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A green synthesis of CTAB–PTP/PAM microhydrogel and its application in oxidation of DBT

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Abstract

Polyacrylamide (PAM) microgels covered with hexadecyltrimethylammonium (CTAB)-peroxotungstophosphate (PTP) complexes were synthesized and characterized by scanning electron microscopy and Fourier transform infrared. The results indicate the CTAB–PTP/PAM composite microsphere with surface-wrinkling morphology and PAM microgel core/CTAB–PTP shell structure. The surface-wrinkling structure changed with the amount of CTAB–PTP supported on the PAM microgels. The results based on CTAB–PTP/PAM composite microspheres used in oxidation of dibenzothiophene demonstrated that the resulting microspheres have high catalytic performance and could be reused three times with a small decrease in activity. The proposed method is commonly significant for construction of reusable catalyst used in diphase catalysis.

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Acknowledgements

We gratefully acknowledge the National Science Foundation of China (20576068, 20773084) and the Project of Yuncheng University in Shanxi Province (20060228) for financial support.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shaanxi Normal University, Xi’an, 710062, Shaanxi, People’s Republic of China

    Shaofei Song & Daodao Hu

  2. Department of Applied Chemistry, Yuncheng University, Yuncheng, 044000, Shanxi, People’s Republic of China

    Shaofei Song

  3. School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an, 710062, Shaanxi, People’s Republic of China

    Shukun Shen

  4. Department of Chemistry and Chemical Engineering, Xi’an University of Arts and Science, Xi’an, 710065, Shaanxi, People’s Republic of China

    Juxiang Yang

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  1. Shaofei Song
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  2. Shukun Shen
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  4. Daodao Hu
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Correspondence to Daodao Hu.

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Song, S., Shen, S., Yang, J. et al. A green synthesis of CTAB–PTP/PAM microhydrogel and its application in oxidation of DBT. J Mater Sci 47, 2501–2508 (2012). https://doi.org/10.1007/s10853-011-6074-7

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  • DOI: https://doi.org/10.1007/s10853-011-6074-7

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