Abstract
The conductive composites were prepared using two different types of conductive black (Conductex and Printex XE2) filled in matrices like EVA and NBR and their different blends. The electromagnetic interference shielding effectiveness (EMI SE) of all composites was measured in the X band frequency range 8–12 GHz. Both conductivity and EMI SE increase with filler loading. However, Printex black shows higher conductivity and better EMI SE at the same loading compared to Conductex black, and this can be used as a material having high EMI shielding effectiveness value. The conductivity of different blends with same filler loading generally found to increase slightly with the increase in NBR concentration. However, EMI SE has some dependency on blend composition. EMI SE increases linearly with thickness of the sample. EMI SE versus conductivity yields two master curves for two different fillers. EMI SE depends on formation of closed packed conductive network in insulating matrix, and Printex black is better than Conductex black in this respect. Some of the composites show appreciably high EMI SE (>45 dB).
Similar content being viewed by others
References
Mottahed BD, Manoocheheri S (1995) Polym Plast Technol Eng 34(2):271
Lakshmi K, John H, Mathew KT, Rani J, George KE (2009) Acta Mater 57:371
Lu G, Li X, Jiang H (1996) Compos Sci Technol 56:193
Kaynak A, Polat A, Yilmazer U (1996) Mater Res Bull 31(10):1195
Chung DDL (2001) Carbon 39:279
Jackson BC, Shawhan G (1998) In: IEEE international symposium on electro-magnetic compatibility, current review of the performance characteristics of conductive coatings for EMI control, vol 1. IEEE, Piscataway, New Jersey, USA, p 567
Sidhu A, Reike J, Michelsen U, Messinger R, Habiger E, Wolf J (1997) In: IEEE international symposium on electromagnetic compatibility IEEE, Piscataway, metallization of plastics for shielding. IEEE, New Jersey, USA, p 102
Hajdu J (1997) Trans Inst Metal Finish 75(pt. 1):B7
Gwinner D, Scheyrer P, Fernandez W (1996) In: Proceedings of 39th annual technical conference—society of vacuum coaters, selective deposition of aluminum on plastic parts for EMI shielding. Society of Vacuum Coaters, Albuquerque, New Mexico, USA, p 336
Bhatia MS (1995) In: Proceedings of 1995 4th international conference on electromagnetic interference and compatibility, technique for depositing metal layers over large areas for EMI shielding. IEEE, Madras, India, p 321
Zhang L, Li W, Liu J, Ren B (1995) Cailiao Gongcheng/J Mater Eng 7:38
Mandich NV (1994) Plat Surf Finish 81(10):60
Jackson BC, Kuzyk P (1994) In: IEEE conference on publication, no. 396, practical guide on the use of electroless coatings for EMI shielding. IEEE, Stevenage, UK, p 119
Mason PJD (1994) In: Proceedings of 37th annual technical conference—society vacuum coaters, technologies and markets for thin film EMI/RFI shielding materials. Society of Vacuum Coaters, Albuquerque, New Mexico, USA, p 192
Pomposo JA, Rodriguez J, Grande H (1999) Synth Met 104(2):107
Courric S, Tran VH (1998) Polymer 39(12):2399
Makela T, Pienimaa S, Taka T, Jussila S, Isotalo H (1997) Synth Met 85(1–3):1335
Kohlman RS, Min YG, MacDiarmid AG, Epstein AJ (1996) J Eng Appl Sci 2:1412
Kaynak A (1996) Mater Res Bull 31(7):845
Borgmans APJH, Glaser RH (1995) Evaluat Eng 34(7):S32
Nguyen MT, Diaz AF (1994) Adv Mater 6(11):858
Unsworth J, Conn C, Jin Z, Kaynak A, Ediriweera R, Innis P, Booth N (1994) J Int Mater Sys Struct 5(5):595
Kaynak A, Unsworth J, Clout R, Mohan AS, Beard GE (1994) J Appl Polym Sci 54(3):269
Kaynak A, Mohan S, Unsworth J, Clout R (1994) J Mater Sci Lett 13(15):1121
Sauerer W (1994) Galvanotechnik 85(5):1467
Xing L, Liu J, Ren S (1998) Cailiao Gongcheng/J Mater Eng 1:19
Jana PB, Mallick AK, De SK (1993) J Mater Sci 28:2097. doi:10.1007/BF00367568
Rupprecht L, Hawkinson C (1999) Med Dev Diagn Ind 21(1):8
Shui X, Chung DDL (2000) J Mater Sci 35:1773. doi:10.1023/A:1004784720338
Tan S, Zhang M, Zeng H (1998) Cailiao Gongcheng/J Mater Eng 5:6
Qinglei L, Tongxiang F, Zhang D (2004) J Mater Sci 39:6209. doi:10.1023/B:JMSC.0000043588.51435.29
Olivero DA, Radford DW (1998) J Reinf Plast Compos 17(8):674
Wen S, Chung DDL (2005) J Mater Sci 40:3897. doi:10.1007/s10853-005-0717-5
Sau KP, Chaki TK, Chakraborty A, Khastgir D (1997) Plast Rubber Compos Process Appl 26(7):291
Das NC, Maiti S (2008) J Mater Sci 43:1920. doi:10.1007/s10853-008-2458-8
Zhu M, Chung DDL (1991) J Electron Package 113:417
Chung DDL (2000) JMEPEG 9:161
Das NC, Khastgir D, Chacraborty A, Chaki TK (2002) J Elastomer Plast 34(3):199
White X, Donald RJ, Mardiguian M (1973) Electromagnetic compatibility handbook, vol 3. Don White Consultants, Gainesville, VA
Pierre, Deltour R, Perenboom JA, Van Bentum PJM (1990) Phys Rev B 42(6):3380
Sohi NJS, Bhadra S, Khastgir D (2010) The effect of different carbon fillers on the electrical conductivity of ethylene vinyl acetate copolymer-based composites and the applicability of different conductivity models. Carbon. doi:10.1016/j.carbon.2010.12.001
Fu SL (1981) IEEE Trans Comp Hybrid Manuf Technol 4(3):289
Probst N, Grivei E (2002) Carbon 40:201
Dick JS (2001) Rubber technology. Compounding and testing for performance. Hanser Publisher, Munich, p 297
Dana P, Hans D, Serge K, Roy C (2003) Appl Surf Sci 217:181
Pramanik PK, Saha TN, Khastgir D (1991) J Elastomer Plast 23(4):345
Acknowledgements
The authors would like to thank Aeronautics Research and Development Board for their financial support to carry out research work.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rahaman, M., Chaki, T.K. & Khastgir, D. Development of high performance EMI shielding material from EVA, NBR, and their blends: effect of carbon black structure. J Mater Sci 46, 3989–3999 (2011). https://doi.org/10.1007/s10853-011-5326-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-011-5326-x