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Synthesis, structure and impedance spectroscopic analysis of [(Pb x Sr1−x )·OTiO2]–[(2SiO2·B2O3)]–7[BaO]–3[K2O] glass ceramic system doped with La2O3

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Abstract

Various compositions of glasses were prepared by melt quenching method in the glass ceramic 64[(Pb x Sr1−x )OTiO2]–25[(2SiO2·B2O3)]–7[BaO]–3[K2O]–1[La2O3] (0.5 ≤ x ≤ 1) system doped with La2O3. Dielectric constant, εr versus temperature, T, plots revealed diffused peaks, while dielectric loss, D, versus T plots showed shifting in the peaks toward the higher temperature side similar to relaxor-like ceramics. Curie temperature was found to change systematically with changing the concentration of SrO. Impedance spectroscopy results indicated the contributions of polarization process relaxing in low frequency region attributed to polarizations at the crystal to glass interface and the glassy region.

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Acknowledgements

The authors would like to thank the Defence Research Development Organisation, India for financial support and to Prof. D. Pandey of School of Materials Science and Technology, IT-BHU, for providing XRD facility.

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Authors and Affiliations

  1. Department of Physics, University of Lucknow, Lucknow, 226007, India

    C. R. Gautam

  2. Department of Applied Physics, Institute of Technology, Banaras Hindu University, Varanasi, 221005, India

    Prabhakar Singh

  3. Solid State Physics Laboratory, Lucknow Road, Timarpur, Delhi, 110054, India

    O. P. Thakur

  4. Department of Ceramic Engineering, Institute of Technology, Banaras Hindu University, Varanasi, 221005, India

    D. Kumar & O. Parkash

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  1. C. R. Gautam
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  2. Prabhakar Singh
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Correspondence to C. R. Gautam.

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Gautam, C.R., Singh, P., Thakur, O.P. et al. Synthesis, structure and impedance spectroscopic analysis of [(Pb x Sr1−x )·OTiO2]–[(2SiO2·B2O3)]–7[BaO]–3[K2O] glass ceramic system doped with La2O3 . J Mater Sci 47, 6652–6664 (2012). https://doi.org/10.1007/s10853-012-6602-0

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