CR) and mass loss rate (MR) were obtained, and the electrical resistances of the CFRPs were also measured. This new study shows that the MWCNTs do not have a statistically significant impact on the corrosion and mass loss rate results, and that both types of CFRP composites have statistically the same electrical resistance. Therefore, common methods used in the engineering practice in conventional hybrid CFRP/steel joints and repairs may be sufficient to delay galvanic corrosion, as there is no increased liability.
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Schnerch D, Rizkalla S (2008) J Bridge Eng 13(2):192. doi:10.1061/(ASCE)1084-0702(2008)13:2(192)
Ekiz E, El-Tawil S, Parra-Montesinos G, Goel S (2004) In: Proceedings of the 13th world conference on earthquake engineering. Vancouver, Canada
Ekiz E, El-Tawil S (2006) In: Proceedings of the 8th U.S. national conference on earthquake engineering. NCEE, San Francisco
El-Tawil S, Ekiz E (2009) J Struct Eng 135(5):530. doi:10.1061/(ASCE)ST.1943-541X.0000003
Harries KA, Peck AJ, Abraham EJ (2009) Thin Wall Struct 47(10):1092. doi:10.1016/j.tws.2008.10.007
Jones SC, Civjan SA (2003) J Compos Constr 7(4):331. doi:10.1061/(ASCE)1090-0268(2003)7:4(331)
Phares BM, Wipf TJ, Klaiber FW, Abu-Hawash A, Lee YS (2003) In: Proceedings of the 2003 mid-continent transportation research symposium. Iowa State University, Ames
Narmashiri K, Sulong NHR, Jumaat MZ (2011) Int J Phys Sci 6(7):1620
Tucker WC, Brown R (1989) J Compos Mater 23(4):389. doi:10.1177/002199838902300406
Tavakkolizadeh M, Saadatmanesh H (2001) J Compos Constr 5(3):200. doi:10.1061/(ASCE)1090-0268(2001)5:3(200)
Zitter H, Pauluzzi K (1993) J Mater Sci Mater Med 4:159
Cortada M, Giner Ll, Costa S, Gil FJ, Rodríguez D, Planell JA (2000) J Mater Sci Mater Med 11:287
Lin YC, Zhong J (2008) J Mater Sci 43:3072. doi:10.1007/s10853-007-2320-4
Waizy H, Seitz J-M, Reifenrath J, Weizbauer A, Bach F-W, Meyer-Lindenberg A, Denkena B, Windhagen H (2012) J Mater Sci. doi:10.1007/s10853-012-6572-2
van Drunen J, Zhao B, Jerkiewicz G (2011) J Mater Sci 46:5931. doi:10.1007/s10853-011-5548-y
Zhang J, Gu Y, Guo Y, Ning C (2012) J Mater Sci 47:5197. doi:10.1007/s10853-012-6403-5
Tawfik Q, Karunasena W (2010) In: Proceedings of the 2010 southern region engineering conference. SREC, Toowoomba
Schnerch D, Stanford K, Sumner E, Rizkalla S (2005) In: Proceedings of the international symposium on bond behaviour of FRP in structures. BBFS, Hong Kong, p 435
Rizkalla S (2004) In: Proceedings of COMPOSITES 2004, convention and trade show, American composites manufacturers association. CICE, Tampa
Baldan A (2004) J Mater Sci 39:4729. doi:10.1023/B:JMSC.0000035317.87118.ab
Mertz DR, Gillespie JW (1996) Rehabilitation of steel bridge girders through the application of composite materials, NCHRP report no. 93-ID 11. Transportation Research Board, Washington, DC
Hollaway LC, Cadei J (2002) Prog Struct Eng Mat 4(2):131. doi:10.1002/pse.112
Seica MV, Packer JA (2007) Compos Struct 80:440. doi:10.1016/j.compstruct.2006.05.029
Okeil AM, Bingol Y, Ferdous MDR (2009) A novel technique for stiffening steel structures, FHWA report no. FHWA/LA.08/441. Louisiana Transportation Research Centre, Baton Rouge
Thostenson ET, Chou T-W (2006) Adv Mater 18(21):2837. doi:10.1002/adma.200600977
Thostenson ET, Chou T-W (2008) Nanotechnol 19(21):215713. doi:10.1088/0957-4484/19/21/215713
