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Preparation and magnetic properties of electrospun CuO/NiO bimetallic nanofibers via sol–gel electrospinning

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Abstract

We report the fabrication and magnetic properties of the CuO/NiO bimetallic composite nanofibers prepared by sol–gel electrospinning and followed by calcination. The added precursors (copper nitrate trihydrate (CuNT) and nickel chloride hexahydrate (NiCH)) significantly influenced the fiber formation and its morphologies during electrospinning. The magnetic properties were investigated by Vibrating Sample Magnetometer and Electron Spin Resonance (ESR) curves. After calcination for the production of the metallic nanofibers, the fiber morphologies were dramatically changed depending on the added amounts of precursors ranging from 2.5 to 7.5 wt%. From the magnetic hysteresis loop (M-H curve) and ESR analysis of the calcined electrospun CuO/NiO bimetallic nanofibers, it was found that the magnetization of the calcined electrospun CuO/NiO bimetallic nanofibers with various weight ratio of CuNT:NiCH = 9:1, 1:1, and 1:9 at an applied magnetic field of 10 kOe was 0.480, 0.402, and 0.337 emu/g, respectively, indicating that the calcined electrospun CuO/NiO bimetallic nanofibers have magnetic properties.

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Acknowledgements

The authors acknowledge the support of Shinshu University Global COE Program. ‘‘International Center of Excellence on Fiber Engineering.’’

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Authors and Affiliations

  1. Nano Fusion Technology Research Group, Faculty of Textile Science & Technology, Interdisciplinary Graduate School of Science and Technology, Shinshu University, Ueda, Nagano, 386-0015, Japan

    Han-Ki Kim, Wataru Honda & Ick-Soo Kim

  2. Department of Organic Materials & Fiber Engineering, Chonbuk National University, 567 Baekje-daero Deokjin-gu, Jeonju-si, Jeollabuk-do, 561-756, Republic of Korea

    Byoung-Suhk Kim

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  1. Han-Ki Kim
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  2. Wataru Honda
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  3. Byoung-Suhk Kim
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  4. Ick-Soo Kim
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Correspondence to Byoung-Suhk Kim or Ick-Soo Kim.

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Kim, HK., Honda, W., Kim, BS. et al. Preparation and magnetic properties of electrospun CuO/NiO bimetallic nanofibers via sol–gel electrospinning. J Mater Sci 48, 1111–1116 (2013). https://doi.org/10.1007/s10853-012-6843-y

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  • DOI: https://doi.org/10.1007/s10853-012-6843-y

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