Lim AS, Melrose ZR, Thostenson ET, Chou T-W (2011) Compos Sci Technol 71:1183. doi:10.1016/j.compscitech.2010.10.009
Bily MA, Kwon YW, Pollak RD (2010) Appl Compos Mater 17:347. doi:10.1007/s10443-009-9124-4
Chung DDL (2004) J Mater Sci 39:2645. doi:10.1023/B:JMSC.0000021439.18202.ea
Park J-M, Kim D-S, Kim S-J, Kim P-G, Yoon D-J, DeVries KL (2007) Compos B Eng 38:847. doi:10.1016/j.compositesb.2006.12.004
Alexopoulos ND, Bartholome C, Poulin P, Marioli-Riga Z (2010) Compos Sci Technol 70:260. doi:10.1016/j.compscitech.2009.10.017
Kostopoulos V, Vavouliotis A, Karapappas P, Tsotra P, Paipetis A (2009) J Intell Mater Syst Struct 20:1025. doi:10.1177/1045389X08099993
Zhang W, Sakalkar V, Koratkar N (2007) Appl Phys Lett 91:133102. doi:10.1063/1.2783970
Rausch J, Mader E (2010) Compos Sci Technol 70:2023. doi:10.1016/j.compscitech.2010.08.003
Loh KJ, Hou TC, Lynch JP, Kotov NA (2007) In: Proceedings of the 6th international workshop on structural health monitoring. Stanford University, Stanford
Ranieri C, Fabbrocino G, Song Y, Shanov V (2011) In: International workshop on smart materials & structures and NDT in aerospace conference. Pratt & Whitney Corporation, Montreal
Aung NN, Zhou W, Goh CS, Nai SML, Wei J (2010) Corros Sci 52:1551
Fukuda H, Szpunar JA, Kondoh K, Chromik R (2010) Corros Sci 52:3917
Turhan MC, Li Q, Jha H, Singer RF, Virtanen S (2011) Electrochim Acta 56:7141
Ireland R, Arronche L, La Saponara V (2012) Compos B Eng 43(2):183. doi:10.1016/j.compositesb.2011.08.001
Yesil S, Winkelmann C, Bayram G, La Saponara V (2010) Mater Sci Eng 527(27–28):7340. doi:10.1016/j.msea.2010.07.105
Arronche L, La Saponara V, Yesil S, Bayram G (2012) J Appl Polym Sci. doi:10.1002/app.38448
ASTM (2003) Conducting and evaluating galvanic corrosion tests in electrolytes, ASTM G71-81 (reapproved 2003). ASTM International, West Conshohocken
ASTM (2004) Calculation of corrosion rates from electrochemical measurements, ASTM G102-89 (reapproved 2004). ASTM International, West Conshohocken
ASTM (2004) Standard practice of laboratory immersion corrosion testing of metals, ASTM G31-72 (reapproved 2004). ASTM International, West Conshohocken
ASTM (2003) Standard practice for preparing, cleaning and evaluating corrosion test specimens, ASTM G1-03. ASTM International, West Conshohocken
Stansbury E, Buchanan RA (2000) Fundamentals of electrochemical corrosion. ASM International, Materials Park
Acknowledgements
This article is based upon the research supported by the National Science Foundation to V. La Saponara, through CAREER Grant CMMI-0642814. Partial support from the Department of Civil and Environmental Engineering at UC Davis to L. Cheng is also appreciated. The authors thank Mr. Robert Ireland, for his valuable discussion on the electrochemical corrosion tests, and Mr. Henry Calanchini and Dr. Kenneth J. Loh of the Department of Civil and Environmental Engineering at UC Davis, for their assistance with the equipment/supplies and the space allowed to be used during the electrochemical corrosion tests.
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Arronche, L., Gordon, K., Ryu, D. et al. Investigation of galvanic corrosion between AISI 1018 carbon steel and CFRPs modified with multi-walled carbon nanotubes. J Mater Sci 48, 1315–1323 (2013). https://doi.org/10.1007/s10853-012-6876-2
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DOI: https://doi.org/10.1007/s10853-012-6876-2